Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protection

This study explores an innovative method to enhance the anti-tarnish and mechanical properties of gold-coated silver sheets, targeting decorative applications through the TiO2 film coatings. The research focuses on gold films with a thickness of approximately 100 nm, and TiO2 films ranging from 10 t...

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Main Authors: Sarocha Khanwaeo, Pisan Srirach, Pichet Limsuwan, Aparporn Sakulkalavek, Rachsak Sakdanuphab
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Results in Physics
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Online Access:http://www.sciencedirect.com/science/article/pii/S2211379724007216
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author Sarocha Khanwaeo
Pisan Srirach
Pichet Limsuwan
Aparporn Sakulkalavek
Rachsak Sakdanuphab
author_facet Sarocha Khanwaeo
Pisan Srirach
Pichet Limsuwan
Aparporn Sakulkalavek
Rachsak Sakdanuphab
author_sort Sarocha Khanwaeo
collection DOAJ
description This study explores an innovative method to enhance the anti-tarnish and mechanical properties of gold-coated silver sheets, targeting decorative applications through the TiO2 film coatings. The research focuses on gold films with a thickness of approximately 100 nm, and TiO2 films ranging from 10 to 31 nm. It was observed that the color of the multilayer coatings exhibited significant sensitivity to variations in thickness, indicating that a TiO2 coating with a thickness around 20 nm could be optimally applied to the gold film, maintaining an acceptable ΔE value. X-ray photoelectron spectroscopy analysis demonstrated the TiO2 film’s potential to inhibit the formation of Ag2S on the surface, thereby enhancing tarnish resistance. Furthermore, the application of a 20 nm TiO2 layer reduced the friction coefficient from 0.28 to 0.24 for gold-coated silver. Durability tests involving 1,000 abrasion cycles revealed that the gold film without TiO2 protection experienced delamination, with only about 57 % of the coated area remaining intact. In contrast, the samples protected with a TiO2 layer retained approximately 90 % of the coating, underscoring the effectiveness of TiO2 in preserving the structural integrity and appearance of the gold-coated silver sheets.
format Article
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institution Kabale University
issn 2211-3797
language English
publishDate 2024-12-01
publisher Elsevier
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series Results in Physics
spelling doaj-art-91c76e5f155f480fa4ed8792df2da7332024-12-19T10:53:42ZengElsevierResults in Physics2211-37972024-12-0167108036Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protectionSarocha Khanwaeo0Pisan Srirach1Pichet Limsuwan2Aparporn Sakulkalavek3Rachsak Sakdanuphab4School of Science, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Rd. Ladkrabang, Bangkok 10520, ThailandSchool of Science, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Rd. Ladkrabang, Bangkok 10520, Thailand; Electronic and Optoelectronic Device Research Unit, School of Science, King Mongkut’s Institute of Technology Ladkrabang, Bangkok 10520, ThailandSchool of Science, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Rd. Ladkrabang, Bangkok 10520, ThailandSchool of Science, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Rd. Ladkrabang, Bangkok 10520, Thailand; Electronic and Optoelectronic Device Research Unit, School of Science, King Mongkut’s Institute of Technology Ladkrabang, Bangkok 10520, ThailandElectronic and Optoelectronic Device Research Unit, School of Science, King Mongkut’s Institute of Technology Ladkrabang, Bangkok 10520, Thailand; College of Advanced Manufacturing Innovation, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung Rd. Ladkrabang, Bangkok 10520, Thailand; Corresponding author at: College of Advanced Manufacturing Innovation, King Mongkut's Institute of Technology Ladkrabang, Chalongkrung Rd. Ladkrabang, Bangkok 10520 Thailand.This study explores an innovative method to enhance the anti-tarnish and mechanical properties of gold-coated silver sheets, targeting decorative applications through the TiO2 film coatings. The research focuses on gold films with a thickness of approximately 100 nm, and TiO2 films ranging from 10 to 31 nm. It was observed that the color of the multilayer coatings exhibited significant sensitivity to variations in thickness, indicating that a TiO2 coating with a thickness around 20 nm could be optimally applied to the gold film, maintaining an acceptable ΔE value. X-ray photoelectron spectroscopy analysis demonstrated the TiO2 film’s potential to inhibit the formation of Ag2S on the surface, thereby enhancing tarnish resistance. Furthermore, the application of a 20 nm TiO2 layer reduced the friction coefficient from 0.28 to 0.24 for gold-coated silver. Durability tests involving 1,000 abrasion cycles revealed that the gold film without TiO2 protection experienced delamination, with only about 57 % of the coated area remaining intact. In contrast, the samples protected with a TiO2 layer retained approximately 90 % of the coating, underscoring the effectiveness of TiO2 in preserving the structural integrity and appearance of the gold-coated silver sheets.http://www.sciencedirect.com/science/article/pii/S2211379724007216Gold coatingSilverAnti-tarnishTiO2 film
spellingShingle Sarocha Khanwaeo
Pisan Srirach
Pichet Limsuwan
Aparporn Sakulkalavek
Rachsak Sakdanuphab
Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protection
Results in Physics
Gold coating
Silver
Anti-tarnish
TiO2 film
title Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protection
title_full Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protection
title_fullStr Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protection
title_full_unstemmed Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protection
title_short Enhancing the anti-tarnish and mechanical properties of gold-coated silver sheets for decorative applications using TiO2 film protection
title_sort enhancing the anti tarnish and mechanical properties of gold coated silver sheets for decorative applications using tio2 film protection
topic Gold coating
Silver
Anti-tarnish
TiO2 film
url http://www.sciencedirect.com/science/article/pii/S2211379724007216
work_keys_str_mv AT sarochakhanwaeo enhancingtheantitarnishandmechanicalpropertiesofgoldcoatedsilversheetsfordecorativeapplicationsusingtio2filmprotection
AT pisansrirach enhancingtheantitarnishandmechanicalpropertiesofgoldcoatedsilversheetsfordecorativeapplicationsusingtio2filmprotection
AT pichetlimsuwan enhancingtheantitarnishandmechanicalpropertiesofgoldcoatedsilversheetsfordecorativeapplicationsusingtio2filmprotection
AT aparpornsakulkalavek enhancingtheantitarnishandmechanicalpropertiesofgoldcoatedsilversheetsfordecorativeapplicationsusingtio2filmprotection
AT rachsaksakdanuphab enhancingtheantitarnishandmechanicalpropertiesofgoldcoatedsilversheetsfordecorativeapplicationsusingtio2filmprotection