New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization
A new interesting category of higher thermally stable polyazomethines containing ferrocene in the polymers main chain 6a–e was synthesized by solution-polycondensation reaction of 1-(m-formylphenyl)-1′-(5-formyl-2-methoxyphenyl)-ferrocene monomer 4 with different aliphatic and aromatic diamines. A...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/198652 |
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| author | Mona Ahmed Abdel-Rahman Mahmoud Ali Hussein Kamal Ibrahim Aly Abdelwareth Abdel-Haleam Sarhan |
| author_facet | Mona Ahmed Abdel-Rahman Mahmoud Ali Hussein Kamal Ibrahim Aly Abdelwareth Abdel-Haleam Sarhan |
| author_sort | Mona Ahmed Abdel-Rahman |
| collection | DOAJ |
| description | A new interesting category of higher thermally stable polyazomethines containing ferrocene in the polymers main chain 6a–e was synthesized by solution-polycondensation reaction of 1-(m-formylphenyl)-1′-(5-formyl-2-methoxyphenyl)-ferrocene monomer 4 with different aliphatic and aromatic diamines. A model compound 5 was synthesized from dialdehyde monomer 4 with aniline and was characterized by elemental and spectral analyses. The desirable resulting polymers were characterized by elemental and spectral analyses, in addition to solubility measurement using different solvents. The thermal properties of these polymers were evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) measurements. The redox behaviours were studied for the ferrocene polymers in comparison with both the parent ferrocene monomer and the model compound by using cyclic voltammetry (CV). |
| format | Article |
| id | doaj-art-819f2dda78e54475bba22c2d495d6614 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-819f2dda78e54475bba22c2d495d66142025-02-03T05:47:17ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/198652198652New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and CharacterizationMona Ahmed Abdel-Rahman0Mahmoud Ali Hussein1Kamal Ibrahim Aly2Abdelwareth Abdel-Haleam Sarhan3Polymer Laboratory 122, Chemistry Department, Faculty of Science, Assiut University, Assiut 71516, EgyptPolymer Laboratory 122, Chemistry Department, Faculty of Science, Assiut University, Assiut 71516, EgyptPolymer Laboratory 122, Chemistry Department, Faculty of Science, Assiut University, Assiut 71516, EgyptPolymer Laboratory 122, Chemistry Department, Faculty of Science, Assiut University, Assiut 71516, EgyptA new interesting category of higher thermally stable polyazomethines containing ferrocene in the polymers main chain 6a–e was synthesized by solution-polycondensation reaction of 1-(m-formylphenyl)-1′-(5-formyl-2-methoxyphenyl)-ferrocene monomer 4 with different aliphatic and aromatic diamines. A model compound 5 was synthesized from dialdehyde monomer 4 with aniline and was characterized by elemental and spectral analyses. The desirable resulting polymers were characterized by elemental and spectral analyses, in addition to solubility measurement using different solvents. The thermal properties of these polymers were evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) measurements. The redox behaviours were studied for the ferrocene polymers in comparison with both the parent ferrocene monomer and the model compound by using cyclic voltammetry (CV).http://dx.doi.org/10.1155/2013/198652 |
| spellingShingle | Mona Ahmed Abdel-Rahman Mahmoud Ali Hussein Kamal Ibrahim Aly Abdelwareth Abdel-Haleam Sarhan New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization Journal of Chemistry |
| title | New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization |
| title_full | New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization |
| title_fullStr | New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization |
| title_full_unstemmed | New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization |
| title_short | New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization |
| title_sort | new polymer syntheses part 57 thermally stable new ferrocene polyazomethines synthetic methodology and characterization |
| url | http://dx.doi.org/10.1155/2013/198652 |
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