Discharge performance of Mg–Zn–Y alloys by regulating quasicrystal I phase as anodes for Mg-air battery

To investigate the influence of the morphology and amount of quasicrystal I phase on discharge performance, a comparative study is conducted on the discharge characteristics of Mg-2.4Zn-0.4Y (ZW-1), Mg-3.6Zn-0.6Y (ZW-2), and Mg-4.8Zn-0.8Y (ZW-3). As the content of Zn and Y rises, the amount of quasi...

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Bibliographic Details
Main Authors: Wenhao Li, Kaibo Nie, Kunkun Deng, Quanxin Shi
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425000602
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Summary:To investigate the influence of the morphology and amount of quasicrystal I phase on discharge performance, a comparative study is conducted on the discharge characteristics of Mg-2.4Zn-0.4Y (ZW-1), Mg-3.6Zn-0.6Y (ZW-2), and Mg-4.8Zn-0.8Y (ZW-3). As the content of Zn and Y rises, the amount of quasicrystal I phase increases, and its morphology transforms from dot-like to strip-like structures. ZW-1 exhibits the best corrosion resistance and discharge performance, followed by ZW-2, with ZW-3 performing the worst. Based on the electrochemical results and characterization, the quasicrystal I phase can enhance the dissolution of the magnesium anode throughout the discharge process. Nonetheless, an excess of the quasicrystal I phase increases galvanic corrosion, leading to unstable discharge voltage and reduced anode efficiency.
ISSN:2238-7854