Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative Study
In this study, the degradation of azo-dye acid orange 10 has been investigated using Polyvinylpyrrolidone and Brij-35 stabilized iridium oxide nanoclusters as catalysts. Simple chemical reduction method was used to synthesize the above-mentioned nanoclusters. The characteristics of the nanocatalysts...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Iranian Environmental Mutagen Society
2023-06-01
|
| Series: | Journal of Water and Environmental Nanotechnology |
| Subjects: | |
| Online Access: | https://www.jwent.net/article_705279_2c15be35f3dc8bfa168bf89e8406b5a1.pdf |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841545213991976960 |
|---|---|
| author | Rajni Lasyal Shakunj Rajput |
| author_facet | Rajni Lasyal Shakunj Rajput |
| author_sort | Rajni Lasyal |
| collection | DOAJ |
| description | In this study, the degradation of azo-dye acid orange 10 has been investigated using Polyvinylpyrrolidone and Brij-35 stabilized iridium oxide nanoclusters as catalysts. Simple chemical reduction method was used to synthesize the above-mentioned nanoclusters. The characteristics of the nanocatalysts were determined by UV-visible spectrophotometer, TEM and XRD. The kinetic study has been carried out at λmax of reaction mixture i.e. 479 nm spectrophotometrically. The degradation follows first order kinetics with respect to oxidant and catalyst concentration while order is one at lower substrate concentration tending towards zero at higher concentration. The degradation kinetics has been supported by the derived rate law. The results showed that Polyvinylpyrrolidone stabilized iridium oxide nanoclusters outperformed Brij-35 stabilized iridium oxide nanoclusters, exhibiting the fastest degradation rate. The progress of the degradation process was monitored by UV-vis spectroscopy. Using Polyvinylpyrrolidone stabilized iridium oxide nanoclusters as a catalyst is a very promising approach for the remediation of acid orange 10 due to the fast degradation rate and high degradation efficiency. In addition, Polyvinylpyrrolidone stabilized iridium oxide nanoclusters can be easily recovered and recycled for three consecutive cycles. It can be inferred from this study that catalytic oxidation methods are active and environment-friendly for the remediation of dyes. |
| format | Article |
| id | doaj-art-8db4e7ff55d344908756e3ecba0b1d2f |
| institution | Kabale University |
| issn | 2476-7204 2476-6615 |
| language | English |
| publishDate | 2023-06-01 |
| publisher | Iranian Environmental Mutagen Society |
| record_format | Article |
| series | Journal of Water and Environmental Nanotechnology |
| spelling | doaj-art-8db4e7ff55d344908756e3ecba0b1d2f2025-01-12T09:33:54ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152023-06-018210812010.22090/jwent.2023.02.002705279Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative StudyRajni Lasyal0Shakunj Rajput1Department of Chemistry, Rajkiya Mahavidyalaya, Chinyalisaur, Uttarkashi, Uttarakhand, India.Department of Chemistry, Government Degree College Bhupatwala, Hardwar, Uttarakhand India.In this study, the degradation of azo-dye acid orange 10 has been investigated using Polyvinylpyrrolidone and Brij-35 stabilized iridium oxide nanoclusters as catalysts. Simple chemical reduction method was used to synthesize the above-mentioned nanoclusters. The characteristics of the nanocatalysts were determined by UV-visible spectrophotometer, TEM and XRD. The kinetic study has been carried out at λmax of reaction mixture i.e. 479 nm spectrophotometrically. The degradation follows first order kinetics with respect to oxidant and catalyst concentration while order is one at lower substrate concentration tending towards zero at higher concentration. The degradation kinetics has been supported by the derived rate law. The results showed that Polyvinylpyrrolidone stabilized iridium oxide nanoclusters outperformed Brij-35 stabilized iridium oxide nanoclusters, exhibiting the fastest degradation rate. The progress of the degradation process was monitored by UV-vis spectroscopy. Using Polyvinylpyrrolidone stabilized iridium oxide nanoclusters as a catalyst is a very promising approach for the remediation of acid orange 10 due to the fast degradation rate and high degradation efficiency. In addition, Polyvinylpyrrolidone stabilized iridium oxide nanoclusters can be easily recovered and recycled for three consecutive cycles. It can be inferred from this study that catalytic oxidation methods are active and environment-friendly for the remediation of dyes.https://www.jwent.net/article_705279_2c15be35f3dc8bfa168bf89e8406b5a1.pdfdegradationkineticsrate lawacid orange10 |
| spellingShingle | Rajni Lasyal Shakunj Rajput Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative Study Journal of Water and Environmental Nanotechnology degradation kinetics rate law acid orange10 |
| title | Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative Study |
| title_full | Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative Study |
| title_fullStr | Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative Study |
| title_full_unstemmed | Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative Study |
| title_short | Polyvinylpyrrolidone and Brij-35 Stabilized IrO2 Nanoclusters As Highly Effective Catalyst In The Degradation Of Acid Orange 10: A Comparative Study |
| title_sort | polyvinylpyrrolidone and brij 35 stabilized iro2 nanoclusters as highly effective catalyst in the degradation of acid orange 10 a comparative study |
| topic | degradation kinetics rate law acid orange10 |
| url | https://www.jwent.net/article_705279_2c15be35f3dc8bfa168bf89e8406b5a1.pdf |
| work_keys_str_mv | AT rajnilasyal polyvinylpyrrolidoneandbrij35stabilizediro2nanoclustersashighlyeffectivecatalystinthedegradationofacidorange10acomparativestudy AT shakunjrajput polyvinylpyrrolidoneandbrij35stabilizediro2nanoclustersashighlyeffectivecatalystinthedegradationofacidorange10acomparativestudy |