Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applications

Abstract Due to the high cost of raw materials, this work aims to benefit from metal waste, especially iron (Fe) and silicon bronze, which results from turning workshops and recycling them to obtain nanocomposites for industrial applications. In this respect, Fe/SiBr/Si3N4/silica fume nanocomposites...

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Main Authors: Mohammed A. Taha, S. A. Gad, Rasha A. Youness
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-024-81657-8
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author Mohammed A. Taha
S. A. Gad
Rasha A. Youness
author_facet Mohammed A. Taha
S. A. Gad
Rasha A. Youness
author_sort Mohammed A. Taha
collection DOAJ
description Abstract Due to the high cost of raw materials, this work aims to benefit from metal waste, especially iron (Fe) and silicon bronze, which results from turning workshops and recycling them to obtain nanocomposites for industrial applications. In this respect, Fe/SiBr/Si3N4/silica fume nanocomposites possessing superior mechanical, wear, and magnetic characteristics have been produced using powder metallurgy (PM) technology. Milled sample particle size, crystal size, and phase composition were investigated using X-ray diffraction (XRD) technique and transmission electron microscopy (TEM). The powders were compressed and sintered in argon to get excellent sinterability. The sintered nanocomposites’ physical, mechanical, wear, electrical, and magnetic properties were investigated. The microstructure was also examined using field emission scanning electron microscopy (FESEM). The results showed a noticeable decrease in the size of particles and crystallite size after adding reinforcements, reaching 22 nm for the sample improved with 5 vol% silica fume and 5 vol% Si3N4 (FS4). In addition, after adding reinforcements, there was a clear improvement in the microhardness, Young’s modulus, and wear rate of Fe-SiBr, reaching 58, 27.89, and 43.21% percent for the sample FS4. Adding reinforcements harms the electrical conductivity of Fe-SiBr, as it decreases to 8.64 × 106 S/m for the same previous sample. Finally, adding reinforcements slightly affects the decrease in magnetization of the nanocomposites.
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spelling doaj-art-87a1740ee1ca4e49971604cd72a45f372025-01-12T12:17:23ZengNature PortfolioScientific Reports2045-23222025-01-0115112010.1038/s41598-024-81657-8Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applicationsMohammed A. Taha0S. A. Gad1Rasha A. Youness2Solid State Physics Department, National Research CentreSolid State Physics Department, National Research CentreSpectroscopy Department, National Research CentreAbstract Due to the high cost of raw materials, this work aims to benefit from metal waste, especially iron (Fe) and silicon bronze, which results from turning workshops and recycling them to obtain nanocomposites for industrial applications. In this respect, Fe/SiBr/Si3N4/silica fume nanocomposites possessing superior mechanical, wear, and magnetic characteristics have been produced using powder metallurgy (PM) technology. Milled sample particle size, crystal size, and phase composition were investigated using X-ray diffraction (XRD) technique and transmission electron microscopy (TEM). The powders were compressed and sintered in argon to get excellent sinterability. The sintered nanocomposites’ physical, mechanical, wear, electrical, and magnetic properties were investigated. The microstructure was also examined using field emission scanning electron microscopy (FESEM). The results showed a noticeable decrease in the size of particles and crystallite size after adding reinforcements, reaching 22 nm for the sample improved with 5 vol% silica fume and 5 vol% Si3N4 (FS4). In addition, after adding reinforcements, there was a clear improvement in the microhardness, Young’s modulus, and wear rate of Fe-SiBr, reaching 58, 27.89, and 43.21% percent for the sample FS4. Adding reinforcements harms the electrical conductivity of Fe-SiBr, as it decreases to 8.64 × 106 S/m for the same previous sample. Finally, adding reinforcements slightly affects the decrease in magnetization of the nanocomposites.https://doi.org/10.1038/s41598-024-81657-8Recycled metal wasteTribo-mechanical propertiesElectrical propertiesMagnetic propertiesIndustrial applications
spellingShingle Mohammed A. Taha
S. A. Gad
Rasha A. Youness
Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applications
Scientific Reports
Recycled metal waste
Tribo-mechanical properties
Electrical properties
Magnetic properties
Industrial applications
title Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applications
title_full Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applications
title_fullStr Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applications
title_full_unstemmed Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applications
title_short Development of Fe/SiBr/Si₃N₄/silica fume nanocomposites from recycled metal waste for industrial applications
title_sort development of fe sibr si₃n₄ silica fume nanocomposites from recycled metal waste for industrial applications
topic Recycled metal waste
Tribo-mechanical properties
Electrical properties
Magnetic properties
Industrial applications
url https://doi.org/10.1038/s41598-024-81657-8
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AT rashaayouness developmentoffesibrsi3n4silicafumenanocompositesfromrecycledmetalwasteforindustrialapplications