Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results
<p>We analyze tropical ozone (O<span class="inline-formula"><sub>3</sub></span>) and carbon monoxide (CO) distributions in the upper troposphere (UT) for 2005–2020 using Aura Microwave Limb Sounder (MLS) observations and simulations from the Whole Atmosphere C...
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Copernicus Publications
2025-01-01
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| Series: | Atmospheric Chemistry and Physics |
| Online Access: | https://acp.copernicus.org/articles/25/597/2025/acp-25-597-2025.pdf |
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| author | L. Froidevaux D. E. Kinnison B. Gaubert M. J. Schwartz N. J. Livesey W. G. Read C. G. Bardeen J. R. Ziemke J. R. Ziemke R. A. Fuller |
| author_facet | L. Froidevaux D. E. Kinnison B. Gaubert M. J. Schwartz N. J. Livesey W. G. Read C. G. Bardeen J. R. Ziemke J. R. Ziemke R. A. Fuller |
| author_sort | L. Froidevaux |
| collection | DOAJ |
| description | <p>We analyze tropical ozone (O<span class="inline-formula"><sub>3</sub></span>) and carbon monoxide (CO) distributions in the upper troposphere (UT) for 2005–2020 using Aura Microwave Limb Sounder (MLS) observations and simulations from the Whole Atmosphere Community Climate Model (WACCM) and two variants of the Community Atmosphere Model with Chemistry (CAM-chem), with each variant using different anthropogenic CO emissions. Trends and variability diagnostics are obtained from multiple linear regression. The MLS zonal mean O<span class="inline-formula"><sub>3</sub></span> UT trend for 20° S–20° N is <span class="inline-formula">+</span>0.39 <span class="inline-formula">±</span> 0.28 % yr<span class="inline-formula"><sup>−1</sup></span>; the WACCM and CAM-chem simulations yield similar trends, although the WACCM result is somewhat smaller. Our analyses of gridded MLS data yield positive O<span class="inline-formula"><sub>3</sub></span> trends (up to 1.4 % yr<span class="inline-formula"><sup>−1</sup></span>) over Indonesia and east of that region, as well as over Africa and the Atlantic. These positive mapped O<span class="inline-formula"><sub>3</sub></span> trends are generally captured by the simulations but in a more muted way. We find broad similarities (and some differences) between mapped MLS UT O<span class="inline-formula"><sub>3</sub></span> trends and corresponding mapped trends of tropospheric column ozone. The MLS zonal mean CO UT trend for 20° S–20° N is <span class="inline-formula">−0.25</span> <span class="inline-formula">±</span> 0.30 % yr<span class="inline-formula"><sup>−1</sup></span>, while the corresponding CAM-chem trend is 0.0 <span class="inline-formula">±</span> 0.14 % yr<span class="inline-formula"><sup>−1</sup></span> when anthropogenic emissions are taken from the Community Emissions Data System (CEDS) version 2. The CAM-chem simulation driven by CAMS-GLOB-ANTv5 emissions yields a tropical mean CO UT trend of 0.22 <span class="inline-formula">±</span> 0.19 % yr<span class="inline-formula"><sup>−1</sup></span>, in contrast to the slightly negative MLS CO trend. Previously published analyses of total column CO data have shown negative trends.</p>
<p>Our tropical composition trend results contribute to continuing international assessments of tropospheric evolution.</p> |
| format | Article |
| id | doaj-art-82ae5bcffecf4984abe7685860647289 |
| institution | Kabale University |
| issn | 1680-7316 1680-7324 |
| language | English |
| publishDate | 2025-01-01 |
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| series | Atmospheric Chemistry and Physics |
| spelling | doaj-art-82ae5bcffecf4984abe76858606472892025-01-17T08:39:25ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242025-01-012559762410.5194/acp-25-597-2025Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model resultsL. Froidevaux0D. E. Kinnison1B. Gaubert2M. J. Schwartz3N. J. Livesey4W. G. Read5C. G. Bardeen6J. R. Ziemke7J. R. Ziemke8R. A. Fuller9Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USANSF National Center for Atmospheric Research (NSF NCAR), Boulder, Colorado, USANSF National Center for Atmospheric Research (NSF NCAR), Boulder, Colorado, USAJet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USAJet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USAJet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USANSF National Center for Atmospheric Research (NSF NCAR), Boulder, Colorado, USANASA Goddard Space Flight Center, Greenbelt, MD, USAGoddard Earth Sciences Technology and Research (GESTAR)/Morgan State University, Baltimore, MD, USAJet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA<p>We analyze tropical ozone (O<span class="inline-formula"><sub>3</sub></span>) and carbon monoxide (CO) distributions in the upper troposphere (UT) for 2005–2020 using Aura Microwave Limb Sounder (MLS) observations and simulations from the Whole Atmosphere Community Climate Model (WACCM) and two variants of the Community Atmosphere Model with Chemistry (CAM-chem), with each variant using different anthropogenic CO emissions. Trends and variability diagnostics are obtained from multiple linear regression. The MLS zonal mean O<span class="inline-formula"><sub>3</sub></span> UT trend for 20° S–20° N is <span class="inline-formula">+</span>0.39 <span class="inline-formula">±</span> 0.28 % yr<span class="inline-formula"><sup>−1</sup></span>; the WACCM and CAM-chem simulations yield similar trends, although the WACCM result is somewhat smaller. Our analyses of gridded MLS data yield positive O<span class="inline-formula"><sub>3</sub></span> trends (up to 1.4 % yr<span class="inline-formula"><sup>−1</sup></span>) over Indonesia and east of that region, as well as over Africa and the Atlantic. These positive mapped O<span class="inline-formula"><sub>3</sub></span> trends are generally captured by the simulations but in a more muted way. We find broad similarities (and some differences) between mapped MLS UT O<span class="inline-formula"><sub>3</sub></span> trends and corresponding mapped trends of tropospheric column ozone. The MLS zonal mean CO UT trend for 20° S–20° N is <span class="inline-formula">−0.25</span> <span class="inline-formula">±</span> 0.30 % yr<span class="inline-formula"><sup>−1</sup></span>, while the corresponding CAM-chem trend is 0.0 <span class="inline-formula">±</span> 0.14 % yr<span class="inline-formula"><sup>−1</sup></span> when anthropogenic emissions are taken from the Community Emissions Data System (CEDS) version 2. The CAM-chem simulation driven by CAMS-GLOB-ANTv5 emissions yields a tropical mean CO UT trend of 0.22 <span class="inline-formula">±</span> 0.19 % yr<span class="inline-formula"><sup>−1</sup></span>, in contrast to the slightly negative MLS CO trend. Previously published analyses of total column CO data have shown negative trends.</p> <p>Our tropical composition trend results contribute to continuing international assessments of tropospheric evolution.</p>https://acp.copernicus.org/articles/25/597/2025/acp-25-597-2025.pdf |
| spellingShingle | L. Froidevaux D. E. Kinnison B. Gaubert M. J. Schwartz N. J. Livesey W. G. Read C. G. Bardeen J. R. Ziemke J. R. Ziemke R. A. Fuller Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results Atmospheric Chemistry and Physics |
| title | Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results |
| title_full | Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results |
| title_fullStr | Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results |
| title_full_unstemmed | Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results |
| title_short | Tropical upper-tropospheric trends in ozone and carbon monoxide (2005–2020): observational and model results |
| title_sort | tropical upper tropospheric trends in ozone and carbon monoxide 2005 2020 observational and model results |
| url | https://acp.copernicus.org/articles/25/597/2025/acp-25-597-2025.pdf |
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