The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon

Computed values of the effective diffusion coefficient, D e , ranging from 4.93 × 10 −10 to 5.96 × 10 −10 m 2 /s were obtained from kinetic data for the adsorption of 1,2-dichloropropane from a mixture with air on to activated carbon particles at concentrations within the range 14.94–31.51 g/m 3 . S...

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Main Authors: Daniel Bobok, Eva Besedová
Format: Article
Language:English
Published: SAGE Publishing 2001-12-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263617011494600
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author Daniel Bobok
Eva Besedová
author_facet Daniel Bobok
Eva Besedová
author_sort Daniel Bobok
collection DOAJ
description Computed values of the effective diffusion coefficient, D e , ranging from 4.93 × 10 −10 to 5.96 × 10 −10 m 2 /s were obtained from kinetic data for the adsorption of 1,2-dichloropropane from a mixture with air on to activated carbon particles at concentrations within the range 14.94–31.51 g/m 3 . Such kinetic adsorption data were obtained over the temperature range 24.1–25.8°C. Using the dependence D e = f(C A0 ), it was possible to compare the calculated values of D e for 1,2-dichloropropane with the experimental data for 1,2-dichloroethane obtained from adsorption measurements. The values of the effective diffusion coefficients for 1,2-dichloropropane as calculated from its desorption by pure air were within the range 1.67 × 10 −10 –2.01 × 10 −10 m 2 /s at temperatures of 24.0–24.2°C. The considerable difference between the values of the effective diffusion coefficient for 1,2-dichloropropane in activated carbon particles as estimated from adsorption and desorption data may be associated with the non-linear course of the adsorption isotherm.
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spelling doaj-art-993245958e0042899f156ce819ac96a42025-01-02T22:38:06ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382001-12-011910.1260/0263617011494600The Diffusion of Chlorinated Hydrocarbons in Particles of Activated CarbonDaniel BobokEva BesedováComputed values of the effective diffusion coefficient, D e , ranging from 4.93 × 10 −10 to 5.96 × 10 −10 m 2 /s were obtained from kinetic data for the adsorption of 1,2-dichloropropane from a mixture with air on to activated carbon particles at concentrations within the range 14.94–31.51 g/m 3 . Such kinetic adsorption data were obtained over the temperature range 24.1–25.8°C. Using the dependence D e = f(C A0 ), it was possible to compare the calculated values of D e for 1,2-dichloropropane with the experimental data for 1,2-dichloroethane obtained from adsorption measurements. The values of the effective diffusion coefficients for 1,2-dichloropropane as calculated from its desorption by pure air were within the range 1.67 × 10 −10 –2.01 × 10 −10 m 2 /s at temperatures of 24.0–24.2°C. The considerable difference between the values of the effective diffusion coefficient for 1,2-dichloropropane in activated carbon particles as estimated from adsorption and desorption data may be associated with the non-linear course of the adsorption isotherm.https://doi.org/10.1260/0263617011494600
spellingShingle Daniel Bobok
Eva Besedová
The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon
Adsorption Science & Technology
title The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon
title_full The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon
title_fullStr The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon
title_full_unstemmed The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon
title_short The Diffusion of Chlorinated Hydrocarbons in Particles of Activated Carbon
title_sort diffusion of chlorinated hydrocarbons in particles of activated carbon
url https://doi.org/10.1260/0263617011494600
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