Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructures

Raman scattering is sensitive to local temperature and thus offers a convenient tool for non-contact and non-destructive optical thermometry at the nanoscale. In turn, all-dielectric nanostructures, such as silicon particles, exhibit strongly enhanced photothermal heating due to Mie resonances, whic...

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Main Authors: Vikram Mor Pal, Nishida Kentaro, Li Chien-Hsuan, Riabov Daniil, Pashina Olesiya, Tang Yu-Lung, Makarov Sergey V., Takahara Junichi, Petrov Mihail I., Chu Shi-Wei
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Language:English
Published: De Gruyter 2024-03-01
Series:Nanophotonics
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Online Access:https://doi.org/10.1515/nanoph-2023-0922
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author Vikram Mor Pal
Nishida Kentaro
Li Chien-Hsuan
Riabov Daniil
Pashina Olesiya
Tang Yu-Lung
Makarov Sergey V.
Takahara Junichi
Petrov Mihail I.
Chu Shi-Wei
author_facet Vikram Mor Pal
Nishida Kentaro
Li Chien-Hsuan
Riabov Daniil
Pashina Olesiya
Tang Yu-Lung
Makarov Sergey V.
Takahara Junichi
Petrov Mihail I.
Chu Shi-Wei
author_sort Vikram Mor Pal
collection DOAJ
description Raman scattering is sensitive to local temperature and thus offers a convenient tool for non-contact and non-destructive optical thermometry at the nanoscale. In turn, all-dielectric nanostructures, such as silicon particles, exhibit strongly enhanced photothermal heating due to Mie resonances, which leads to the strong modulation of elastic Rayleigh scattering intensity through subsequent thermo-optical effects. However, the influence of the complex photo-thermo-optical effect on inelastic Raman scattering has yet to be explored for resonant dielectric nanostructures. In this work, we experimentally demonstrate that the strong photo-thermo-optical interaction results in the nonlinear dependence of the Raman scattering signal intensity from a crystalline silicon nanoparticle via the thermal reconfiguration of the resonant response. Our results reveal a crucial role of the Mie resonance spectral sensitivity to temperature, which modifies not only the conversion of the incident light into heat but also Raman scattering efficiency. The developed comprehensive model provides the mechanism for thermal modulation of Raman scattering, shedding light on the photon–phonon interaction physics of resonant material, which is essential for the validation of Raman nanothermometry in resonant silicon structures under a strong laser field.
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spelling doaj-art-97159b4efdb3475ba95d189274564a6a2024-11-25T11:19:12ZengDe GruyterNanophotonics2192-86142024-03-0113183581358910.1515/nanoph-2023-0922Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructuresVikram Mor Pal0Nishida Kentaro1Li Chien-Hsuan2Riabov Daniil3Pashina Olesiya4Tang Yu-Lung5Makarov Sergey V.6Takahara Junichi7Petrov Mihail I.8Chu Shi-Wei9Department of Physics, 33561National Taiwan University, 1, Sec 4, Roosevelt Rd., Taipei10617, TaiwanDepartment of Physics, 33561National Taiwan University, 1, Sec 4, Roosevelt Rd., Taipei10617, TaiwanDepartment of Physics, 33561National Taiwan University, 1, Sec 4, Roosevelt Rd., Taipei10617, TaiwanSchool of Physics and Engineering, 65071ITMO University, Lomonosova 9, Saint Petersburg191002, RussiaSchool of Physics and Engineering, 65071ITMO University, Lomonosova 9, Saint Petersburg191002, RussiaDepartment of Physics, 33561National Taiwan University, 1, Sec 4, Roosevelt Rd., Taipei10617, TaiwanSchool of Physics and Engineering, 65071ITMO University, Lomonosova 9, Saint Petersburg191002, RussiaGraduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka565-0871, JapanSchool of Physics and Engineering, 65071ITMO University, Lomonosova 9, Saint Petersburg191002, RussiaDepartment of Physics, 33561National Taiwan University, 1, Sec 4, Roosevelt Rd., Taipei10617, TaiwanRaman scattering is sensitive to local temperature and thus offers a convenient tool for non-contact and non-destructive optical thermometry at the nanoscale. In turn, all-dielectric nanostructures, such as silicon particles, exhibit strongly enhanced photothermal heating due to Mie resonances, which leads to the strong modulation of elastic Rayleigh scattering intensity through subsequent thermo-optical effects. However, the influence of the complex photo-thermo-optical effect on inelastic Raman scattering has yet to be explored for resonant dielectric nanostructures. In this work, we experimentally demonstrate that the strong photo-thermo-optical interaction results in the nonlinear dependence of the Raman scattering signal intensity from a crystalline silicon nanoparticle via the thermal reconfiguration of the resonant response. Our results reveal a crucial role of the Mie resonance spectral sensitivity to temperature, which modifies not only the conversion of the incident light into heat but also Raman scattering efficiency. The developed comprehensive model provides the mechanism for thermal modulation of Raman scattering, shedding light on the photon–phonon interaction physics of resonant material, which is essential for the validation of Raman nanothermometry in resonant silicon structures under a strong laser field.https://doi.org/10.1515/nanoph-2023-0922photothermal effectmie resonancesilicon nanoparticlesraman spectroscopy; raman thermometry
spellingShingle Vikram Mor Pal
Nishida Kentaro
Li Chien-Hsuan
Riabov Daniil
Pashina Olesiya
Tang Yu-Lung
Makarov Sergey V.
Takahara Junichi
Petrov Mihail I.
Chu Shi-Wei
Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructures
Nanophotonics
photothermal effect
mie resonance
silicon nanoparticles
raman spectroscopy; raman thermometry
title Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructures
title_full Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructures
title_fullStr Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructures
title_full_unstemmed Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructures
title_short Photo-thermo-optical modulation of Raman scattering from Mie-resonant silicon nanostructures
title_sort photo thermo optical modulation of raman scattering from mie resonant silicon nanostructures
topic photothermal effect
mie resonance
silicon nanoparticles
raman spectroscopy; raman thermometry
url https://doi.org/10.1515/nanoph-2023-0922
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