Enhancement of the thermoelectric figure of merit in the Dirac semimetal Cd3As2 by band-structure and -filling control
Topological materials attract a considerable research interest because of their characteristic band structure giving rise to various new phenomena in quantum physics. Besides this, they are tempting from a functional materials point of view: Topological materials bear potential for an enhanced therm...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Taylor & Francis Group
2024-12-01
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| Series: | Science and Technology of Advanced Materials |
| Subjects: | |
| Online Access: | https://www.tandfonline.com/doi/10.1080/14686996.2024.2412971 |
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| Summary: | Topological materials attract a considerable research interest because of their characteristic band structure giving rise to various new phenomena in quantum physics. Besides this, they are tempting from a functional materials point of view: Topological materials bear potential for an enhanced thermoelectric efficiency because they possess the required ingredients, such as intermediate carrier concentrations, large mobilities, heavy elements etc. Against this background, this work reports an enhanced thermoelectric performance of the topological Dirac semimetal Cd3As2 upon alloying the trivial semiconductor Zn3As2. This allows to gain fine-tuned control over both the band filling and the band topology in Cd3-xZnxAs2. As a result, the thermoelectric figure of merit exceeds 0.5 around [Formula: see text] and [Formula: see text] at elevated temperatures. The former is due to an enhancement of the power factor, while the latter is a consequence of a strong suppression of the thermal conductivity. In addition, in terms of first-principle band structure calculations, the thermopower in this system is theoretically evaluated, which suggests that the topological aspects of the band structure change when traversing [Formula: see text]. |
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| ISSN: | 1468-6996 1878-5514 |