New Pyrazolines with Imine Moiety: Synthesis, Characterization

Chalcone was prepared  by   claisen- schmidt  condensation  between   reaction equivalent moles  from 4-amino acetophenone with  thiophen -2-carboxaldehyde in presence sodium hydroxide as base, the mechanism was involved the abstraction α Proton by base from the α-carbon of the ketone to form carba...

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Bibliographic Details
Main Authors: Marwa A. Atiyah, Olfat A. Nief, Abdulkader M. Noori
Format: Article
Language:English
Published: Tikrit University 2021-11-01
Series:Tikrit Journal of Pure Science
Subjects:
Online Access:https://tjpsj.org/index.php/tjps/article/view/175
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Summary:Chalcone was prepared  by   claisen- schmidt  condensation  between   reaction equivalent moles  from 4-amino acetophenone with  thiophen -2-carboxaldehyde in presence sodium hydroxide as base, the mechanism was involved the abstraction α Proton by base from the α-carbon of the ketone to form carbanion, which attacks carbonyl of aldehyde contains no α-hydrogens to produce α-β-unsaturated ketone, Chalcone derivative used to synthesize pyrazoline derivatives by condensation with 2,4-dinitro phenyl hydrazine. The newly synthesized compounds were determined using spectroscopic methods such as FTIR, Mass spectra, 1H-NMR.
ISSN:1813-1662
2415-1726