Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing Bacteria

The effects of medium and flow rate on the film-forming structures of B10 Cu-Ni alloys and their resistance to corrosion caused by sulfate-reducing bacteria are investigated in this article. Combined with a predicted cloud map of pipeline corrosion area and a particle motion trajectory map obtained...

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Main Authors: Bochao Lu, Ning Cui, Yimeng Zhang, Ding Guo, Yanan Wang, Xiaopeng Wang, Jizhou Duan
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Metals
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Online Access:https://www.mdpi.com/2075-4701/14/12/1451
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author Bochao Lu
Ning Cui
Yimeng Zhang
Ding Guo
Yanan Wang
Xiaopeng Wang
Jizhou Duan
author_facet Bochao Lu
Ning Cui
Yimeng Zhang
Ding Guo
Yanan Wang
Xiaopeng Wang
Jizhou Duan
author_sort Bochao Lu
collection DOAJ
description The effects of medium and flow rate on the film-forming structures of B10 Cu-Ni alloys and their resistance to corrosion caused by sulfate-reducing bacteria are investigated in this article. Combined with a predicted cloud map of pipeline corrosion area and a particle motion trajectory map obtained using Computational Fluid Dynamics (CFD), the growth law of alloy passivation films was analyzed and the pitting process of sulfate-reducing bacteria (SRB) on passivation films was revealed. The results show that the film formation effect is best when the stream of water in the film-forming environment is filtered seawater with a flow rate of 0.8 m/s, which consists of a uniform and dense gray-brown passivated film layer with the strongest resistance to SRB corrosion. When the flow rate is 0 m/s, the clay particles in the seawater cover the surface of the passivation film, hindering the contact of oxygen with the substrate and inhibiting the growth of the passivation film. When the stream of water in the film-forming environment is seawater with a flow rate of 3 m/s, the surface of the substrate shows obvious scouring marks, which is favorable for the enrichment of SRB and further accelerates the pitting corrosion of the substrate. Cl<sup>−</sup> has a significant influence on the formation of passivation films on B10 Cu-Ni alloys. When the filming medium is deionized water, the B10 Cu-Ni alloy does not form a complete passivation film at all flow rates.
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issn 2075-4701
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spelling doaj-art-88fa556176174d60b96439e911f7692b2024-12-27T14:40:08ZengMDPI AGMetals2075-47012024-12-011412145110.3390/met14121451Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing BacteriaBochao Lu0Ning Cui1Yimeng Zhang2Ding Guo3Yanan Wang4Xiaopeng Wang5Jizhou Duan6School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, ChinaSchool of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, ChinaKey Laboratory of Advanced Marine Materials, Key Laboratory of Marine Environmental Corrosion and Biofouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, ChinaKey Laboratory of Advanced Marine Materials, Key Laboratory of Marine Environmental Corrosion and Biofouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, ChinaKey Laboratory of Advanced Marine Materials, Key Laboratory of Marine Environmental Corrosion and Biofouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, ChinaCenter of Analysis and Measurement, Harbin Institute of Technology, Harbin 150001, ChinaKey Laboratory of Advanced Marine Materials, Key Laboratory of Marine Environmental Corrosion and Biofouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, ChinaThe effects of medium and flow rate on the film-forming structures of B10 Cu-Ni alloys and their resistance to corrosion caused by sulfate-reducing bacteria are investigated in this article. Combined with a predicted cloud map of pipeline corrosion area and a particle motion trajectory map obtained using Computational Fluid Dynamics (CFD), the growth law of alloy passivation films was analyzed and the pitting process of sulfate-reducing bacteria (SRB) on passivation films was revealed. The results show that the film formation effect is best when the stream of water in the film-forming environment is filtered seawater with a flow rate of 0.8 m/s, which consists of a uniform and dense gray-brown passivated film layer with the strongest resistance to SRB corrosion. When the flow rate is 0 m/s, the clay particles in the seawater cover the surface of the passivation film, hindering the contact of oxygen with the substrate and inhibiting the growth of the passivation film. When the stream of water in the film-forming environment is seawater with a flow rate of 3 m/s, the surface of the substrate shows obvious scouring marks, which is favorable for the enrichment of SRB and further accelerates the pitting corrosion of the substrate. Cl<sup>−</sup> has a significant influence on the formation of passivation films on B10 Cu-Ni alloys. When the filming medium is deionized water, the B10 Cu-Ni alloy does not form a complete passivation film at all flow rates.https://www.mdpi.com/2075-4701/14/12/1451<i>D. bizertensis</i>biocorrosionpitting corrosionComputational Fluid Dynamics simulationstream of water into a filmpassivation film
spellingShingle Bochao Lu
Ning Cui
Yimeng Zhang
Ding Guo
Yanan Wang
Xiaopeng Wang
Jizhou Duan
Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing Bacteria
Metals
<i>D. bizertensis</i>
biocorrosion
pitting corrosion
Computational Fluid Dynamics simulation
stream of water into a film
passivation film
title Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing Bacteria
title_full Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing Bacteria
title_fullStr Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing Bacteria
title_full_unstemmed Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing Bacteria
title_short Effects of Medium and Flow Rate on the Film-Forming Structures of B10 Cu-Ni Alloys and Their Resistance to Corrosion Caused by Sulfate-Reducing Bacteria
title_sort effects of medium and flow rate on the film forming structures of b10 cu ni alloys and their resistance to corrosion caused by sulfate reducing bacteria
topic <i>D. bizertensis</i>
biocorrosion
pitting corrosion
Computational Fluid Dynamics simulation
stream of water into a film
passivation film
url https://www.mdpi.com/2075-4701/14/12/1451
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