Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIx

Perovskites are organic-inorganic compounds with a crystal structure that revolutionize many optoelectronic applications, especially solar cells. The CsPbBr3−xIx, a perovskite, has garnered significant attention due to its tunable band gap and excellent photovoltaic properties. In this theoretical s...

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Main Author: Veysel Çelik
Format: Article
Language:English
Published: Sakarya University 2023-12-01
Series:Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
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Online Access:https://dergipark.org.tr/tr/download/article-file/3034740
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author Veysel Çelik
author_facet Veysel Çelik
author_sort Veysel Çelik
collection DOAJ
description Perovskites are organic-inorganic compounds with a crystal structure that revolutionize many optoelectronic applications, especially solar cells. The CsPbBr3−xIx, a perovskite, has garnered significant attention due to its tunable band gap and excellent photovoltaic properties. In this theoretical study, the structural, electronic, and optical properties of CsPbBr3−xIx are investigated through density functional theory calculations. The calculations reveal that the substitution of Br with I leads to a significant reduction in the band gap of CsPbBr3−xIx, resulting in improved light absorption properties. The obtained data show that the coexistence of Br and I ions in the structure creates an energy level similar to the shallow energy levels caused by doping at the R symmetry point in the band structure.
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id doaj-art-95d389322ec6470a8b47ea83f7743851
institution Kabale University
issn 2147-835X
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publishDate 2023-12-01
publisher Sakarya University
record_format Article
series Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
spelling doaj-art-95d389322ec6470a8b47ea83f77438512024-12-23T08:15:45ZengSakarya UniversitySakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi2147-835X2023-12-012761276128510.16984/saufenbilder.127081428Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIxVeysel Çelik0https://orcid.org/0000-0001-5020-8422Siirt ÜniversitesiPerovskites are organic-inorganic compounds with a crystal structure that revolutionize many optoelectronic applications, especially solar cells. The CsPbBr3−xIx, a perovskite, has garnered significant attention due to its tunable band gap and excellent photovoltaic properties. In this theoretical study, the structural, electronic, and optical properties of CsPbBr3−xIx are investigated through density functional theory calculations. The calculations reveal that the substitution of Br with I leads to a significant reduction in the band gap of CsPbBr3−xIx, resulting in improved light absorption properties. The obtained data show that the coexistence of Br and I ions in the structure creates an energy level similar to the shallow energy levels caused by doping at the R symmetry point in the band structure.https://dergipark.org.tr/tr/download/article-file/3034740tunable band gapperovskitesolar cellscspbbr_(3-x)i_xdft
spellingShingle Veysel Çelik
Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIx
Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
tunable band gap
perovskite
solar cells
cspbbr_(3-x)i_x
dft
title Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIx
title_full Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIx
title_fullStr Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIx
title_full_unstemmed Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIx
title_short Mechanism of Tunable Band Gap of Halide Cubic Perovskite CsPbBr3−xIx
title_sort mechanism of tunable band gap of halide cubic perovskite cspbbr3 xix
topic tunable band gap
perovskite
solar cells
cspbbr_(3-x)i_x
dft
url https://dergipark.org.tr/tr/download/article-file/3034740
work_keys_str_mv AT veyselcelik mechanismoftunablebandgapofhalidecubicperovskitecspbbr3xix