Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches

In metal hydride beds (MHBs), reaction heat transfer often limits the dynamic performance. Heat transfer within the MHB usually involves solid and gas phases. To account for both, an effective thermal conductivity (ETC) is defined. Measuring and predicting the ETC of metal hydride beds is of primary...

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Main Authors: Gabriele Scarpati, Julián A. Puszkiel, Jan Warfsmann, Fahim Karimi, Elio Jannelli, Claudio Pistidda, Thomas Klassen, Julian Jepsen
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/18/1/194
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author Gabriele Scarpati
Julián A. Puszkiel
Jan Warfsmann
Fahim Karimi
Elio Jannelli
Claudio Pistidda
Thomas Klassen
Julian Jepsen
author_facet Gabriele Scarpati
Julián A. Puszkiel
Jan Warfsmann
Fahim Karimi
Elio Jannelli
Claudio Pistidda
Thomas Klassen
Julian Jepsen
author_sort Gabriele Scarpati
collection DOAJ
description In metal hydride beds (MHBs), reaction heat transfer often limits the dynamic performance. Heat transfer within the MHB usually involves solid and gas phases. To account for both, an effective thermal conductivity (ETC) is defined. Measuring and predicting the ETC of metal hydride beds is of primary importance when designing hydride-based systems for high dynamics. This review paper presents an integral overview of the experimental and modeling approaches to characterize the ETC in MHBs. The most relevant methods for measuring the ETC of metal hydride beds are described, and the results and scopes are shown. A comprehensive description of the models applied to calculate the ETC of the MHBs under different conditions is developed. Moreover, the effects of operation parameters such as P, T, and composition on the ETC of the presented models are analyzed. Finally, a summary and conclusions about experimental techniques, a historical overview with a classification of the ETC models, a discussion about the needed parameters, and a comparison between ETC experimental and calculated results are provided.
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series Energies
spelling doaj-art-8e2a49b1b3fe4bed8d67afc34fcab4f02025-01-10T13:17:23ZengMDPI AGEnergies1996-10732025-01-0118119410.3390/en18010194Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling ApproachesGabriele Scarpati0Julián A. Puszkiel1Jan Warfsmann2Fahim Karimi3Elio Jannelli4Claudio Pistidda5Thomas Klassen6Julian Jepsen7Department of Engineering, University of Naples “Parthenope”, 80143 Naples, ItalyHelmholtz-Zentrum Hereon, Max-Planck-Straße 1, 21502 Geesthacht, GermanyHelmholtz-Zentrum Hereon, Max-Planck-Straße 1, 21502 Geesthacht, GermanyHelmholtz-Zentrum Hereon, Max-Planck-Straße 1, 21502 Geesthacht, GermanyDepartment of Engineering, University of Naples “Parthenope”, 80143 Naples, ItalyHelmholtz-Zentrum Hereon, Max-Planck-Straße 1, 21502 Geesthacht, GermanyHelmholtz-Zentrum Hereon, Max-Planck-Straße 1, 21502 Geesthacht, GermanyHelmholtz-Zentrum Hereon, Max-Planck-Straße 1, 21502 Geesthacht, GermanyIn metal hydride beds (MHBs), reaction heat transfer often limits the dynamic performance. Heat transfer within the MHB usually involves solid and gas phases. To account for both, an effective thermal conductivity (ETC) is defined. Measuring and predicting the ETC of metal hydride beds is of primary importance when designing hydride-based systems for high dynamics. This review paper presents an integral overview of the experimental and modeling approaches to characterize the ETC in MHBs. The most relevant methods for measuring the ETC of metal hydride beds are described, and the results and scopes are shown. A comprehensive description of the models applied to calculate the ETC of the MHBs under different conditions is developed. Moreover, the effects of operation parameters such as P, T, and composition on the ETC of the presented models are analyzed. Finally, a summary and conclusions about experimental techniques, a historical overview with a classification of the ETC models, a discussion about the needed parameters, and a comparison between ETC experimental and calculated results are provided.https://www.mdpi.com/1996-1073/18/1/194hydrideseffective thermal conductivitymodelingexperimentalhydrogen
spellingShingle Gabriele Scarpati
Julián A. Puszkiel
Jan Warfsmann
Fahim Karimi
Elio Jannelli
Claudio Pistidda
Thomas Klassen
Julian Jepsen
Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches
Energies
hydrides
effective thermal conductivity
modeling
experimental
hydrogen
title Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches
title_full Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches
title_fullStr Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches
title_full_unstemmed Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches
title_short Comprehensive Overview of the Effective Thermal Conductivity for Hydride Materials: Experimental and Modeling Approaches
title_sort comprehensive overview of the effective thermal conductivity for hydride materials experimental and modeling approaches
topic hydrides
effective thermal conductivity
modeling
experimental
hydrogen
url https://www.mdpi.com/1996-1073/18/1/194
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