Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systems

The increasing demand for clean energy and the urgent need to reduce greenhouse gas emissions have led to a growing awareness of the importance of thermal energy storage systems in the diversification of the electric matrix. Sensible heat and latent heat storage are the two main techniques, and the...

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Main Authors: Pablo R. Dellicompagni, Judith Franco, Julia Santapaola, Victoria Flexer, Silvana Flores Larsen
Format: Article
Language:English
Published: Elsevier 2024-10-01
Series:Next Energy
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949821X24000656
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author Pablo R. Dellicompagni
Judith Franco
Julia Santapaola
Victoria Flexer
Silvana Flores Larsen
author_facet Pablo R. Dellicompagni
Judith Franco
Julia Santapaola
Victoria Flexer
Silvana Flores Larsen
author_sort Pablo R. Dellicompagni
collection DOAJ
description The increasing demand for clean energy and the urgent need to reduce greenhouse gas emissions have led to a growing awareness of the importance of thermal energy storage systems in the diversification of the electric matrix. Sensible heat and latent heat storage are the two main techniques, and the choice of storage system depends on the melting point of the substances and the thermal energy required for the processes. This study focused on waste salts obtained from the production process of lithium carbonate. The thermophysical properties of these salts, including specific heat, density, and thermal stability, were examined through various characterization techniques such as X-ray diffraction, chemical analysis, scanning electron microscopy, thermogravimetry, and differential scanning calorimetry. The results revealed promising thermal properties, chemical stability, and physical availability of the waste salts. Additionally, the study explored the potential benefits of reutilizing these waste salts, such as reducing environmental impact, promoting circular economy principles, and creating new market opportunities for commercial products. Overall, this research provides valuable insights into the thermophysical properties of waste salts from lithium carbonate production. The main results are heat capacity in the solid phase (0.767–3.143 J/g°C) and storable thermal energy (114–1153 TWht). These findings contribute to the design and optimization of thermal energy storage systems, highlighting the potential for sustainable and efficient energy storage solutions in the context of global clean energy transitions.
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spelling doaj-art-9462cda01ea74425844d8a94e894e8122024-12-08T06:13:48ZengElsevierNext Energy2949-821X2024-10-015100160Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systemsPablo R. Dellicompagni0Judith Franco1Julia Santapaola2Victoria Flexer3Silvana Flores Larsen4Instituto de Investigaciones en Energía No Convencional (INENCO), 5150 Bolivia Av, Salta 4400, Argentina; Corresponding author.Instituto de Investigaciones en Energía No Convencional (INENCO), 5150 Bolivia Av, Salta 4400, ArgentinaFacultad de Ingeniería – Universidad Nacional de Jujuy, 10 Ítalo Palanca St., San Salvador de Jujuy 4600, ArgentinaCentro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy (CIDMEJu), Juan A. Rojas esq. San Martín, Palpalá, Jujuy 4612, ArgentinaInstituto de Investigaciones en Energía No Convencional (INENCO), 5150 Bolivia Av, Salta 4400, ArgentinaThe increasing demand for clean energy and the urgent need to reduce greenhouse gas emissions have led to a growing awareness of the importance of thermal energy storage systems in the diversification of the electric matrix. Sensible heat and latent heat storage are the two main techniques, and the choice of storage system depends on the melting point of the substances and the thermal energy required for the processes. This study focused on waste salts obtained from the production process of lithium carbonate. The thermophysical properties of these salts, including specific heat, density, and thermal stability, were examined through various characterization techniques such as X-ray diffraction, chemical analysis, scanning electron microscopy, thermogravimetry, and differential scanning calorimetry. The results revealed promising thermal properties, chemical stability, and physical availability of the waste salts. Additionally, the study explored the potential benefits of reutilizing these waste salts, such as reducing environmental impact, promoting circular economy principles, and creating new market opportunities for commercial products. Overall, this research provides valuable insights into the thermophysical properties of waste salts from lithium carbonate production. The main results are heat capacity in the solid phase (0.767–3.143 J/g°C) and storable thermal energy (114–1153 TWht). These findings contribute to the design and optimization of thermal energy storage systems, highlighting the potential for sustainable and efficient energy storage solutions in the context of global clean energy transitions.http://www.sciencedirect.com/science/article/pii/S2949821X24000656Thermal energy storageWaste saltsLithium carbonate productionSustainable energyCircular economy
spellingShingle Pablo R. Dellicompagni
Judith Franco
Julia Santapaola
Victoria Flexer
Silvana Flores Larsen
Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systems
Next Energy
Thermal energy storage
Waste salts
Lithium carbonate production
Sustainable energy
Circular economy
title Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systems
title_full Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systems
title_fullStr Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systems
title_full_unstemmed Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systems
title_short Analysis and characterization of residual salts from lithium carbonate industry: Their potential uses for thermal storage systems
title_sort analysis and characterization of residual salts from lithium carbonate industry their potential uses for thermal storage systems
topic Thermal energy storage
Waste salts
Lithium carbonate production
Sustainable energy
Circular economy
url http://www.sciencedirect.com/science/article/pii/S2949821X24000656
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