Ammonium Oxathioamidate
Ammonium oxathioamidate (<b>1</b>) was synthesised by the reaction between <i>O</i>-ethyl-thioxamate (oxalic acid-1-amide-2-<i>O</i>-ethyl ester) and ammonium hydrogen carbonate in water solution. Compound <b>1</b> was fully characterised by both micro...
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-11-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2024/4/M1924 |
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| author | M. Carla Aragoni David B. Cordes Anna Pintus Enrico Podda Riccardo Serra Alexandra M. Z. Slawin J. Derek Woollins Massimiliano Arca |
| author_facet | M. Carla Aragoni David B. Cordes Anna Pintus Enrico Podda Riccardo Serra Alexandra M. Z. Slawin J. Derek Woollins Massimiliano Arca |
| author_sort | M. Carla Aragoni |
| collection | DOAJ |
| description | Ammonium oxathioamidate (<b>1</b>) was synthesised by the reaction between <i>O</i>-ethyl-thioxamate (oxalic acid-1-amide-2-<i>O</i>-ethyl ester) and ammonium hydrogen carbonate in water solution. Compound <b>1</b> was fully characterised by both microanalytical (elemental analysis, melting point determination) and spectroscopic means (FT-IR and NMR spectroscopy). Crystals suitable for single-crystal X-ray diffraction were isolated by slow evaporation of an ethanol solution of the compound. The analysis of the crystal packing reveals the prominent role exerted by intermolecular hydrogen bonding (HB) and chalcogen bonding (ChB) interactions. |
| format | Article |
| id | doaj-art-8b2028c14b3c4a3186e5ce2e2c7a6ba6 |
| institution | Kabale University |
| issn | 1422-8599 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj-art-8b2028c14b3c4a3186e5ce2e2c7a6ba62024-12-27T14:42:16ZengMDPI AGMolbank1422-85992024-11-0120244M192410.3390/M1924Ammonium OxathioamidateM. Carla Aragoni0David B. Cordes1Anna Pintus2Enrico Podda3Riccardo Serra4Alexandra M. Z. Slawin5J. Derek Woollins6Massimiliano Arca7Dipartimento di Scienze Chimiche e Geologiche, Università Degli Studi Di Cagliari, S.S. 554 bivio Sestu, Monserrato, 09042 Cagliari, ItalyEaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife KY16 9ST, UKDipartimento di Scienze Chimiche e Geologiche, Università Degli Studi Di Cagliari, S.S. 554 bivio Sestu, Monserrato, 09042 Cagliari, ItalyDipartimento di Scienze Chimiche e Geologiche, Università Degli Studi Di Cagliari, S.S. 554 bivio Sestu, Monserrato, 09042 Cagliari, ItalyDipartimento di Scienze Chimiche e Geologiche, Università Degli Studi Di Cagliari, S.S. 554 bivio Sestu, Monserrato, 09042 Cagliari, ItalyEaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife KY16 9ST, UKEaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife KY16 9ST, UKDipartimento di Scienze Chimiche e Geologiche, Università Degli Studi Di Cagliari, S.S. 554 bivio Sestu, Monserrato, 09042 Cagliari, ItalyAmmonium oxathioamidate (<b>1</b>) was synthesised by the reaction between <i>O</i>-ethyl-thioxamate (oxalic acid-1-amide-2-<i>O</i>-ethyl ester) and ammonium hydrogen carbonate in water solution. Compound <b>1</b> was fully characterised by both microanalytical (elemental analysis, melting point determination) and spectroscopic means (FT-IR and NMR spectroscopy). Crystals suitable for single-crystal X-ray diffraction were isolated by slow evaporation of an ethanol solution of the compound. The analysis of the crystal packing reveals the prominent role exerted by intermolecular hydrogen bonding (HB) and chalcogen bonding (ChB) interactions.https://www.mdpi.com/1422-8599/2024/4/M1924thiooxamateoxalic acid derivativeshydrogen bondingXRD |
| spellingShingle | M. Carla Aragoni David B. Cordes Anna Pintus Enrico Podda Riccardo Serra Alexandra M. Z. Slawin J. Derek Woollins Massimiliano Arca Ammonium Oxathioamidate Molbank thiooxamate oxalic acid derivatives hydrogen bonding XRD |
| title | Ammonium Oxathioamidate |
| title_full | Ammonium Oxathioamidate |
| title_fullStr | Ammonium Oxathioamidate |
| title_full_unstemmed | Ammonium Oxathioamidate |
| title_short | Ammonium Oxathioamidate |
| title_sort | ammonium oxathioamidate |
| topic | thiooxamate oxalic acid derivatives hydrogen bonding XRD |
| url | https://www.mdpi.com/1422-8599/2024/4/M1924 |
| work_keys_str_mv | AT mcarlaaragoni ammoniumoxathioamidate AT davidbcordes ammoniumoxathioamidate AT annapintus ammoniumoxathioamidate AT enricopodda ammoniumoxathioamidate AT riccardoserra ammoniumoxathioamidate AT alexandramzslawin ammoniumoxathioamidate AT jderekwoollins ammoniumoxathioamidate AT massimilianoarca ammoniumoxathioamidate |