Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous Solutions

Herein, we explain an effective method for the synthesis of halloysite/CoFe 2 O 4 magnetic composites (magnetic halloysite nanotubes or MHNTs) and their use as as adsorbents to effectively remove tetracycline hydrochloride (TC–HCl) from aqueous solutions. The synthesized composites were characterize...

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Main Authors: Weisheng Guan, Xu Wang, Jianming Pan, Junru Lei, Ya Zhou, Chenchen Lu, Yongsheng Yan
Format: Article
Language:English
Published: SAGE Publishing 2012-07-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.30.7.579
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author Weisheng Guan
Xu Wang
Jianming Pan
Junru Lei
Ya Zhou
Chenchen Lu
Yongsheng Yan
author_facet Weisheng Guan
Xu Wang
Jianming Pan
Junru Lei
Ya Zhou
Chenchen Lu
Yongsheng Yan
author_sort Weisheng Guan
collection DOAJ
description Herein, we explain an effective method for the synthesis of halloysite/CoFe 2 O 4 magnetic composites (magnetic halloysite nanotubes or MHNTs) and their use as as adsorbents to effectively remove tetracycline hydrochloride (TC–HCl) from aqueous solutions. The synthesized composites were characterized by the following methods: Fourier transform infrared, X-ray diffraction, transmission electron microscopy, vibrating sample magnetometry and atomic absorption spectrometry. Our study results indicated that MHNTs have strong magnetic (Ms = 34.02 emu/g) and low leakage properties. The adsorption capacities of MHNTs were investigated by performing a series of experiments with different pH, temperatures, initial concentrations and reaction time. The Langmuir isotherm model fitted to equilibrium data better than the Freundlich model. The kinetic properties of the composites were well-described by applying the pseudo-second-order equation. Even after carrying out two repeated experimental cycles, the reusability of the synthesized composites did not obviously degenerate.
format Article
id doaj-art-94f9e09f7a364a5dbf1948e4d3f2179d
institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2012-07-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-94f9e09f7a364a5dbf1948e4d3f2179d2025-01-03T01:19:24ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382012-07-013010.1260/0263-6174.30.7.579Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous SolutionsWeisheng Guan0Xu Wang1Jianming Pan2Junru Lei3Ya Zhou4Chenchen Lu5Yongsheng Yan6 School of Environmental Science and Engineering, Chang'an University, Xi ‘an 710054, P. R. China School of Environmental Science and Engineering, Chang'an University, Xi ‘an 710054, P. R. China School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. China School of Environmental Science and Engineering, Chang'an University, Xi ‘an 710054, P. R. China School of Environmental Science and Engineering, Chang'an University, Xi ‘an 710054, P. R. China School of Environmental Science and Engineering, Chang'an University, Xi ‘an 710054, P. R. China School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. ChinaHerein, we explain an effective method for the synthesis of halloysite/CoFe 2 O 4 magnetic composites (magnetic halloysite nanotubes or MHNTs) and their use as as adsorbents to effectively remove tetracycline hydrochloride (TC–HCl) from aqueous solutions. The synthesized composites were characterized by the following methods: Fourier transform infrared, X-ray diffraction, transmission electron microscopy, vibrating sample magnetometry and atomic absorption spectrometry. Our study results indicated that MHNTs have strong magnetic (Ms = 34.02 emu/g) and low leakage properties. The adsorption capacities of MHNTs were investigated by performing a series of experiments with different pH, temperatures, initial concentrations and reaction time. The Langmuir isotherm model fitted to equilibrium data better than the Freundlich model. The kinetic properties of the composites were well-described by applying the pseudo-second-order equation. Even after carrying out two repeated experimental cycles, the reusability of the synthesized composites did not obviously degenerate.https://doi.org/10.1260/0263-6174.30.7.579
spellingShingle Weisheng Guan
Xu Wang
Jianming Pan
Junru Lei
Ya Zhou
Chenchen Lu
Yongsheng Yan
Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous Solutions
Adsorption Science & Technology
title Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous Solutions
title_full Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous Solutions
title_fullStr Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous Solutions
title_full_unstemmed Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous Solutions
title_short Synthesis of Magnetic Halloysite Composites for the Effective Removal of Tetracycline Hydrochloride from Aqueous Solutions
title_sort synthesis of magnetic halloysite composites for the effective removal of tetracycline hydrochloride from aqueous solutions
url https://doi.org/10.1260/0263-6174.30.7.579
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