Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactor
This experimental study uses a modified homemade novel nano-catalyst (8 %Mn3O4/AC-nanoparticles) to explore the oxidative desulfurization (ODS) process in a digital baffle batch reactor (DBBR) to remove sulfur compounds from light gas oil. With its efficient impregnation, high activity, excellent di...
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| Format: | Article |
| Language: | English |
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Elsevier
2025-04-01
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| Series: | South African Journal of Chemical Engineering |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S1026918525000046 |
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| author | Amer T. Nawaf Jasim I. Humadi Ali A. Hassan Mohamed A. Habila Rajesh Haldhar |
| author_facet | Amer T. Nawaf Jasim I. Humadi Ali A. Hassan Mohamed A. Habila Rajesh Haldhar |
| author_sort | Amer T. Nawaf |
| collection | DOAJ |
| description | This experimental study uses a modified homemade novel nano-catalyst (8 %Mn3O4/AC-nanoparticles) to explore the oxidative desulfurization (ODS) process in a digital baffle batch reactor (DBBR) to remove sulfur compounds from light gas oil. With its efficient impregnation, high activity, excellent distribution of pore sizes, and increased surface area, the manganese oxide nano-catalyst design supported on activated nanoparticles exhibits exceptional catalytic performance. To gain a greater understanding of the ODS process, moderate operating conditions are used at various reaction temperatures, reaction times, and oxidant amounts. Results of the experiment indicate that increasing the temperature, batch reaction, and oxidant quantity increases the conversion of sulfur compounds. It has been determined that the novel nano-catalysts are 93.33 % effective at removing sulfur at a reaction temperature of 90 °C, a batch time of 45 min, and an oxidant agent amount of 5 ml from H2O2. |
| format | Article |
| id | doaj-art-69397086623544ac8a1549bcd3c7ee91 |
| institution | Kabale University |
| issn | 1026-9185 |
| language | English |
| publishDate | 2025-04-01 |
| publisher | Elsevier |
| record_format | Article |
| series | South African Journal of Chemical Engineering |
| spelling | doaj-art-69397086623544ac8a1549bcd3c7ee912025-01-16T04:28:21ZengElsevierSouth African Journal of Chemical Engineering1026-91852025-04-0152819Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactorAmer T. Nawaf0Jasim I. Humadi1Ali A. Hassan2Mohamed A. Habila3Rajesh Haldhar4Department of Petroleum and Gas Refining Engineering, College of Petroleum Processes Engineering, Tikrit University, Tikrit, Iraq; Corresponding author.Department of Petroleum and Gas Refining Engineering, College of Petroleum Processes Engineering, Tikrit University, Tikrit, Iraq; Corresponding author.Chemical Department, College of Engineering, University of Muthanna, Muthanna, Iraq; Petroleum Department, College of Engineering, Al-Ayen University, Thi-Qar, IraqDepartment of Chemistry, College of Science, King Saud University, P. O. Box 2455, Riyadh, 11451, Saudi ArabiaSchool of Chemical Engineering, Yeungnam University, Gyeongsan, 35841, Republic of Korea; Corresponding author.This experimental study uses a modified homemade novel nano-catalyst (8 %Mn3O4/AC-nanoparticles) to explore the oxidative desulfurization (ODS) process in a digital baffle batch reactor (DBBR) to remove sulfur compounds from light gas oil. With its efficient impregnation, high activity, excellent distribution of pore sizes, and increased surface area, the manganese oxide nano-catalyst design supported on activated nanoparticles exhibits exceptional catalytic performance. To gain a greater understanding of the ODS process, moderate operating conditions are used at various reaction temperatures, reaction times, and oxidant amounts. Results of the experiment indicate that increasing the temperature, batch reaction, and oxidant quantity increases the conversion of sulfur compounds. It has been determined that the novel nano-catalysts are 93.33 % effective at removing sulfur at a reaction temperature of 90 °C, a batch time of 45 min, and an oxidant agent amount of 5 ml from H2O2.http://www.sciencedirect.com/science/article/pii/S1026918525000046New designManganese oxideOxidative desulfurizationDbbr reactorHydrogene oxide |
| spellingShingle | Amer T. Nawaf Jasim I. Humadi Ali A. Hassan Mohamed A. Habila Rajesh Haldhar Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactor South African Journal of Chemical Engineering New design Manganese oxide Oxidative desulfurization Dbbr reactor Hydrogene oxide |
| title | Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactor |
| title_full | Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactor |
| title_fullStr | Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactor |
| title_full_unstemmed | Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactor |
| title_short | Improving of fuel quality and environment using new synthetic (Mn3O4/AC-nano-particles) for oxidative desulfurization using digital baffle batch reactor |
| title_sort | improving of fuel quality and environment using new synthetic mn3o4 ac nano particles for oxidative desulfurization using digital baffle batch reactor |
| topic | New design Manganese oxide Oxidative desulfurization Dbbr reactor Hydrogene oxide |
| url | http://www.sciencedirect.com/science/article/pii/S1026918525000046 |
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