Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> Coatings

In order to enhance the corrosion protection of K2SiO3&#x00A0;coatings, SiO2&#x00A0;aerogel (SA) was used as a carrier loaded with 70 mg/mL benzotriazole (BTA) corrosion inhibitor (SA@BTA-70).The SA@BTA-70 dispersion and BTA slow-release properties in K2SiO3&#x00A0;solution were research...

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Main Author: HAO Guoqiang, WANG Shuchuang, CHEN Zengyong, ZHANG Xinyi, LIU Xianwen, WANG Shirong, YANG Jingxia
Format: Article
Language:zho
Published: Editorial Department of Materials Protection 2024-09-01
Series:Cailiao Baohu
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Online Access:http://www.mat-pro.com/fileup/1001-1560/PDF/20240907.pdf
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author HAO Guoqiang, WANG Shuchuang, CHEN Zengyong, ZHANG Xinyi, LIU Xianwen, WANG Shirong, YANG Jingxia
author_facet HAO Guoqiang, WANG Shuchuang, CHEN Zengyong, ZHANG Xinyi, LIU Xianwen, WANG Shirong, YANG Jingxia
author_sort HAO Guoqiang, WANG Shuchuang, CHEN Zengyong, ZHANG Xinyi, LIU Xianwen, WANG Shirong, YANG Jingxia
collection DOAJ
description In order to enhance the corrosion protection of K2SiO3&#x00A0;coatings, SiO2&#x00A0;aerogel (SA) was used as a carrier loaded with 70 mg/mL benzotriazole (BTA) corrosion inhibitor (SA@BTA-70).The SA@BTA-70 dispersion and BTA slow-release properties in K2SiO3&#x00A0;solution were researched,and their influence on the corrosion resistance of K2SiO3&#x00A0;coatings were also investigated.Moreover,the surface change of SiO2&#x00A0;aerogel before and after heat treatment at 600 ℃was investigated by Fourier transform infrared spectrometer, specific surface area adsorption tester, etc.to improve its dispersibility in aqueous K2SiO3.Through TGA and UV-vis monitoring,it was found that the effective load of BTA in SiO2&#x00A0;aerogel was 17.6%(mass fraction), and it had good slow-release performance under weak acidic / alkaline condition.Electrochemical impedance spectroscopy (EIS) results showed the low-frequency impedance of the K2SiO3&#x00A0;coating containing SA@BTA-70 was around 5.0 &#x00D7;103&#x00A0;Ω&#x00B7;cm2.The neutral salt spray resistance test showed that no obvious rust spots appeared after salt spray resistance test for 30 d, demonstrating the coating possessed excellent corrosion protection ability.From the above results, it could be obtained that SiO2&#x00A0;aerogel effectively loaded BTA corrosion inhibitor, and had good slow release in K2SiO3&#x00A0;solution, which effectively improved the corrosion resistance of K2SiO3&#x00A0;coatings.
format Article
id doaj-art-879cbdbd18b54e6bb662a1e835d9a983
institution Kabale University
issn 1001-1560
language zho
publishDate 2024-09-01
publisher Editorial Department of Materials Protection
record_format Article
series Cailiao Baohu
spelling doaj-art-879cbdbd18b54e6bb662a1e835d9a9832024-11-14T08:44:37ZzhoEditorial Department of Materials ProtectionCailiao Baohu1001-15602024-09-01579546210.16577/j.issn.1001-1560.2024.0201Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> CoatingsHAO Guoqiang, WANG Shuchuang, CHEN Zengyong, ZHANG Xinyi, LIU Xianwen, WANG Shirong, YANG Jingxia0 (1.School of Chemistry and Chemical Engineering, Shanghai University of Engineering and Technology, Shanghai 201600, China;2.T&H Novel Materials Co., Ltd., Quanzhou 362011, China) In order to enhance the corrosion protection of K2SiO3&#x00A0;coatings, SiO2&#x00A0;aerogel (SA) was used as a carrier loaded with 70 mg/mL benzotriazole (BTA) corrosion inhibitor (SA@BTA-70).The SA@BTA-70 dispersion and BTA slow-release properties in K2SiO3&#x00A0;solution were researched,and their influence on the corrosion resistance of K2SiO3&#x00A0;coatings were also investigated.Moreover,the surface change of SiO2&#x00A0;aerogel before and after heat treatment at 600 ℃was investigated by Fourier transform infrared spectrometer, specific surface area adsorption tester, etc.to improve its dispersibility in aqueous K2SiO3.Through TGA and UV-vis monitoring,it was found that the effective load of BTA in SiO2&#x00A0;aerogel was 17.6%(mass fraction), and it had good slow-release performance under weak acidic / alkaline condition.Electrochemical impedance spectroscopy (EIS) results showed the low-frequency impedance of the K2SiO3&#x00A0;coating containing SA@BTA-70 was around 5.0 &#x00D7;103&#x00A0;Ω&#x00B7;cm2.The neutral salt spray resistance test showed that no obvious rust spots appeared after salt spray resistance test for 30 d, demonstrating the coating possessed excellent corrosion protection ability.From the above results, it could be obtained that SiO2&#x00A0;aerogel effectively loaded BTA corrosion inhibitor, and had good slow release in K2SiO3&#x00A0;solution, which effectively improved the corrosion resistance of K2SiO3&#x00A0;coatings.http://www.mat-pro.com/fileup/1001-1560/PDF/20240907.pdfsio2&#x00a0;aerogel; bta corrosion inhibitor; load and release; k2sio3&#x00a0;coating; corrosion resistance
spellingShingle HAO Guoqiang, WANG Shuchuang, CHEN Zengyong, ZHANG Xinyi, LIU Xianwen, WANG Shirong, YANG Jingxia
Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> Coatings
Cailiao Baohu
sio2&#x00a0;aerogel; bta corrosion inhibitor; load and release; k2sio3&#x00a0;coating; corrosion resistance
title Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> Coatings
title_full Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> Coatings
title_fullStr Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> Coatings
title_full_unstemmed Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> Coatings
title_short Corrosion Resistance of SiO<sub>2</sub> Aerogel Loaded with Benzotriazole Inhibitor in K<sub>2</sub>SiO<sub>3</sub> Coatings
title_sort corrosion resistance of sio sub 2 sub aerogel loaded with benzotriazole inhibitor in k sub 2 sub sio sub 3 sub coatings
topic sio2&#x00a0;aerogel; bta corrosion inhibitor; load and release; k2sio3&#x00a0;coating; corrosion resistance
url http://www.mat-pro.com/fileup/1001-1560/PDF/20240907.pdf
work_keys_str_mv AT haoguoqiangwangshuchuangchenzengyongzhangxinyiliuxianwenwangshirongyangjingxia corrosionresistanceofsiosub2subaerogelloadedwithbenzotriazoleinhibitorinksub2subsiosub3subcoatings