Use of Classical Adsorption Theory to Understand the Dynamic Filtration of Volatile Toxicants in Cigarette Smoke by Active Carbons
The ability of two very different active carbons, a polymer-derived carbon (with ultramicropores and supermicropores, and a large volume of “transport” pores) and a coconut shell-derived carbon (predominantly ultramicroporous), to reduce the levels of volatile toxicants in cigarette smoke has been m...
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Main Authors: | , , , , , , , |
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Format: | Article |
Language: | English |
Published: |
SAGE Publishing
2011-02-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/0263-6174.29.2.117 |
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Summary: | The ability of two very different active carbons, a polymer-derived carbon (with ultramicropores and supermicropores, and a large volume of “transport” pores) and a coconut shell-derived carbon (predominantly ultramicroporous), to reduce the levels of volatile toxicants in cigarette smoke has been measured and compared. The polymer-derived carbon was found to be approximately twice as effective in removing the majority of measured smoke vapour-phase toxicants compared to the coconut shell-derived carbon in three different cigarette formats and with two different smoking regimes. Single-component dynamic breakthrough experiments were conducted with benzene, acrylonitrile and 2-butanone at 298 K for beds of each carbon under dry (0% RH) and wet (60% RH) conditions. Longer breakthrough times were found with the polymer-derived carbon, and breakthrough times recorded under wet conditions were found to be up to 20% shorter than those obtained under dry conditions. Correlations between micropore volume, dynamic adsorption volume and filter bed breakthrough time have been demonstrated. |
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ISSN: | 0263-6174 2048-4038 |