Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 Nanorod
Insecticides are chemicals used to control insects by killing them or preventing them from engaging in undesirable or destructive behaviors. Imidacloprid is an insecticide made to mimic nicotine. Nicotine is naturally found in many plants, including tobacco, and is toxic to insects. Imidacloprid is...
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Iranian Chemical Society
2024-10-01
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Series: | Nanochemistry Research |
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Online Access: | http://www.nanochemres.org/article_203004_13a23ca2e9d1505f56cdda0c97388fa3.pdf |
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author | Razieh Razavi Zeinab Nazari Moslem Basij |
author_facet | Razieh Razavi Zeinab Nazari Moslem Basij |
author_sort | Razieh Razavi |
collection | DOAJ |
description | Insecticides are chemicals used to control insects by killing them or preventing them from engaging in undesirable or destructive behaviors. Imidacloprid is an insecticide made to mimic nicotine. Nicotine is naturally found in many plants, including tobacco, and is toxic to insects. Imidacloprid is used to control sucking insects, termites, some soil insects, and fleas on pets. In this study, imidacloprid removal was investigated by synthesized MoO3 from an aqueous solution. For this purpose, FT-IR, XRD, UV–Vis, SEM, and EDS were used to characterize the synthesized nano adsorbents and to determine the removal process. Batch adsorption studies were conducted to investigate the effect of temperature, initial Imidacloprid concentration, and adsorbent count and contact time as important adsorption parameters. The maximum equilibrium time was 25 min with 5 mg adsorbent at 45ºC and pH=7 for MoO3. All the adsorption equilibrium data were well fitted to the Freundlich and Langmuir isotherm model with heterogeneous, multilayer, temperature-dependent, irreversible, and nonspontaneous behavior. The ∆H is 0.2 J, and the ∆S is 2.3 J mol-1K-1. |
format | Article |
id | doaj-art-9b1408375fd84c54be3cc709e6992458 |
institution | Kabale University |
issn | 2538-4279 2423-818X |
language | English |
publishDate | 2024-10-01 |
publisher | Iranian Chemical Society |
record_format | Article |
series | Nanochemistry Research |
spelling | doaj-art-9b1408375fd84c54be3cc709e69924582025-01-12T10:25:19ZengIranian Chemical SocietyNanochemistry Research2538-42792423-818X2024-10-019427227910.22036/NCR.2024.04.03203004Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 NanorodRazieh Razavi0Zeinab Nazari1Moslem Basij2Department of Chemistry, Faculty of Science, University of Jiroft, Jiroft, IranDepartment of Chemistry, Faculty of Science, University of Jiroft, Jiroft, IranDepartment of Plant Protection, Faculty of Agriculture, University of Jiroft, Jiroft, IranInsecticides are chemicals used to control insects by killing them or preventing them from engaging in undesirable or destructive behaviors. Imidacloprid is an insecticide made to mimic nicotine. Nicotine is naturally found in many plants, including tobacco, and is toxic to insects. Imidacloprid is used to control sucking insects, termites, some soil insects, and fleas on pets. In this study, imidacloprid removal was investigated by synthesized MoO3 from an aqueous solution. For this purpose, FT-IR, XRD, UV–Vis, SEM, and EDS were used to characterize the synthesized nano adsorbents and to determine the removal process. Batch adsorption studies were conducted to investigate the effect of temperature, initial Imidacloprid concentration, and adsorbent count and contact time as important adsorption parameters. The maximum equilibrium time was 25 min with 5 mg adsorbent at 45ºC and pH=7 for MoO3. All the adsorption equilibrium data were well fitted to the Freundlich and Langmuir isotherm model with heterogeneous, multilayer, temperature-dependent, irreversible, and nonspontaneous behavior. The ∆H is 0.2 J, and the ∆S is 2.3 J mol-1K-1.http://www.nanochemres.org/article_203004_13a23ca2e9d1505f56cdda0c97388fa3.pdfimidaclopridmoo3adsorptionremovalisotherm |
spellingShingle | Razieh Razavi Zeinab Nazari Moslem Basij Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 Nanorod Nanochemistry Research imidacloprid moo3 adsorption removal isotherm |
title | Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 Nanorod |
title_full | Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 Nanorod |
title_fullStr | Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 Nanorod |
title_full_unstemmed | Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 Nanorod |
title_short | Adsorption Removal of Imidacloprid Insecticide in Agriculture Industry Using MoO3 Nanorod |
title_sort | adsorption removal of imidacloprid insecticide in agriculture industry using moo3 nanorod |
topic | imidacloprid moo3 adsorption removal isotherm |
url | http://www.nanochemres.org/article_203004_13a23ca2e9d1505f56cdda0c97388fa3.pdf |
work_keys_str_mv | AT raziehrazavi adsorptionremovalofimidaclopridinsecticideinagricultureindustryusingmoo3nanorod AT zeinabnazari adsorptionremovalofimidaclopridinsecticideinagricultureindustryusingmoo3nanorod AT moslembasij adsorptionremovalofimidaclopridinsecticideinagricultureindustryusingmoo3nanorod |