Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteries

A parameterized mathematical model for Lithium-ion battery cell is presented in this paper for performance analysis with a particular focus on battery discharge behavior and electrochemical impedance spectroscopy profile. The model utilizes various physical properties as input and consists of two ma...

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Main Authors: Jin Zhao, Jaber A. Abu Qahouq
Format: Article
Language:English
Published: Elsevier 2024-10-01
Series:Next Energy
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949821X24000589
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author Jin Zhao
Jaber A. Abu Qahouq
author_facet Jin Zhao
Jaber A. Abu Qahouq
author_sort Jin Zhao
collection DOAJ
description A parameterized mathematical model for Lithium-ion battery cell is presented in this paper for performance analysis with a particular focus on battery discharge behavior and electrochemical impedance spectroscopy profile. The model utilizes various physical properties as input and consists of two major sub-models in a complementary manner. The first sub-model is an adapted Doyle-Fuller-Newman (DFN) framework to simulate electrochemical, thermodynamic, and transport phenomena within the battery. The second sub-model is a calibrated solid-electrolyte interphase (SEI) layer formation model. This model emphasizes the electrical dynamic response in terms of the reaction process, layer growth, and conductance change. The equivalent circuit component values are derived from the outputs of both sub-models, reflecting the battery’s changing physical parameters. The simulated discharge curves and electrochemical impedance spectroscopy (EIS) profiles are then provided with a comparison against empirical results for validation, which exhibit good agreement. This modeling methodology aims to bridge the gap between the physical model and the equivalent circuit model (ECM), enabling more accurate battery performance predictions and operation status tracking.
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institution Kabale University
issn 2949-821X
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spelling doaj-art-8954ae9fad2546039072fa64a0f346952024-12-08T06:13:46ZengElsevierNext Energy2949-821X2024-10-015100153Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteriesJin Zhao0Jaber A. Abu Qahouq1Corresponding author.; Department of Electrical and Computer Engineering, The University of Alabama, Box 870286, Tuscaloosa, AL, 35487-0286, USADepartment of Electrical and Computer Engineering, The University of Alabama, Box 870286, Tuscaloosa, AL, 35487-0286, USAA parameterized mathematical model for Lithium-ion battery cell is presented in this paper for performance analysis with a particular focus on battery discharge behavior and electrochemical impedance spectroscopy profile. The model utilizes various physical properties as input and consists of two major sub-models in a complementary manner. The first sub-model is an adapted Doyle-Fuller-Newman (DFN) framework to simulate electrochemical, thermodynamic, and transport phenomena within the battery. The second sub-model is a calibrated solid-electrolyte interphase (SEI) layer formation model. This model emphasizes the electrical dynamic response in terms of the reaction process, layer growth, and conductance change. The equivalent circuit component values are derived from the outputs of both sub-models, reflecting the battery’s changing physical parameters. The simulated discharge curves and electrochemical impedance spectroscopy (EIS) profiles are then provided with a comparison against empirical results for validation, which exhibit good agreement. This modeling methodology aims to bridge the gap between the physical model and the equivalent circuit model (ECM), enabling more accurate battery performance predictions and operation status tracking.http://www.sciencedirect.com/science/article/pii/S2949821X24000589Li-ion batteryMathematical modelingPhysics modelSimulation and validationEISECM
spellingShingle Jin Zhao
Jaber A. Abu Qahouq
Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteries
Next Energy
Li-ion battery
Mathematical modeling
Physics model
Simulation and validation
EIS
ECM
title Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteries
title_full Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteries
title_fullStr Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteries
title_full_unstemmed Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteries
title_short Modeling and validation for performance analysis and impedance spectroscopy characterization of lithium-ion batteries
title_sort modeling and validation for performance analysis and impedance spectroscopy characterization of lithium ion batteries
topic Li-ion battery
Mathematical modeling
Physics model
Simulation and validation
EIS
ECM
url http://www.sciencedirect.com/science/article/pii/S2949821X24000589
work_keys_str_mv AT jinzhao modelingandvalidationforperformanceanalysisandimpedancespectroscopycharacterizationoflithiumionbatteries
AT jaberaabuqahouq modelingandvalidationforperformanceanalysisandimpedancespectroscopycharacterizationoflithiumionbatteries