Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and Sputtering

Hexamethyldisiloxane (HMDSO) is an organosilicon compound with a modifiable bandgap, depending on the deposition conditions. This material has many unique properties due to its stability, low toxicity, and strong adhesion, making it useful as a protective barrier against corrosion, moisture, and oxi...

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Main Authors: Ahmed Kotbi, Michael Lejeune, Pierre Barroy, Ilham Hamdi Alaoui, Wiaam El Hakim, Frederic Lamarque, Andreas Zeinert
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Photonics
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Online Access:https://www.mdpi.com/2304-6732/11/11/1096
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author Ahmed Kotbi
Michael Lejeune
Pierre Barroy
Ilham Hamdi Alaoui
Wiaam El Hakim
Frederic Lamarque
Andreas Zeinert
author_facet Ahmed Kotbi
Michael Lejeune
Pierre Barroy
Ilham Hamdi Alaoui
Wiaam El Hakim
Frederic Lamarque
Andreas Zeinert
author_sort Ahmed Kotbi
collection DOAJ
description Hexamethyldisiloxane (HMDSO) is an organosilicon compound with a modifiable bandgap, depending on the deposition conditions. This material has many unique properties due to its stability, low toxicity, and strong adhesion, making it useful as a protective barrier against corrosion, moisture, and oxidation. In this work, HMDSO films were deposited on glass substrates by the Plasma Enhanced Chemical Vapor Deposition (PECVD) technique at different deposition times. The optical properties of HMDSO films, such as dielectric permittivity, refractive index, extinction and absorption coefficients, and band gap energy, are inferred from transmission and reflection spectra. As the deposition time increased, the real part of the dielectric constant, the refractive index, and the bandgap energy showed a decrease, dropping from 4.24 to 3.40, from 2.06 to 1.84, and from 2.85 eV to 2.03 eV, respectively. The latter result is determined using classical models such as the O’Leary-Johnson-Lim (‘OJL’) interband transition and the harmonic oscillator model. HMDSO and Silver are used in this study for the fabrication of optical filters using two types of structures, a multiple cavity metal–dielectric (MCMD) and the Fabry–Perot structure. The silver layers are deposited by a sputtering process. The MCMD optical filter shows a higher transmittance of about 30%, but a wide range of wavelengths is transmitted. In contrast, the Fabry–Perot filter showed high contrast but a lower transmittance of about 20%.
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spelling doaj-art-93f99b669c2d4a9c804c29a2ce4334fe2024-11-26T18:18:35ZengMDPI AGPhotonics2304-67322024-11-011111109610.3390/photonics11111096Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and SputteringAhmed Kotbi0Michael Lejeune1Pierre Barroy2Ilham Hamdi Alaoui3Wiaam El Hakim4Frederic Lamarque5Andreas Zeinert6Laboratory of Condensed Matter Physics, University of Picardie Jules Verne, 33 Rue Saint Leu, 80039 Amiens, FranceLaboratory of Condensed Matter Physics, University of Picardie Jules Verne, 33 Rue Saint Leu, 80039 Amiens, FranceLaboratory of Condensed Matter Physics, University of Picardie Jules Verne, 33 Rue Saint Leu, 80039 Amiens, FranceLaboratory of Condensed Matter Physics, University of Picardie Jules Verne, 33 Rue Saint Leu, 80039 Amiens, FranceMechanical Engineering Department, Université de Technologie de Compiègne, 60203 Compiègne Cedex, FranceMechanical Engineering Department, Université de Technologie de Compiègne, 60203 Compiègne Cedex, FranceLaboratory of Condensed Matter Physics, University of Picardie Jules Verne, 33 Rue Saint Leu, 80039 Amiens, FranceHexamethyldisiloxane (HMDSO) is an organosilicon compound with a modifiable bandgap, depending on the deposition conditions. This material has many unique properties due to its stability, low toxicity, and strong adhesion, making it useful as a protective barrier against corrosion, moisture, and oxidation. In this work, HMDSO films were deposited on glass substrates by the Plasma Enhanced Chemical Vapor Deposition (PECVD) technique at different deposition times. The optical properties of HMDSO films, such as dielectric permittivity, refractive index, extinction and absorption coefficients, and band gap energy, are inferred from transmission and reflection spectra. As the deposition time increased, the real part of the dielectric constant, the refractive index, and the bandgap energy showed a decrease, dropping from 4.24 to 3.40, from 2.06 to 1.84, and from 2.85 eV to 2.03 eV, respectively. The latter result is determined using classical models such as the O’Leary-Johnson-Lim (‘OJL’) interband transition and the harmonic oscillator model. HMDSO and Silver are used in this study for the fabrication of optical filters using two types of structures, a multiple cavity metal–dielectric (MCMD) and the Fabry–Perot structure. The silver layers are deposited by a sputtering process. The MCMD optical filter shows a higher transmittance of about 30%, but a wide range of wavelengths is transmitted. In contrast, the Fabry–Perot filter showed high contrast but a lower transmittance of about 20%.https://www.mdpi.com/2304-6732/11/11/1096thin filmsPECVDsputteringHMDSOsilveroptical properties
spellingShingle Ahmed Kotbi
Michael Lejeune
Pierre Barroy
Ilham Hamdi Alaoui
Wiaam El Hakim
Frederic Lamarque
Andreas Zeinert
Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and Sputtering
Photonics
thin films
PECVD
sputtering
HMDSO
silver
optical properties
title Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and Sputtering
title_full Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and Sputtering
title_fullStr Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and Sputtering
title_full_unstemmed Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and Sputtering
title_short Low-Cost Optical Filters Based on SiO<sub>x</sub>C<sub>y</sub>:H and Ag Thin Films Fabricated by Plasma Enhanced Chemical Vapor Deposition and Sputtering
title_sort low cost optical filters based on sio sub x sub c sub y sub h and ag thin films fabricated by plasma enhanced chemical vapor deposition and sputtering
topic thin films
PECVD
sputtering
HMDSO
silver
optical properties
url https://www.mdpi.com/2304-6732/11/11/1096
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