Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin
The goal of the present study was to clarify the nature of benzene forming in base catalyzed side-chain alkylation of toluene with methanol. Benzene formation has been observed as a primary product in the very beginning of conversion of toluene/methanol mixture on the basic catalysts. Dynamics of al...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2017-09-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/0263617417705963 |
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| _version_ | 1846092137406398464 |
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| author | Yuliya G Voloshyna Olexandra P Pertko Serhiy V Konovalov Lyubov K Patrylak |
| author_facet | Yuliya G Voloshyna Olexandra P Pertko Serhiy V Konovalov Lyubov K Patrylak |
| author_sort | Yuliya G Voloshyna |
| collection | DOAJ |
| description | The goal of the present study was to clarify the nature of benzene forming in base catalyzed side-chain alkylation of toluene with methanol. Benzene formation has been observed as a primary product in the very beginning of conversion of toluene/methanol mixture on the basic catalysts. Dynamics of alteration of its content in reaction products has been explained. The nature of sites responsible for benzene formation has been suggested considering conception concerning preferences in toluene or methanol adsorption on the catalyst of different basicity. Toluene has been concluded to be a raw material for benzene formation. |
| format | Article |
| id | doaj-art-99734ae8b3d4447bb9cf5403aaad7b18 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2017-09-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-99734ae8b3d4447bb9cf5403aaad7b182025-01-02T21:31:19ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382017-09-013510.1177/0263617417705963Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable originYuliya G VoloshynaOlexandra P PertkoSerhiy V KonovalovLyubov K PatrylakThe goal of the present study was to clarify the nature of benzene forming in base catalyzed side-chain alkylation of toluene with methanol. Benzene formation has been observed as a primary product in the very beginning of conversion of toluene/methanol mixture on the basic catalysts. Dynamics of alteration of its content in reaction products has been explained. The nature of sites responsible for benzene formation has been suggested considering conception concerning preferences in toluene or methanol adsorption on the catalyst of different basicity. Toluene has been concluded to be a raw material for benzene formation.https://doi.org/10.1177/0263617417705963 |
| spellingShingle | Yuliya G Voloshyna Olexandra P Pertko Serhiy V Konovalov Lyubov K Patrylak Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin Adsorption Science & Technology |
| title | Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin |
| title_full | Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin |
| title_fullStr | Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin |
| title_full_unstemmed | Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin |
| title_short | Benzene as a by-product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin |
| title_sort | benzene as a by product of toluene with methanol transformation on the basic zeolite catalysts and its presumable origin |
| url | https://doi.org/10.1177/0263617417705963 |
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