Adsorption of Boron by Metallurgical Slag and Iron Nanoparticles

Boron is a problematic pollutant because of the difficulty involved in removing it from water with an acceptable cost-to-benefit ratio, especially at extremely high concentrations (600 mg B/l). It is also necessary to remove the pollutant to comply with the quality criteria for drinking water (1 mg...

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Main Authors: B.M. Mercado-Borrayo, R. Schouwenaars, M.I. Litter, R.M. Ramirez-Zamora
Format: Article
Language:English
Published: SAGE Publishing 2014-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.32.2-3.117
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author B.M. Mercado-Borrayo
R. Schouwenaars
M.I. Litter
R.M. Ramirez-Zamora
author_facet B.M. Mercado-Borrayo
R. Schouwenaars
M.I. Litter
R.M. Ramirez-Zamora
author_sort B.M. Mercado-Borrayo
collection DOAJ
description Boron is a problematic pollutant because of the difficulty involved in removing it from water with an acceptable cost-to-benefit ratio, especially at extremely high concentrations (600 mg B/l). It is also necessary to remove the pollutant to comply with the quality criteria for drinking water (1 mg B/l) and even for agricultural irrigation purposes (0.5–15 mg B/l depending on crop tolerance). Although some newly proposed water-treatment technologies use economical adsorbents, they are unable to achieve the residual concentrations. The aim of this work is to show that adsorption using metallurgical slags (SL) can be used either as a pre-treatment of the zero-valent iron nanoparticles (nano-Fe 0 ) or as a final treatment itself for removing boron at high concentrations to obtain effluents complying with the standards established for drinking water and wastewater reuse. Adsorption tests (kinetics and isotherms) were carried out for both adsorbents. The slags showed good results as an adsorbent for boron removal in the pre-treatment and final treatment stages, with a very low cost compared with nano-Fe 0 . The use of slags instead of expensive commercial adsorbents makes adsorption of water with high boron concentrations feasible, and allows obtaining treated wastewater for agricultural irrigation of very tolerant crops.
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institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2014-03-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-79a71cab998247878559da20c2243f1d2025-01-02T22:37:41ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382014-03-013210.1260/0263-6174.32.2-3.117Adsorption of Boron by Metallurgical Slag and Iron NanoparticlesB.M. Mercado-Borrayo0R. Schouwenaars1M.I. Litter2R.M. Ramirez-Zamora3 Instituto de Ingeniería, Coordinación de Ingeniería Ambiental, Universidad Nacional Autónoma de México (UNAM), Coyoacán 04510, DF, Mexico Facultad de Ingeniería, Departamento de Materiales y Manufactura, DIMEI, Universidad Nacional Autónoma de México, Coyoacán 04510, DF, Mexico Comisión Nacional de Energía Atómica, San Martín, Provincia de Buenos Aires, 1650, Argentina Instituto de Ingeniería, Coordinación de Ingeniería Ambiental, Universidad Nacional Autónoma de México (UNAM), Coyoacán 04510, DF, MexicoBoron is a problematic pollutant because of the difficulty involved in removing it from water with an acceptable cost-to-benefit ratio, especially at extremely high concentrations (600 mg B/l). It is also necessary to remove the pollutant to comply with the quality criteria for drinking water (1 mg B/l) and even for agricultural irrigation purposes (0.5–15 mg B/l depending on crop tolerance). Although some newly proposed water-treatment technologies use economical adsorbents, they are unable to achieve the residual concentrations. The aim of this work is to show that adsorption using metallurgical slags (SL) can be used either as a pre-treatment of the zero-valent iron nanoparticles (nano-Fe 0 ) or as a final treatment itself for removing boron at high concentrations to obtain effluents complying with the standards established for drinking water and wastewater reuse. Adsorption tests (kinetics and isotherms) were carried out for both adsorbents. The slags showed good results as an adsorbent for boron removal in the pre-treatment and final treatment stages, with a very low cost compared with nano-Fe 0 . The use of slags instead of expensive commercial adsorbents makes adsorption of water with high boron concentrations feasible, and allows obtaining treated wastewater for agricultural irrigation of very tolerant crops.https://doi.org/10.1260/0263-6174.32.2-3.117
spellingShingle B.M. Mercado-Borrayo
R. Schouwenaars
M.I. Litter
R.M. Ramirez-Zamora
Adsorption of Boron by Metallurgical Slag and Iron Nanoparticles
Adsorption Science & Technology
title Adsorption of Boron by Metallurgical Slag and Iron Nanoparticles
title_full Adsorption of Boron by Metallurgical Slag and Iron Nanoparticles
title_fullStr Adsorption of Boron by Metallurgical Slag and Iron Nanoparticles
title_full_unstemmed Adsorption of Boron by Metallurgical Slag and Iron Nanoparticles
title_short Adsorption of Boron by Metallurgical Slag and Iron Nanoparticles
title_sort adsorption of boron by metallurgical slag and iron nanoparticles
url https://doi.org/10.1260/0263-6174.32.2-3.117
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AT rschouwenaars adsorptionofboronbymetallurgicalslagandironnanoparticles
AT militter adsorptionofboronbymetallurgicalslagandironnanoparticles
AT rmramirezzamora adsorptionofboronbymetallurgicalslagandironnanoparticles