Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice Straw

Membrane filtration is one of the preferred choices for petroleum wastewater disposal due to its simplicity and low energy consumption. In this paper, a biodegradable superhydrophobic membrane based on loofah and rice straw (LF-RS) was prepared and modified with dodecyltriethoxysilane to improve its...

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Main Authors: Mamadou Souare, Changqing Dong, Tong Xing, Junjiao Zhang, Xiaoying Hu
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/14/11/243
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author Mamadou Souare
Changqing Dong
Tong Xing
Junjiao Zhang
Xiaoying Hu
author_facet Mamadou Souare
Changqing Dong
Tong Xing
Junjiao Zhang
Xiaoying Hu
author_sort Mamadou Souare
collection DOAJ
description Membrane filtration is one of the preferred choices for petroleum wastewater disposal due to its simplicity and low energy consumption. In this paper, a biodegradable superhydrophobic membrane based on loofah and rice straw (LF-RS) was prepared and modified with dodecyltriethoxysilane to improve its stability, morphology, and performance. The membrane showed an efficiency of 99.06% for oil/water separation with an average water flux of 2057.37 Lm<sup>−2</sup>h<sup>−1</sup> and a tensile strength of 11.19 MPa. The tensile strength of the LF-RS membrane was 322.47% higher than that of the PVDF membrane and 126.58% higher than that of the commercially available nitrocellulose membrane. Through molecular simulations, we showed a 96.3% reduction in interaction energy between water and membrane post-modification, which is beneficial for increasing the contact angle and separation performance. This study provides an option for the large-scale, cost-effective fabrication of eco-friendly membranes for pollutant removal.
format Article
id doaj-art-7e59f918b99f4321aa0308357d84020d
institution Kabale University
issn 2077-0375
language English
publishDate 2024-11-01
publisher MDPI AG
record_format Article
series Membranes
spelling doaj-art-7e59f918b99f4321aa0308357d84020d2024-11-26T18:13:00ZengMDPI AGMembranes2077-03752024-11-01141124310.3390/membranes14110243Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice StrawMamadou Souare0Changqing Dong1Tong Xing2Junjiao Zhang3Xiaoying Hu4National Engineering Laboratory for Biomass Power Generation Equipment, School of New Energy, North China Electric Power University, Beijing 102206, ChinaNational Engineering Laboratory for Biomass Power Generation Equipment, School of New Energy, North China Electric Power University, Beijing 102206, ChinaNational Engineering Laboratory for Biomass Power Generation Equipment, School of New Energy, North China Electric Power University, Beijing 102206, ChinaSchool of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing 102206, ChinaNational Engineering Laboratory for Biomass Power Generation Equipment, School of New Energy, North China Electric Power University, Beijing 102206, ChinaMembrane filtration is one of the preferred choices for petroleum wastewater disposal due to its simplicity and low energy consumption. In this paper, a biodegradable superhydrophobic membrane based on loofah and rice straw (LF-RS) was prepared and modified with dodecyltriethoxysilane to improve its stability, morphology, and performance. The membrane showed an efficiency of 99.06% for oil/water separation with an average water flux of 2057.37 Lm<sup>−2</sup>h<sup>−1</sup> and a tensile strength of 11.19 MPa. The tensile strength of the LF-RS membrane was 322.47% higher than that of the PVDF membrane and 126.58% higher than that of the commercially available nitrocellulose membrane. Through molecular simulations, we showed a 96.3% reduction in interaction energy between water and membrane post-modification, which is beneficial for increasing the contact angle and separation performance. This study provides an option for the large-scale, cost-effective fabrication of eco-friendly membranes for pollutant removal.https://www.mdpi.com/2077-0375/14/11/243loofahrice strawoil/water separationsuperhydrophobic
spellingShingle Mamadou Souare
Changqing Dong
Tong Xing
Junjiao Zhang
Xiaoying Hu
Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice Straw
Membranes
loofah
rice straw
oil/water separation
superhydrophobic
title Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice Straw
title_full Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice Straw
title_fullStr Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice Straw
title_full_unstemmed Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice Straw
title_short Efficient Separation of Oil/Water by a Biodegradable and Superhydrophobic Composite Based on Loofah and Rice Straw
title_sort efficient separation of oil water by a biodegradable and superhydrophobic composite based on loofah and rice straw
topic loofah
rice straw
oil/water separation
superhydrophobic
url https://www.mdpi.com/2077-0375/14/11/243
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AT changqingdong efficientseparationofoilwaterbyabiodegradableandsuperhydrophobiccompositebasedonloofahandricestraw
AT tongxing efficientseparationofoilwaterbyabiodegradableandsuperhydrophobiccompositebasedonloofahandricestraw
AT junjiaozhang efficientseparationofoilwaterbyabiodegradableandsuperhydrophobiccompositebasedonloofahandricestraw
AT xiaoyinghu efficientseparationofoilwaterbyabiodegradableandsuperhydrophobiccompositebasedonloofahandricestraw