Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II)
Bis(triphenylsulfonium) tetrachloridomanganate(II), (C18H15S)2[MnCl4] (I), triphenylsulfonium tetrachloridoferrate(III), (C18H15S)[FeCl4] (II), and bis(triphenylsulfonium) tetrachloridocobaltate(II), (C18H15S)2[CoCl4] (III), crystallize in the monoclinic space groups P21/n [(I) and (III)] and P21/c...
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International Union of Crystallography
2025-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025006668 |
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| author | Waylan Callaway Matthew Elterman Nikita Krasilnikov Gavin Roberts Davis Rutan Ty Spencer Clifford W. Padgett Will E. Lynch |
| author_facet | Waylan Callaway Matthew Elterman Nikita Krasilnikov Gavin Roberts Davis Rutan Ty Spencer Clifford W. Padgett Will E. Lynch |
| author_sort | Waylan Callaway |
| collection | DOAJ |
| description | Bis(triphenylsulfonium) tetrachloridomanganate(II), (C18H15S)2[MnCl4] (I), triphenylsulfonium tetrachloridoferrate(III), (C18H15S)[FeCl4] (II), and bis(triphenylsulfonium) tetrachloridocobaltate(II), (C18H15S)2[CoCl4] (III), crystallize in the monoclinic space groups P21/n [(I) and (III)] and P21/c [(II)]. Compounds (I) and (III) each contain two crystallographically independent triphenylsulfonium (TPS+) cations in the asymmetric unit, whereas (II) has one. In all three compounds, the sulfonium centers adopt distorted trigonal–pyramidal geometries, with S—C bond lengths falling roughly in the 1.78–1.79 Å range and C—S—C angles observed at about 101 to 106°. The [MCl4]n− anions (M = Mn2+, Fe3+, Co2+; n = 2,1,2) adopt slightly distorted tetrahedral geometries, with M—Cl bond lengths in the 2.19–2.38 Å range and Cl—M—Cl angles of approximately 104–113°. Hirshfeld surface analyses shows that H...H and H...C contacts dominate the TPS+ cation environments, whereas H...Cl and short M—S interactions link each [MCl4]n− anion to the surrounding cations. In (I) and (III), inversion-centered π–π stacking further consolidates the crystal packing, while in (II) no π–π interactions are observed. |
| format | Article |
| id | doaj-art-946f9d0f242e449e86d8c32158f8fceb |
| institution | Kabale University |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-946f9d0f242e449e86d8c32158f8fceb2025-08-20T03:44:29ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-08-0181877077510.1107/S2056989025006668ny2014Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II)Waylan Callaway0Matthew Elterman1Nikita Krasilnikov2Gavin Roberts3Davis Rutan4Ty Spencer5Clifford W. Padgett6Will E. Lynch7Center for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USACenter for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USACenter for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USACenter for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USACenter for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USACenter for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USACenter for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USACenter for Advanced Materials Science, Department of Biochemistry, Chemistry and Physics, Georgia Southern University, 11935 Abercorn Street, Savannah, Georgia 31419, USABis(triphenylsulfonium) tetrachloridomanganate(II), (C18H15S)2[MnCl4] (I), triphenylsulfonium tetrachloridoferrate(III), (C18H15S)[FeCl4] (II), and bis(triphenylsulfonium) tetrachloridocobaltate(II), (C18H15S)2[CoCl4] (III), crystallize in the monoclinic space groups P21/n [(I) and (III)] and P21/c [(II)]. Compounds (I) and (III) each contain two crystallographically independent triphenylsulfonium (TPS+) cations in the asymmetric unit, whereas (II) has one. In all three compounds, the sulfonium centers adopt distorted trigonal–pyramidal geometries, with S—C bond lengths falling roughly in the 1.78–1.79 Å range and C—S—C angles observed at about 101 to 106°. The [MCl4]n− anions (M = Mn2+, Fe3+, Co2+; n = 2,1,2) adopt slightly distorted tetrahedral geometries, with M—Cl bond lengths in the 2.19–2.38 Å range and Cl—M—Cl angles of approximately 104–113°. Hirshfeld surface analyses shows that H...H and H...C contacts dominate the TPS+ cation environments, whereas H...Cl and short M—S interactions link each [MCl4]n− anion to the surrounding cations. In (I) and (III), inversion-centered π–π stacking further consolidates the crystal packing, while in (II) no π–π interactions are observed.https://journals.iucr.org/paper?S2056989025006668crystal structuretriphenylsulfonium ionsalts |
| spellingShingle | Waylan Callaway Matthew Elterman Nikita Krasilnikov Gavin Roberts Davis Rutan Ty Spencer Clifford W. Padgett Will E. Lynch Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure triphenylsulfonium ion salts |
| title | Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II) |
| title_full | Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II) |
| title_fullStr | Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II) |
| title_full_unstemmed | Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II) |
| title_short | Syntheses and crystal structures of three triphenylsulfonium salts of manganese(II), iron(III) and cobalt(II) |
| title_sort | syntheses and crystal structures of three triphenylsulfonium salts of manganese ii iron iii and cobalt ii |
| topic | crystal structure triphenylsulfonium ion salts |
| url | https://journals.iucr.org/paper?S2056989025006668 |
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