Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten Salt

Abstract Beryllium is a crucial strategic metal characterized by its exceptional properties, which has facilitated its extensive application across various high‐tech industries. However, despite advancements in refining techniques, the purification of industrial‐grade beryllium scrap remains insuffi...

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Main Authors: Yuzhen Chen, Shaolong Li, Zepeng Lv, Wen Luo, Peng Qiao, Dongxin Wang, Jilin He, Jianxun Song
Format: Article
Language:English
Published: Wiley-VCH 2025-05-01
Series:ChemElectroChem
Subjects:
Online Access:https://doi.org/10.1002/celc.202400710
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author Yuzhen Chen
Shaolong Li
Zepeng Lv
Wen Luo
Peng Qiao
Dongxin Wang
Jilin He
Jianxun Song
author_facet Yuzhen Chen
Shaolong Li
Zepeng Lv
Wen Luo
Peng Qiao
Dongxin Wang
Jilin He
Jianxun Song
author_sort Yuzhen Chen
collection DOAJ
description Abstract Beryllium is a crucial strategic metal characterized by its exceptional properties, which has facilitated its extensive application across various high‐tech industries. However, despite advancements in refining techniques, the purification of industrial‐grade beryllium scrap remains insufficiently explored. This gap has led to challenges such as resource waste and environmental concerns. This study aims to bridge this gap by investigating the electrolytic refining process of beryllium scrap through molten salt electrolysis. Linear sweep voltammetry (LSV), cyclic voltammetry (CV), and square wave voltammetry (SWV) are employed to analyze both anodic dissolution and cathodic reduction behaviors. The study demonstrates that beryllium undergoes a single‐step, two‐electron transfer reduction process, while impurity elements are separated as anodic slime. The effects of current density on beryllium deposition morphology and removal efficiency have been further investigated. This research provides a novel approach to beryllium scrap purification, contributing significantly to the optimization of the beryllium supply chain and offering valuable insights into sustainable metal refinement practices.
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institution Kabale University
issn 2196-0216
language English
publishDate 2025-05-01
publisher Wiley-VCH
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series ChemElectroChem
spelling doaj-art-8e8d24e948f5486f8171045e29eda75c2025-08-20T03:46:38ZengWiley-VCHChemElectroChem2196-02162025-05-011211n/an/a10.1002/celc.202400710Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten SaltYuzhen Chen0Shaolong Li1Zepeng Lv2Wen Luo3Peng Qiao4Dongxin Wang5Jilin He6Jianxun Song7School of Material Science and Engineering Zhengzhou University 450001 Zhengzhou Henan PR ChinaSchool of Material Science and Engineering Zhengzhou University 450001 Zhengzhou Henan PR ChinaSchool of Material Science and Engineering Zhengzhou University 450001 Zhengzhou Henan PR ChinaState Key Laboratory of Special Rare Metal Materials Northwest Rare Metal Materials Research Institute Ningxia Co., Ltd 753000 Shizuishan ChinaState Key Laboratory of Special Rare Metal Materials Northwest Rare Metal Materials Research Institute Ningxia Co., Ltd 753000 Shizuishan ChinaState Key Laboratory of Special Rare Metal Materials Northwest Rare Metal Materials Research Institute Ningxia Co., Ltd 753000 Shizuishan ChinaSchool of Material Science and Engineering Zhengzhou University 450001 Zhengzhou Henan PR ChinaSchool of Material Science and Engineering Zhengzhou University 450001 Zhengzhou Henan PR ChinaAbstract Beryllium is a crucial strategic metal characterized by its exceptional properties, which has facilitated its extensive application across various high‐tech industries. However, despite advancements in refining techniques, the purification of industrial‐grade beryllium scrap remains insufficiently explored. This gap has led to challenges such as resource waste and environmental concerns. This study aims to bridge this gap by investigating the electrolytic refining process of beryllium scrap through molten salt electrolysis. Linear sweep voltammetry (LSV), cyclic voltammetry (CV), and square wave voltammetry (SWV) are employed to analyze both anodic dissolution and cathodic reduction behaviors. The study demonstrates that beryllium undergoes a single‐step, two‐electron transfer reduction process, while impurity elements are separated as anodic slime. The effects of current density on beryllium deposition morphology and removal efficiency have been further investigated. This research provides a novel approach to beryllium scrap purification, contributing significantly to the optimization of the beryllium supply chain and offering valuable insights into sustainable metal refinement practices.https://doi.org/10.1002/celc.202400710beryllium scrapmolten saltelectrochemical behaviorselectrochemical refining
spellingShingle Yuzhen Chen
Shaolong Li
Zepeng Lv
Wen Luo
Peng Qiao
Dongxin Wang
Jilin He
Jianxun Song
Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten Salt
ChemElectroChem
beryllium scrap
molten salt
electrochemical behaviors
electrochemical refining
title Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten Salt
title_full Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten Salt
title_fullStr Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten Salt
title_full_unstemmed Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten Salt
title_short Electrochemical Behavior and Reclamation of Beryllium Scrap in Molten Salt
title_sort electrochemical behavior and reclamation of beryllium scrap in molten salt
topic beryllium scrap
molten salt
electrochemical behaviors
electrochemical refining
url https://doi.org/10.1002/celc.202400710
work_keys_str_mv AT yuzhenchen electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt
AT shaolongli electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt
AT zepenglv electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt
AT wenluo electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt
AT pengqiao electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt
AT dongxinwang electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt
AT jilinhe electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt
AT jianxunsong electrochemicalbehaviorandreclamationofberylliumscrapinmoltensalt