The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-Perchlorate
In cold methanol, energetic ionic liquid 1-n-propyl-3-vinyl-imidazol-1-ium perchlorate, <b>1</b>, crystallizes in the presence of excess Ba(ClO<sub>4</sub>)<sub>2</sub>, <b>2</b>, into tetrakis 1-propyl-3-vinyl-imidazol-1-ium·barium hexa-perchlorate, &...
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MDPI AG
2024-10-01
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| author | Yuval Zertal Natalia Fridman Levi Gottlieb Yoav Eichen |
| author_facet | Yuval Zertal Natalia Fridman Levi Gottlieb Yoav Eichen |
| author_sort | Yuval Zertal |
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| description | In cold methanol, energetic ionic liquid 1-n-propyl-3-vinyl-imidazol-1-ium perchlorate, <b>1</b>, crystallizes in the presence of excess Ba(ClO<sub>4</sub>)<sub>2</sub>, <b>2</b>, into tetrakis 1-propyl-3-vinyl-imidazol-1-ium·barium hexa-perchlorate, <b>3</b>. Crystals of <b>3</b>, with molecular formula (C<sub>8</sub>H<sub>13</sub>N<sub>2</sub>)<sub>4</sub>·BaCl<sub>6</sub>O<sub>24</sub>, are colorless and monoclinic, with space group P2<sub>1</sub>/c. The crystal structure is characterized by a dodecahedral coordination around the barium atom, with each perchlorate chelating Ba<sup>2+</sup> in a κ<sup>2</sup>O,O’ fashion, and the Ba(ClO<sub>4</sub>)<sub>6</sub><sup>4−</sup> anion is surrounded by four imidazolium cations. |
| format | Article |
| id | doaj-art-908b460c3f5b42a7b3cc4194b10ae45e |
| institution | Kabale University |
| issn | 1420-3049 |
| language | English |
| publishDate | 2024-10-01 |
| publisher | MDPI AG |
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| series | Molecules |
| spelling | doaj-art-908b460c3f5b42a7b3cc4194b10ae45e2024-11-08T14:38:02ZengMDPI AGMolecules1420-30492024-10-012921501010.3390/molecules29215010The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-PerchlorateYuval Zertal0Natalia Fridman1Levi Gottlieb2Yoav Eichen3Schulich Faculty of Chemistry, Technion−Israel Institute of Technology Technion City, Haifa 3200003, IsraelSchulich Faculty of Chemistry, Technion−Israel Institute of Technology Technion City, Haifa 3200003, IsraelRAFAEL, Advanced Defense Systems Ltd., POB 2250, Haifa 3102101, IsraelSchulich Faculty of Chemistry, Technion−Israel Institute of Technology Technion City, Haifa 3200003, IsraelIn cold methanol, energetic ionic liquid 1-n-propyl-3-vinyl-imidazol-1-ium perchlorate, <b>1</b>, crystallizes in the presence of excess Ba(ClO<sub>4</sub>)<sub>2</sub>, <b>2</b>, into tetrakis 1-propyl-3-vinyl-imidazol-1-ium·barium hexa-perchlorate, <b>3</b>. Crystals of <b>3</b>, with molecular formula (C<sub>8</sub>H<sub>13</sub>N<sub>2</sub>)<sub>4</sub>·BaCl<sub>6</sub>O<sub>24</sub>, are colorless and monoclinic, with space group P2<sub>1</sub>/c. The crystal structure is characterized by a dodecahedral coordination around the barium atom, with each perchlorate chelating Ba<sup>2+</sup> in a κ<sup>2</sup>O,O’ fashion, and the Ba(ClO<sub>4</sub>)<sub>6</sub><sup>4−</sup> anion is surrounded by four imidazolium cations.https://www.mdpi.com/1420-3049/29/21/5010energetic materialsionic liquidshigh coordination number |
| spellingShingle | Yuval Zertal Natalia Fridman Levi Gottlieb Yoav Eichen The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-Perchlorate Molecules energetic materials ionic liquids high coordination number |
| title | The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-Perchlorate |
| title_full | The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-Perchlorate |
| title_fullStr | The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-Perchlorate |
| title_full_unstemmed | The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-Perchlorate |
| title_short | The Crystal Structure of Dodecahedral Ba<sup>2+</sup> Hexa-Perchlorate Complex Tetrakis 1-N-Propyl-3-vinyl-imidazol-1-ium·Barium Hexa-Perchlorate |
| title_sort | crystal structure of dodecahedral ba sup 2 sup hexa perchlorate complex tetrakis 1 n propyl 3 vinyl imidazol 1 ium·barium hexa perchlorate |
| topic | energetic materials ionic liquids high coordination number |
| url | https://www.mdpi.com/1420-3049/29/21/5010 |
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