Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)

In this study, silica sands from the commune of Houéyogbé were used to synthesize silica particles by the sol-gel method, using sodium silicate as the reaction precursor. Analysis by X-ray diffraction, infrared spectroscopy, and scanning electron microscopy revealed the formation of pure amorphous s...

Full description

Saved in:
Bibliographic Details
Main Authors: Houefaannick Leslie Glitho, Etienne V. Sagbo, Sèmiyou A. Osseni, Sidoine S. Bonou, Arthur Cakpo, Ignace Agani, Armel Laibi, Wariskéwouyèmi Chouti
Format: Article
Language:English
Published: Iranian Environmental Mutagen Society 2024-11-01
Series:Journal of Water and Environmental Nanotechnology
Subjects:
Online Access:https://www.jwent.net/article_718458_eaeba4265a978a715c73fccbdf8b06b3.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1841545203758923776
author Houefaannick Leslie Glitho
Etienne V. Sagbo
Sèmiyou A. Osseni
Sidoine S. Bonou
Arthur Cakpo
Ignace Agani
Armel Laibi
Wariskéwouyèmi Chouti
author_facet Houefaannick Leslie Glitho
Etienne V. Sagbo
Sèmiyou A. Osseni
Sidoine S. Bonou
Arthur Cakpo
Ignace Agani
Armel Laibi
Wariskéwouyèmi Chouti
author_sort Houefaannick Leslie Glitho
collection DOAJ
description In this study, silica sands from the commune of Houéyogbé were used to synthesize silica particles by the sol-gel method, using sodium silicate as the reaction precursor. Analysis by X-ray diffraction, infrared spectroscopy, and scanning electron microscopy revealed the formation of pure amorphous silica with spherical shapes. This material was used as an adsorbent to remove 2,4-dichlorophenoxyacetic acid, one of the pesticides most widely used by farmers in Benin. The use of pesticides is a major environmental problem due to their toxicity. Pesticides pollute soils, surface, and groundwater, and it is, therefore, important to find a way of mitigating or even eliminating their effects on the environment. Adsorption tests for this pollutant were carried out in batch mode. The adsorption study showed a maximum of over 90%. The kinetic study indicates that adsorption is effective from the first five (5) minutes and becomes established after one hour. The L-type adsorption isotherm shows that pesticide adsorption takes place by progressive saturation (monolayer).
format Article
id doaj-art-6e7aa3bba2b74945a920914198510024
institution Kabale University
issn 2476-7204
2476-6615
language English
publishDate 2024-11-01
publisher Iranian Environmental Mutagen Society
record_format Article
series Journal of Water and Environmental Nanotechnology
spelling doaj-art-6e7aa3bba2b74945a9209141985100242025-01-12T09:34:38ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152024-11-019446948010.22090/jwent.2024.04.08718458Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)Houefaannick Leslie Glitho0Etienne V. Sagbo1Sèmiyou A. Osseni2Sidoine S. Bonou3Arthur Cakpo4Ignace Agani5Armel Laibi6Wariskéwouyèmi Chouti7Laboratory of Physical Chemistry, Materials and Molecular Modeling / Unit of Inorganic Chemistry, Materials Engineering and Environment (LCP3M / UCIIME), Faculty of Science and Technology (FAST), University of Abomey-Calavi (UAC), BeninLaboratory of Physical Chemistry, Materials and Molecular Modeling / Unit of Inorganic Chemistry, Materials Engineering and Environment (LCP3M / UCIIME), Faculty of Science and Technology (FAST), University of Abomey-Calavi (UAC), BeninLaboratory of Physical Chemistry, Materials and Molecular Modeling / Unit of Inorganic Chemistry, Materials Engineering and Environment (LCP3M / UCIIME), Faculty of Science and Technology (FAST), University of Abomey-Calavi (UAC), BeninLaboratory of Physical Chemistry, Materials and Molecular Modeling / Unit of Inorganic Chemistry, Materials Engineering and Environment (LCP3M / UCIIME), Faculty of Science and Technology (FAST), University of Abomey-Calavi (UAC), BeninLaboratory of Physical Chemistry, Materials and Molecular Modeling / Unit of Inorganic Chemistry, Materials Engineering and Environment (LCP3M / UCIIME), Faculty of Science and Technology (FAST), University of Abomey-Calavi (UAC), BeninKaba Chemistry and Applications Research Laboratory, Faculty of Sciences and Technologies of Natitingou/UNSTIM, Benin.Laboratory of Physical Chemistry, Materials and Molecular Modeling / Unit of Inorganic Chemistry, Materials Engineering and Environment (LCP3M / UCIIME), Faculty of Science and Technology (FAST), University of Abomey-Calavi (UAC), BeninLaboratory of Physical Chemistry, Materials and Molecular Modeling / Unit of Inorganic Chemistry, Materials Engineering and Environment (LCP3M / UCIIME), Faculty of Science and Technology (FAST), University of Abomey-Calavi (UAC), BeninIn this study, silica sands from the commune of Houéyogbé were used to synthesize silica particles by the sol-gel method, using sodium silicate as the reaction precursor. Analysis by X-ray diffraction, infrared spectroscopy, and scanning electron microscopy revealed the formation of pure amorphous silica with spherical shapes. This material was used as an adsorbent to remove 2,4-dichlorophenoxyacetic acid, one of the pesticides most widely used by farmers in Benin. The use of pesticides is a major environmental problem due to their toxicity. Pesticides pollute soils, surface, and groundwater, and it is, therefore, important to find a way of mitigating or even eliminating their effects on the environment. Adsorption tests for this pollutant were carried out in batch mode. The adsorption study showed a maximum of over 90%. The kinetic study indicates that adsorption is effective from the first five (5) minutes and becomes established after one hour. The L-type adsorption isotherm shows that pesticide adsorption takes place by progressive saturation (monolayer).https://www.jwent.net/article_718458_eaeba4265a978a715c73fccbdf8b06b3.pdfbeninsilicasol-gel24-d acidadsorption
spellingShingle Houefaannick Leslie Glitho
Etienne V. Sagbo
Sèmiyou A. Osseni
Sidoine S. Bonou
Arthur Cakpo
Ignace Agani
Armel Laibi
Wariskéwouyèmi Chouti
Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)
Journal of Water and Environmental Nanotechnology
benin
silica
sol-gel
2
4-d acid
adsorption
title Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)
title_full Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)
title_fullStr Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)
title_full_unstemmed Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)
title_short Removal of 2,4-Dichloro Phenoxy Acetic Acid by Silica Particles Obtained from the Siliceous Sand of Houeyogbe(Republic of Benin)
title_sort removal of 2 4 dichloro phenoxy acetic acid by silica particles obtained from the siliceous sand of houeyogbe republic of benin
topic benin
silica
sol-gel
2
4-d acid
adsorption
url https://www.jwent.net/article_718458_eaeba4265a978a715c73fccbdf8b06b3.pdf
work_keys_str_mv AT houefaannickleslieglitho removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin
AT etiennevsagbo removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin
AT semiyouaosseni removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin
AT sidoinesbonou removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin
AT arthurcakpo removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin
AT ignaceagani removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin
AT armellaibi removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin
AT wariskewouyemichouti removalof24dichlorophenoxyaceticacidbysilicaparticlesobtainedfromthesiliceoussandofhoueyogberepublicofbenin