Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS Performance

A small amount of silver was obliquely deposited onto a polymer subwavelength grating to form a metasurface that comprised silver split-tubes. An ultra-thin silver film with a monitor-controlled thickness of 20 nm at the corner of each ridge of the grating provided the most sensitive surface-enhance...

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Main Authors: Yi-Jun Jen, Meng-Jie Lin
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/14/23/1871
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author Yi-Jun Jen
Meng-Jie Lin
author_facet Yi-Jun Jen
Meng-Jie Lin
author_sort Yi-Jun Jen
collection DOAJ
description A small amount of silver was obliquely deposited onto a polymer subwavelength grating to form a metasurface that comprised silver split-tubes. An ultra-thin silver film with a monitor-controlled thickness of 20 nm at the corner of each ridge of the grating provided the most sensitive surface-enhanced Raman scattering (SERS) measurements. An excitation laser beam that was incident from the substrate provided similar or better SERS enhancement than did the general configuration with the laser beam incident directly on the surface of the nanostructure. Near-field simulations were conducted to model the localized electric field enhancement and to quantify the SERS performance, demonstrating the effectiveness of this novel deposition method.
format Article
id doaj-art-82b49650264c4b0683a32b49625f1dac
institution Kabale University
issn 2079-4991
language English
publishDate 2024-11-01
publisher MDPI AG
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series Nanomaterials
spelling doaj-art-82b49650264c4b0683a32b49625f1dac2024-12-13T16:29:12ZengMDPI AGNanomaterials2079-49912024-11-011423187110.3390/nano14231871Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS PerformanceYi-Jun Jen0Meng-Jie Lin1Department of Electro-Optical Engineering, National Taipei University of Technology, Taipei 106, TaiwanDepartment of Electro-Optical Engineering, National Taipei University of Technology, Taipei 106, TaiwanA small amount of silver was obliquely deposited onto a polymer subwavelength grating to form a metasurface that comprised silver split-tubes. An ultra-thin silver film with a monitor-controlled thickness of 20 nm at the corner of each ridge of the grating provided the most sensitive surface-enhanced Raman scattering (SERS) measurements. An excitation laser beam that was incident from the substrate provided similar or better SERS enhancement than did the general configuration with the laser beam incident directly on the surface of the nanostructure. Near-field simulations were conducted to model the localized electric field enhancement and to quantify the SERS performance, demonstrating the effectiveness of this novel deposition method.https://www.mdpi.com/2079-4991/14/23/1871oblique depositionplasmonic nanostructuressurface-enhanced Raman scattering (SERS)ultra-thin silver filmspolymer gratings
spellingShingle Yi-Jun Jen
Meng-Jie Lin
Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS Performance
Nanomaterials
oblique deposition
plasmonic nanostructures
surface-enhanced Raman scattering (SERS)
ultra-thin silver films
polymer gratings
title Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS Performance
title_full Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS Performance
title_fullStr Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS Performance
title_full_unstemmed Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS Performance
title_short Oblique Deposited Ultra-Thin Silver Films on Polymer Gratings for Sensitive SERS Performance
title_sort oblique deposited ultra thin silver films on polymer gratings for sensitive sers performance
topic oblique deposition
plasmonic nanostructures
surface-enhanced Raman scattering (SERS)
ultra-thin silver films
polymer gratings
url https://www.mdpi.com/2079-4991/14/23/1871
work_keys_str_mv AT yijunjen obliquedepositedultrathinsilverfilmsonpolymergratingsforsensitivesersperformance
AT mengjielin obliquedepositedultrathinsilverfilmsonpolymergratingsforsensitivesersperformance