The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon
Computed values of the effective diffusion coefficient, D e , ranging from 4.93 × 10 −10 to 5.96 × 10 −10 m 2 /s were obtained from kinetic data for the adsorption of 1,2-dichloropropane from a mixture with air on to activated carbon particles at concentrations within the range 14.94–31.51 g/m 3 . S...
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SAGE Publishing
2001-12-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/0263617011494600 |
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author | Daniel Bobok Eva Besedová |
author_facet | Daniel Bobok Eva Besedová |
author_sort | Daniel Bobok |
collection | DOAJ |
description | Computed values of the effective diffusion coefficient, D e , ranging from 4.93 × 10 −10 to 5.96 × 10 −10 m 2 /s were obtained from kinetic data for the adsorption of 1,2-dichloropropane from a mixture with air on to activated carbon particles at concentrations within the range 14.94–31.51 g/m 3 . Such kinetic adsorption data were obtained over the temperature range 24.1–25.8°C. Using the dependence D e = f(C A0 ), it was possible to compare the calculated values of D e for 1,2-dichloropropane with the experimental data for 1,2-dichloroethane obtained from adsorption measurements. The values of the effective diffusion coefficients for 1,2-dichloropropane as calculated from its desorption by pure air were within the range 1.67 × 10 −10 –2.01 × 10 −10 m 2 /s at temperatures of 24.0–24.2°C. The considerable difference between the values of the effective diffusion coefficient for 1,2-dichloropropane in activated carbon particles as estimated from adsorption and desorption data may be associated with the non-linear course of the adsorption isotherm. |
format | Article |
id | doaj-art-993245958e0042899f156ce819ac96a4 |
institution | Kabale University |
issn | 0263-6174 2048-4038 |
language | English |
publishDate | 2001-12-01 |
publisher | SAGE Publishing |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj-art-993245958e0042899f156ce819ac96a42025-01-02T22:38:06ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382001-12-011910.1260/0263617011494600The Diffusion of Chlorinated Hydrocarbons in Particles of Activated CarbonDaniel BobokEva BesedováComputed values of the effective diffusion coefficient, D e , ranging from 4.93 × 10 −10 to 5.96 × 10 −10 m 2 /s were obtained from kinetic data for the adsorption of 1,2-dichloropropane from a mixture with air on to activated carbon particles at concentrations within the range 14.94–31.51 g/m 3 . Such kinetic adsorption data were obtained over the temperature range 24.1–25.8°C. Using the dependence D e = f(C A0 ), it was possible to compare the calculated values of D e for 1,2-dichloropropane with the experimental data for 1,2-dichloroethane obtained from adsorption measurements. The values of the effective diffusion coefficients for 1,2-dichloropropane as calculated from its desorption by pure air were within the range 1.67 × 10 −10 –2.01 × 10 −10 m 2 /s at temperatures of 24.0–24.2°C. The considerable difference between the values of the effective diffusion coefficient for 1,2-dichloropropane in activated carbon particles as estimated from adsorption and desorption data may be associated with the non-linear course of the adsorption isotherm.https://doi.org/10.1260/0263617011494600 |
spellingShingle | Daniel Bobok Eva Besedová The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon Adsorption Science & Technology |
title | The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon |
title_full | The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon |
title_fullStr | The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon |
title_full_unstemmed | The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon |
title_short | The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon |
title_sort | diffusion of chlorinated hydrocarbons in particles of activated carbon |
url | https://doi.org/10.1260/0263617011494600 |
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