Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistance
Recently, laser surface modification has emerged as a promising approach to improve the mechanical features of titanium (Ti), such as corrosion and wear resistance, as well as hardness. In this study, a simple, environmentally friendly, controllable, and cost-effective pulsed laser ablation (PLA) me...
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Elsevier
2025-03-01
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| Series: | Journal of Materials Research and Technology |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S223878542403028X |
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| author | Ensiye Shabanlou Babak Jaleh Maryam Molaei Mohammad Kashfi Saeid Azizian Arash Fattah-Alhosseini Kyong Yop Rhee |
| author_facet | Ensiye Shabanlou Babak Jaleh Maryam Molaei Mohammad Kashfi Saeid Azizian Arash Fattah-Alhosseini Kyong Yop Rhee |
| author_sort | Ensiye Shabanlou |
| collection | DOAJ |
| description | Recently, laser surface modification has emerged as a promising approach to improve the mechanical features of titanium (Ti), such as corrosion and wear resistance, as well as hardness. In this study, a simple, environmentally friendly, controllable, and cost-effective pulsed laser ablation (PLA) method was applied to form the titanium dioxide (TiO2) ceramic structure on the surface of Ti metal. For the first time, hydrogen peroxide (H2O2) was used as an irradiation environment to modify the surface properties of Ti. The effects of different numbers of laser scanning cycles on the generated TiO2 structures and their corrosion behaviors were studied. The ablated samples were characterized using X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The results confirmed the fabrication of the monoclinic TiO2-B structure (bronze phase of TiO2) for all numbers of laser scanning cycles. The TiO2-B structure formed on the Ti surface after PLA positively affected its wear and corrosion resistances in Ringer's solution. Therefore, laser ablation of Ti in H2O2 aqueous solution is a facile approach to form stable TiO2-B and it improves the wear and corrosion resistances of Ti. |
| format | Article |
| id | doaj-art-767a0aa756e041f484184dd42a266af2 |
| institution | Kabale University |
| issn | 2238-7854 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materials Research and Technology |
| spelling | doaj-art-767a0aa756e041f484184dd42a266af22025-01-09T06:14:04ZengElsevierJournal of Materials Research and Technology2238-78542025-03-0135119129Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistanceEnsiye Shabanlou0Babak Jaleh1Maryam Molaei2Mohammad Kashfi3Saeid Azizian4Arash Fattah-Alhosseini5Kyong Yop Rhee6Department of Physics, Faculty of Science, Bu-Ali Sina University, Hamedan, 65174, IranDepartment of Physics, Faculty of Science, Bu-Ali Sina University, Hamedan, 65174, Iran; Corresponding author.Department of Materials Engineering, Faculty of Engineering, Bu-Ali Sina University, Hamedan, IranDepartment of Mechanical Engineering, Faculty of Engineering, Ayatollah Boroujerdi University, Boroujerd, IranDepartment of Physical Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, IranDepartment of Materials Engineering, Faculty of Engineering, Bu-Ali Sina University, Hamedan, IranDepartment of Mechanical Engineering, Kyung Hee University, 17104, Yongin, Republic of Korea; Corresponding author.Recently, laser surface modification has emerged as a promising approach to improve the mechanical features of titanium (Ti), such as corrosion and wear resistance, as well as hardness. In this study, a simple, environmentally friendly, controllable, and cost-effective pulsed laser ablation (PLA) method was applied to form the titanium dioxide (TiO2) ceramic structure on the surface of Ti metal. For the first time, hydrogen peroxide (H2O2) was used as an irradiation environment to modify the surface properties of Ti. The effects of different numbers of laser scanning cycles on the generated TiO2 structures and their corrosion behaviors were studied. The ablated samples were characterized using X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The results confirmed the fabrication of the monoclinic TiO2-B structure (bronze phase of TiO2) for all numbers of laser scanning cycles. The TiO2-B structure formed on the Ti surface after PLA positively affected its wear and corrosion resistances in Ringer's solution. Therefore, laser ablation of Ti in H2O2 aqueous solution is a facile approach to form stable TiO2-B and it improves the wear and corrosion resistances of Ti.http://www.sciencedirect.com/science/article/pii/S223878542403028XSurface treatmentTitanium dioxide (TiO2)Monoclinic TiO2-BCorrosionPulsed laser ablation in liquid (PLAL)Hydrogen peroxide (H2O2) |
| spellingShingle | Ensiye Shabanlou Babak Jaleh Maryam Molaei Mohammad Kashfi Saeid Azizian Arash Fattah-Alhosseini Kyong Yop Rhee Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistance Journal of Materials Research and Technology Surface treatment Titanium dioxide (TiO2) Monoclinic TiO2-B Corrosion Pulsed laser ablation in liquid (PLAL) Hydrogen peroxide (H2O2) |
| title | Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistance |
| title_full | Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistance |
| title_fullStr | Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistance |
| title_full_unstemmed | Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistance |
| title_short | Enhancing surface properties of Ti via pulsed laser ablation in H2O2: Formation of stable TiO2-B structure with improved corrosion and wear resistance |
| title_sort | enhancing surface properties of ti via pulsed laser ablation in h2o2 formation of stable tio2 b structure with improved corrosion and wear resistance |
| topic | Surface treatment Titanium dioxide (TiO2) Monoclinic TiO2-B Corrosion Pulsed laser ablation in liquid (PLAL) Hydrogen peroxide (H2O2) |
| url | http://www.sciencedirect.com/science/article/pii/S223878542403028X |
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