In situ generated diphenylphosphine-chelated imidazo[1,5-a]pyridin-3-ylidene nickel(0) catalysts for highly efficient acrylate synthesis from ethylene and CO2

In situ generated diphenylphosphine-chelated imidazo[1,5-a]pyridin-3-ylidene nickel(0) catalysts for highly efficient acrylate synthesis from ethylene and CO2

Diphenylphosphine-chelated imidazo[1,5-a]pyridin-3-ylidene (PPh₂-ImPy) nickel(0) catalysts were synthesized in-situ from imidazolium salts and various commercially available nickel(0) complexes using a base. These catalysts exhibited a highly planar and rigid structure, as confirmed by X-ray crystal...

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Bibliographic Details
Main Authors:	Changmuk Kang, Seyong Kim, Woosong Han, Huijeong Ryu, Wooyong Seong, Jiyun Kim, Da-Ae Park, Seongwook Park, Kyungho Park, Hyun Min Park, Hyun Tae Kim, Chang Hee Lee, Sukwon Hong
Format:	Article
Language:	English
Published:	Elsevier 2025-01-01
Series:	Journal of CO2 Utilization
Subjects:	N-heterocyclic carbene Nickel Acrylate Ethylene Carbon dioxide
Online Access:	http://www.sciencedirect.com/science/article/pii/S2212982024003391
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