Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial Polymerization

Abstract Microencapsulated ionic liquids (ILs) have a wide range of exciting properties. They can be synthesized by a variety of methods, of which interfacial polymerization represents a very simple, fast, and reliable production process, but the number of available shell materials that can be obtai...

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Main Authors: Robin Scholl, Dominic Freudenmann
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:Advanced Materials Interfaces
Subjects:
Online Access:https://doi.org/10.1002/admi.202400393
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author Robin Scholl
Dominic Freudenmann
author_facet Robin Scholl
Dominic Freudenmann
author_sort Robin Scholl
collection DOAJ
description Abstract Microencapsulated ionic liquids (ILs) have a wide range of exciting properties. They can be synthesized by a variety of methods, of which interfacial polymerization represents a very simple, fast, and reliable production process, but the number of available shell materials that can be obtained by this method is limited. However, recent advances in the field of interfacial polymerization have described the formation of a polyamide membrane at the IL/organic phase interface, which is extended in this work to the first microencapsulation of ILs with a polyamide shell, providing an additional and versatile shell material. The IL‐filled microcapsules are obtained using a surfactant‐free synthesis process and inexpensive, low‐toxicity monomers and solvents and feature an exceptionally high core‐to‐shell weight ratio enabling a broad range of possible applications.
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institution Kabale University
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publisher Wiley-VCH
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series Advanced Materials Interfaces
spelling doaj-art-9d09cf1b877e4acb9973b963f743fe852025-01-03T08:39:29ZengWiley-VCHAdvanced Materials Interfaces2196-73502025-01-01121n/an/a10.1002/admi.202400393Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial PolymerizationRobin Scholl0Dominic Freudenmann1Department for Chemical Propellant TechnologyInstitute of Space PropulsionIm Langen Grund 74239 Hardthausen am Kocher GermanyDepartment for Chemical Propellant TechnologyInstitute of Space PropulsionIm Langen Grund 74239 Hardthausen am Kocher GermanyAbstract Microencapsulated ionic liquids (ILs) have a wide range of exciting properties. They can be synthesized by a variety of methods, of which interfacial polymerization represents a very simple, fast, and reliable production process, but the number of available shell materials that can be obtained by this method is limited. However, recent advances in the field of interfacial polymerization have described the formation of a polyamide membrane at the IL/organic phase interface, which is extended in this work to the first microencapsulation of ILs with a polyamide shell, providing an additional and versatile shell material. The IL‐filled microcapsules are obtained using a surfactant‐free synthesis process and inexpensive, low‐toxicity monomers and solvents and feature an exceptionally high core‐to‐shell weight ratio enabling a broad range of possible applications.https://doi.org/10.1002/admi.202400393interfacial polymerizationionic liquidsmicroencapsulationpolymerization
spellingShingle Robin Scholl
Dominic Freudenmann
Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial Polymerization
Advanced Materials Interfaces
interfacial polymerization
ionic liquids
microencapsulation
polymerization
title Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial Polymerization
title_full Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial Polymerization
title_fullStr Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial Polymerization
title_full_unstemmed Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial Polymerization
title_short Ionic Liquid‐Filled Polyamide Microcapsules Obtained by Interfacial Polymerization
title_sort ionic liquid filled polyamide microcapsules obtained by interfacial polymerization
topic interfacial polymerization
ionic liquids
microencapsulation
polymerization
url https://doi.org/10.1002/admi.202400393
work_keys_str_mv AT robinscholl ionicliquidfilledpolyamidemicrocapsulesobtainedbyinterfacialpolymerization
AT dominicfreudenmann ionicliquidfilledpolyamidemicrocapsulesobtainedbyinterfacialpolymerization