Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>

Based on modern concepts of the nonlinear percolation mechanisms of electrical and magnetic properties in granular metal–dielectric nanocomposites, the authors present for the first time a comparative analysis of their own results of a comprehensive study of nonlinear electromagnetic properties in t...

Full description

Saved in:
Bibliographic Details
Main Authors: Evelina Pavlovna Domashevskaya, Sergey Alexandrovich Ivkov, Elena Alexandrovna Ganshina, Lyubov Vladimirovna Guda, Valeriy Grigoryevich Vlasenko, Alexander Victorovich Sitnikov
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/15/6/463
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849341903885041664
author Evelina Pavlovna Domashevskaya
Sergey Alexandrovich Ivkov
Elena Alexandrovna Ganshina
Lyubov Vladimirovna Guda
Valeriy Grigoryevich Vlasenko
Alexander Victorovich Sitnikov
author_facet Evelina Pavlovna Domashevskaya
Sergey Alexandrovich Ivkov
Elena Alexandrovna Ganshina
Lyubov Vladimirovna Guda
Valeriy Grigoryevich Vlasenko
Alexander Victorovich Sitnikov
author_sort Evelina Pavlovna Domashevskaya
collection DOAJ
description Based on modern concepts of the nonlinear percolation mechanisms of electrical and magnetic properties in granular metal–dielectric nanocomposites, the authors present for the first time a comparative analysis of their own results of a comprehensive study of nonlinear electromagnetic properties in two nanocomposite systems: metal–dielectric Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and alloy–dielectric (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>, obtained by ion-beam sputtering of composite targets in a wide range of different compositions. For the first time, the features of the influence of atomic composition and structural-phase transitions on nonlinear magnetoresistive, magnetic, and magneto-optical properties in two systems are presented in comparison, one of which, Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>, showed soft magnetic properties, and the second, (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>, hard magnetic properties, during the transition from the superparamagnetic to the ferromagnetic state. Moreover, for the first time, the concentration dependences of the oscillating fine structure of XANES K-absorption edges of Co atoms in the first system and Co and Fe atoms in the second system are presented, which undergo changes at the percolation thresholds in each of the two systems and thus confirm the nonlinear nature of the electromagnetic properties changes in each of the two systems at the atomic level.
format Article
id doaj-art-7ccd2e14f45b46669d6eb799b7af468c
institution Kabale University
issn 2079-4991
language English
publishDate 2025-03-01
publisher MDPI AG
record_format Article
series Nanomaterials
spelling doaj-art-7ccd2e14f45b46669d6eb799b7af468c2025-08-20T03:43:31ZengMDPI AGNanomaterials2079-49912025-03-0115646310.3390/nano15060463Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>Evelina Pavlovna Domashevskaya0Sergey Alexandrovich Ivkov1Elena Alexandrovna Ganshina2Lyubov Vladimirovna Guda3Valeriy Grigoryevich Vlasenko4Alexander Victorovich Sitnikov5Department of Solid-State Physics and Nanostructures, Voronezh State University, Universitetskaya pl., 1, 394018 Voronezh, RussiaDepartment of Solid-State Physics and Nanostructures, Voronezh State University, Universitetskaya pl., 1, 394018 Voronezh, RussiaDepartment of Magnetism, Faculty of Physics, Lomonosov Moscow State University, Leninskiye Gory B 1-2, GSP-1, 119991 Moscow, RussiaThe Smart Materials Research Institute, South Federal University, St. Sorge, 5, 344090 Rostov-on-Don, RussiaThe Smart Materials Research Institute, South Federal University, St. Sorge, 5, 344090 Rostov-on-Don, RussiaDepartment of Solid State Physics, Faculty of Radio Engineering and Electronics, Voronezh State Technical University, Moskovsky pr., 14, 394026 Voronezh, RussiaBased on modern concepts of the nonlinear percolation mechanisms of electrical and magnetic properties in granular metal–dielectric nanocomposites, the authors present for the first time a comparative analysis of their own results of a comprehensive study of nonlinear electromagnetic properties in two nanocomposite systems: metal–dielectric Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and alloy–dielectric (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>, obtained by ion-beam sputtering of composite targets in a wide range of different compositions. For the first time, the features of the influence of atomic composition and structural-phase transitions on nonlinear magnetoresistive, magnetic, and magneto-optical properties in two systems are presented in comparison, one of which, Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>, showed soft magnetic properties, and the second, (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>, hard magnetic properties, during the transition from the superparamagnetic to the ferromagnetic state. Moreover, for the first time, the concentration dependences of the oscillating fine structure of XANES K-absorption edges of Co atoms in the first system and Co and Fe atoms in the second system are presented, which undergo changes at the percolation thresholds in each of the two systems and thus confirm the nonlinear nature of the electromagnetic properties changes in each of the two systems at the atomic level.https://www.mdpi.com/2079-4991/15/6/463metal–dielectric and alloy–dielectric nanocompositesnanocrystalsphase transformationspercolation thresholdnonlinear propertiessoft and hard magnetic materials
spellingShingle Evelina Pavlovna Domashevskaya
Sergey Alexandrovich Ivkov
Elena Alexandrovna Ganshina
Lyubov Vladimirovna Guda
Valeriy Grigoryevich Vlasenko
Alexander Victorovich Sitnikov
Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>
Nanomaterials
metal–dielectric and alloy–dielectric nanocomposites
nanocrystals
phase transformations
percolation threshold
nonlinear properties
soft and hard magnetic materials
title Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>
title_full Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>
title_fullStr Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>
title_full_unstemmed Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>
title_short Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Co<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub> and (CoFeZr)<sub>x</sub>(MgF<sub>2</sub>)<sub>100−x</sub>
title_sort feature of nonlinear electromagnetic properties and local atomic structure of metals in two systems of nanocomposites co sub x sub mgf sub 2 sub sub 100 x sub and cofezr sub x sub mgf sub 2 sub sub 100 x sub
topic metal–dielectric and alloy–dielectric nanocomposites
nanocrystals
phase transformations
percolation threshold
nonlinear properties
soft and hard magnetic materials
url https://www.mdpi.com/2079-4991/15/6/463
work_keys_str_mv AT evelinapavlovnadomashevskaya featureofnonlinearelectromagneticpropertiesandlocalatomicstructureofmetalsintwosystemsofnanocompositescosubxsubmgfsub2subsub100xsubandcofezrsubxsubmgfsub2subsub100xsub
AT sergeyalexandrovichivkov featureofnonlinearelectromagneticpropertiesandlocalatomicstructureofmetalsintwosystemsofnanocompositescosubxsubmgfsub2subsub100xsubandcofezrsubxsubmgfsub2subsub100xsub
AT elenaalexandrovnaganshina featureofnonlinearelectromagneticpropertiesandlocalatomicstructureofmetalsintwosystemsofnanocompositescosubxsubmgfsub2subsub100xsubandcofezrsubxsubmgfsub2subsub100xsub
AT lyubovvladimirovnaguda featureofnonlinearelectromagneticpropertiesandlocalatomicstructureofmetalsintwosystemsofnanocompositescosubxsubmgfsub2subsub100xsubandcofezrsubxsubmgfsub2subsub100xsub
AT valeriygrigoryevichvlasenko featureofnonlinearelectromagneticpropertiesandlocalatomicstructureofmetalsintwosystemsofnanocompositescosubxsubmgfsub2subsub100xsubandcofezrsubxsubmgfsub2subsub100xsub
AT alexandervictorovichsitnikov featureofnonlinearelectromagneticpropertiesandlocalatomicstructureofmetalsintwosystemsofnanocompositescosubxsubmgfsub2subsub100xsubandcofezrsubxsubmgfsub2subsub100xsub