Investigating dutasteride fluorescence for highly sensitive analytical profit

Abstract For the first time, an extremely rapid and sensitive simple spectrofluorometric method was developed based on measuring the native fluorescence of dutasteride (DUT) in acetonitrile. Following its excitation at 245 nm, the intensity of the fluorescence was measured at 325 nm. The linearity l...

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Main Authors: Mariam Rashad, Fawzi Elsebaei, Zeinab Sheribah, Mohamed Walash
Format: Article
Language:English
Published: Springer 2025-05-01
Series:Discover Chemistry
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Online Access:https://doi.org/10.1007/s44371-025-00192-1
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author Mariam Rashad
Fawzi Elsebaei
Zeinab Sheribah
Mohamed Walash
author_facet Mariam Rashad
Fawzi Elsebaei
Zeinab Sheribah
Mohamed Walash
author_sort Mariam Rashad
collection DOAJ
description Abstract For the first time, an extremely rapid and sensitive simple spectrofluorometric method was developed based on measuring the native fluorescence of dutasteride (DUT) in acetonitrile. Following its excitation at 245 nm, the intensity of the fluorescence was measured at 325 nm. The linearity lies in the range of 20.0–600.0 ng mL−1. The developed method was optimized and validated in compliance with ICH guidelines. This abstract follows reviewer recommendations. For the first time, an extremely rapid, eco-friendly, cost-effective, accurate, sensitive, and simple spectrofluorometric method was developed based on measuring the native fluorescence of dutasteride (DUT) used in the treatment of benign prostatic hyperplasia (BPH) in acetonitrile (ACN) as the diluting solvent. Following its excitation at 245 nm, the intensity of the fluorescence emission was measured at 325 nm. The linearity lies in the range of 20.0–600.0 ng mL⁻1 without the use of any surfactant or buffer at room temperature. It was also applied on a prepared tablet. The developed method was optimized and validated in compliance with ICH guidelines. Dutasteride (DUT) estimation using the suggested approach was found to be precise, accurate, robust, specific, and sensitive. In addition, we used some of the greenness assessment and environmental safety methods, such as AGREE and Analytical Eco Scale, to prove its ecological capability in terms of solvent, chemical, energy consumption, and waste generation.
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spelling doaj-art-767b51e25d8a4f55bbf61f813af6c10c2025-08-20T03:09:19ZengSpringerDiscover Chemistry3005-11932025-05-012111010.1007/s44371-025-00192-1Investigating dutasteride fluorescence for highly sensitive analytical profitMariam Rashad0Fawzi Elsebaei1Zeinab Sheribah2Mohamed Walash3Faculty of Pharmacy, Pharmaceutical Analytical Chemistry Department, Mansoura UniversityFaculty of Pharmacy, Pharmaceutical Analytical Chemistry Department, Mansoura UniversityFaculty of Pharmacy, Pharmaceutical Analytical Chemistry Department, Mansoura UniversityFaculty of Pharmacy, Pharmaceutical Analytical Chemistry Department, Mansoura UniversityAbstract For the first time, an extremely rapid and sensitive simple spectrofluorometric method was developed based on measuring the native fluorescence of dutasteride (DUT) in acetonitrile. Following its excitation at 245 nm, the intensity of the fluorescence was measured at 325 nm. The linearity lies in the range of 20.0–600.0 ng mL−1. The developed method was optimized and validated in compliance with ICH guidelines. This abstract follows reviewer recommendations. For the first time, an extremely rapid, eco-friendly, cost-effective, accurate, sensitive, and simple spectrofluorometric method was developed based on measuring the native fluorescence of dutasteride (DUT) used in the treatment of benign prostatic hyperplasia (BPH) in acetonitrile (ACN) as the diluting solvent. Following its excitation at 245 nm, the intensity of the fluorescence emission was measured at 325 nm. The linearity lies in the range of 20.0–600.0 ng mL⁻1 without the use of any surfactant or buffer at room temperature. It was also applied on a prepared tablet. The developed method was optimized and validated in compliance with ICH guidelines. Dutasteride (DUT) estimation using the suggested approach was found to be precise, accurate, robust, specific, and sensitive. In addition, we used some of the greenness assessment and environmental safety methods, such as AGREE and Analytical Eco Scale, to prove its ecological capability in terms of solvent, chemical, energy consumption, and waste generation.https://doi.org/10.1007/s44371-025-00192-1DutasterideFluorescenceBenign prostatic hyperplasiaPharmaceuticalPrepared tabletNative
spellingShingle Mariam Rashad
Fawzi Elsebaei
Zeinab Sheribah
Mohamed Walash
Investigating dutasteride fluorescence for highly sensitive analytical profit
Discover Chemistry
Dutasteride
Fluorescence
Benign prostatic hyperplasia
Pharmaceutical
Prepared tablet
Native
title Investigating dutasteride fluorescence for highly sensitive analytical profit
title_full Investigating dutasteride fluorescence for highly sensitive analytical profit
title_fullStr Investigating dutasteride fluorescence for highly sensitive analytical profit
title_full_unstemmed Investigating dutasteride fluorescence for highly sensitive analytical profit
title_short Investigating dutasteride fluorescence for highly sensitive analytical profit
title_sort investigating dutasteride fluorescence for highly sensitive analytical profit
topic Dutasteride
Fluorescence
Benign prostatic hyperplasia
Pharmaceutical
Prepared tablet
Native
url https://doi.org/10.1007/s44371-025-00192-1
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AT fawzielsebaei investigatingdutasteridefluorescenceforhighlysensitiveanalyticalprofit
AT zeinabsheribah investigatingdutasteridefluorescenceforhighlysensitiveanalyticalprofit
AT mohamedwalash investigatingdutasteridefluorescenceforhighlysensitiveanalyticalprofit