Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-Diol
We studied the porous structures and thermal properties of spherical shaped cross-linked polymers. These novel polymeric microspheres were synthesized by emulsion–suspension polymerization of aromatic tetrafunctional monomer [2,7-(2-hydroxy-3-methacryloyloxypropoxy)naphthalene (2,7-NAF.DM)] with typ...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2015-08-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.33.6-8.531 |
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| author | Beata Podkościelna Mateusz Lutomski |
| author_facet | Beata Podkościelna Mateusz Lutomski |
| author_sort | Beata Podkościelna |
| collection | DOAJ |
| description | We studied the porous structures and thermal properties of spherical shaped cross-linked polymers. These novel polymeric microspheres were synthesized by emulsion–suspension polymerization of aromatic tetrafunctional monomer [2,7-(2-hydroxy-3-methacryloyloxypropoxy)naphthalene (2,7-NAF.DM)] with typical, commercially available monomers (styrene, divinylbenze ne and methyl methacrylate). The monomer 2,7-NAF.DM was obtained in the two-step process. In the first step, the epoxy resin was synthesized by treating epichlorohydrin with naphthalene-2,7-diol. In the second step, the obtained epoxy derivatives were subjected to esterification with methacrylic acid. Porous structures of the obtained microspheres in the dry state were studied by nitrogen adsorption–desorption measurements. Thermal stabilities and degradation behaviours of the obtained co-polymers were characterized by differential scanning calorimetry and thermogravimetric/derivative thermogravimetry analyses. In addition, we also present the photoluminescent properties of these microspheres. |
| format | Article |
| id | doaj-art-9423dfe645a54c098108f81e63d64df6 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2015-08-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-9423dfe645a54c098108f81e63d64df62025-01-03T01:19:32ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382015-08-013310.1260/0263-6174.33.6-8.531Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-DiolBeata PodkościelnaMateusz LutomskiWe studied the porous structures and thermal properties of spherical shaped cross-linked polymers. These novel polymeric microspheres were synthesized by emulsion–suspension polymerization of aromatic tetrafunctional monomer [2,7-(2-hydroxy-3-methacryloyloxypropoxy)naphthalene (2,7-NAF.DM)] with typical, commercially available monomers (styrene, divinylbenze ne and methyl methacrylate). The monomer 2,7-NAF.DM was obtained in the two-step process. In the first step, the epoxy resin was synthesized by treating epichlorohydrin with naphthalene-2,7-diol. In the second step, the obtained epoxy derivatives were subjected to esterification with methacrylic acid. Porous structures of the obtained microspheres in the dry state were studied by nitrogen adsorption–desorption measurements. Thermal stabilities and degradation behaviours of the obtained co-polymers were characterized by differential scanning calorimetry and thermogravimetric/derivative thermogravimetry analyses. In addition, we also present the photoluminescent properties of these microspheres.https://doi.org/10.1260/0263-6174.33.6-8.531 |
| spellingShingle | Beata Podkościelna Mateusz Lutomski Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-Diol Adsorption Science & Technology |
| title | Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-Diol |
| title_full | Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-Diol |
| title_fullStr | Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-Diol |
| title_full_unstemmed | Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-Diol |
| title_short | Study of Porous Structures and Thermal Properties of Luminescent Polymeric Microspheres Derivatives of Naphthalene-2,7-Diol |
| title_sort | study of porous structures and thermal properties of luminescent polymeric microspheres derivatives of naphthalene 2 7 diol |
| url | https://doi.org/10.1260/0263-6174.33.6-8.531 |
| work_keys_str_mv | AT beatapodkoscielna studyofporousstructuresandthermalpropertiesofluminescentpolymericmicrospheresderivativesofnaphthalene27diol AT mateuszlutomski studyofporousstructuresandthermalpropertiesofluminescentpolymericmicrospheresderivativesofnaphthalene27diol |