Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiation

In the present work, truncated octahedron and octahedron shaped Cu2O and Cu2O/TiO2-QD composite have been synthesized using precipitation method and used as a photocatalyst. Synthesized material was characterized by using various analytical techniques- XRD, SEM, TEM and UV-Visible DRS. TEM images cl...

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Main Authors: Shobha Musmade, Dinesh Hase, Amit Waghmare, Kailas Kadam, Jayshree Khedkar, Anil Gadhave, Kanhaiyalal Bhavsar, Vaishali Murade
Format: Article
Language:English
Published: Iranian Environmental Mutagen Society 2023-11-01
Series:Journal of Water and Environmental Nanotechnology
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Online Access:https://www.jwent.net/article_708747_741d933f86d822d7d3bdaa00ae9f198e.pdf
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author Shobha Musmade
Dinesh Hase
Amit Waghmare
Kailas Kadam
Jayshree Khedkar
Anil Gadhave
Kanhaiyalal Bhavsar
Vaishali Murade
author_facet Shobha Musmade
Dinesh Hase
Amit Waghmare
Kailas Kadam
Jayshree Khedkar
Anil Gadhave
Kanhaiyalal Bhavsar
Vaishali Murade
author_sort Shobha Musmade
collection DOAJ
description In the present work, truncated octahedron and octahedron shaped Cu2O and Cu2O/TiO2-QD composite have been synthesized using precipitation method and used as a photocatalyst. Synthesized material was characterized by using various analytical techniques- XRD, SEM, TEM and UV-Visible DRS. TEM images clearly shows that the TiO2 was highly dispersed and firmly anchored on single crystals of copper oxide in Cu2O/TiO2-QD composite and also confirmed the truncated octahedron and octahedron shapes of copper oxide. The excellent performance of synthesized Cu2O/TiO2-QD photocatalyst has been proved the maximum degradation (89.00%) of Congo red dye at pH=6. The effect of various parameters in the dye degradation such as influence of pH, amount of photocatalyst, concentration of dye and reusability of the photocatalyst has been studied. The highest degradation rate was found with concentration of Congo red dye 9 mg/L, 150mg/L of Cu2O/TiO2-QD, and 110 min. Thus, the photocatalytic performance of Cu2O/TiO2-QD composite revealed the excellent and effective degradation of Congo-red dye.
format Article
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institution Kabale University
issn 2476-7204
2476-6615
language English
publishDate 2023-11-01
publisher Iranian Environmental Mutagen Society
record_format Article
series Journal of Water and Environmental Nanotechnology
spelling doaj-art-825d55291f2140b997dc71b499bc2a862025-01-12T09:34:11ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152023-11-018440641610.22090/jwent.2023.04.007708747Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiationShobha Musmade0Dinesh Hase1Amit Waghmare2Kailas Kadam3Jayshree Khedkar4Anil Gadhave5Kanhaiyalal Bhavsar6Vaishali Murade7Padmashri Vikhe Patil’s Arts, Science and Commerce College, Pravaranagar, Loni KD., Ahmednagar, MS, IndiaAmrutvahini College of Pharmacy, Sangamner Ahmednagar, MS, IndiaASC College, Satral, Ahmednagar, MS, IndiaPadmashri Vikhe Patil’s Arts, Science and Commerce College, Pravaranagar, Loni KD., Ahmednagar, MS, IndiaShri Anand College, Pathardi, Ahmednagar, MS, IndiaPadmashri Vikhe Patil’s Arts, Science and Commerce College, Pravaranagar, Loni KD., Ahmednagar, MS, IndiaMGSM’s Arts, Science and Commerce College, Chopda, Jalgaon, IndiaPadmashri Vikhe Patil’s Arts, Science and Commerce College, Pravaranagar, Loni KD., Ahmednagar, MS, IndiaIn the present work, truncated octahedron and octahedron shaped Cu2O and Cu2O/TiO2-QD composite have been synthesized using precipitation method and used as a photocatalyst. Synthesized material was characterized by using various analytical techniques- XRD, SEM, TEM and UV-Visible DRS. TEM images clearly shows that the TiO2 was highly dispersed and firmly anchored on single crystals of copper oxide in Cu2O/TiO2-QD composite and also confirmed the truncated octahedron and octahedron shapes of copper oxide. The excellent performance of synthesized Cu2O/TiO2-QD photocatalyst has been proved the maximum degradation (89.00%) of Congo red dye at pH=6. The effect of various parameters in the dye degradation such as influence of pH, amount of photocatalyst, concentration of dye and reusability of the photocatalyst has been studied. The highest degradation rate was found with concentration of Congo red dye 9 mg/L, 150mg/L of Cu2O/TiO2-QD, and 110 min. Thus, the photocatalytic performance of Cu2O/TiO2-QD composite revealed the excellent and effective degradation of Congo-red dye.https://www.jwent.net/article_708747_741d933f86d822d7d3bdaa00ae9f198e.pdfcapping agentphotoexcitationphotocatalysistruncated octahedron
spellingShingle Shobha Musmade
Dinesh Hase
Amit Waghmare
Kailas Kadam
Jayshree Khedkar
Anil Gadhave
Kanhaiyalal Bhavsar
Vaishali Murade
Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiation
Journal of Water and Environmental Nanotechnology
capping agent
photoexcitation
photocatalysis
truncated octahedron
title Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiation
title_full Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiation
title_fullStr Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiation
title_full_unstemmed Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiation
title_short Synthesis of shape controlled Cu2O and Cu2O/TiO2-QD composite for degradation of Congo red dye under visible-light irradiation
title_sort synthesis of shape controlled cu2o and cu2o tio2 qd composite for degradation of congo red dye under visible light irradiation
topic capping agent
photoexcitation
photocatalysis
truncated octahedron
url https://www.jwent.net/article_708747_741d933f86d822d7d3bdaa00ae9f198e.pdf
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