Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium Alloy

The active properties,easy oxidation and poor corrosion resistance of AZ31 magnesium alloy have always been the biggest challenges in its practical application.In order to improve its corrosion resistance, reduce the corrosion rate and prolong its service life, a stable and corrosion-resistant alumi...

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Main Author: LUO Zhonglong, ZHU Li, ZHANG Peng, RAO Sixian
Format: Article
Language:zho
Published: Editorial Department of Materials Protection 2024-12-01
Series:Cailiao Baohu
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Online Access:http://www.mat-pro.com/fileup/1001-1560/PDF/20241203.pdf
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author LUO Zhonglong, ZHU Li, ZHANG Peng, RAO Sixian
author_facet LUO Zhonglong, ZHU Li, ZHANG Peng, RAO Sixian
author_sort LUO Zhonglong, ZHU Li, ZHANG Peng, RAO Sixian
collection DOAJ
description The active properties,easy oxidation and poor corrosion resistance of AZ31 magnesium alloy have always been the biggest challenges in its practical application.In order to improve its corrosion resistance, reduce the corrosion rate and prolong its service life, a stable and corrosion-resistant aluminum phosphate-polymethyl methacrylate (AP/PMMA) superhydrophobic coating was prepared on the surface by impregnation method.The microstructure, chemical composition, phase composition and molecular structure of the coating were analyzed by scanning electron microscope (SEM),X-ray energy dispersive spectrometer (EDS),X-ray diffractometer (XRD) and Fourier transform infrared spectrometer (FTIR).Moreover, the hydrophobicity and corrosion resistance were tested by contact angle meter (CA), Tafel curve and EIS.Results showed that with the increase of immersion time, the contact angle (WCA) of the coating increased first and then decreased.The surface contact angle of the coating prepared by the 60 s immersion sample could reach 154.7 °, showing superhydrophobicity.The surface corrosion current density was 2.289 × 10-9 A/cm2, which was 4 orders of magnitude lower than that of the magnesium substrate.The corrosion potential was increased from-0.941 V to-0.735 V after polishing, indicating that the AP/PMMA superhydrophobic coating could effectively improve the corrosion resistance of AZ31 magnesium alloy.
format Article
id doaj-art-68c7ae48aecd42849c0a7b4557a7fd79
institution Kabale University
issn 1001-1560
language zho
publishDate 2024-12-01
publisher Editorial Department of Materials Protection
record_format Article
series Cailiao Baohu
spelling doaj-art-68c7ae48aecd42849c0a7b4557a7fd792025-01-14T07:51:35ZzhoEditorial Department of Materials ProtectionCailiao Baohu1001-15602024-12-015712172610.16577/j.issn.1001-1560.2024.0266Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium AlloyLUO Zhonglong, ZHU Li, ZHANG Peng, RAO Sixian0(School of Mechanical Engineering, Anhui University of Technology, Ma’ anshan 243002, China)The active properties,easy oxidation and poor corrosion resistance of AZ31 magnesium alloy have always been the biggest challenges in its practical application.In order to improve its corrosion resistance, reduce the corrosion rate and prolong its service life, a stable and corrosion-resistant aluminum phosphate-polymethyl methacrylate (AP/PMMA) superhydrophobic coating was prepared on the surface by impregnation method.The microstructure, chemical composition, phase composition and molecular structure of the coating were analyzed by scanning electron microscope (SEM),X-ray energy dispersive spectrometer (EDS),X-ray diffractometer (XRD) and Fourier transform infrared spectrometer (FTIR).Moreover, the hydrophobicity and corrosion resistance were tested by contact angle meter (CA), Tafel curve and EIS.Results showed that with the increase of immersion time, the contact angle (WCA) of the coating increased first and then decreased.The surface contact angle of the coating prepared by the 60 s immersion sample could reach 154.7 °, showing superhydrophobicity.The surface corrosion current density was 2.289 × 10-9 A/cm2, which was 4 orders of magnitude lower than that of the magnesium substrate.The corrosion potential was increased from-0.941 V to-0.735 V after polishing, indicating that the AP/PMMA superhydrophobic coating could effectively improve the corrosion resistance of AZ31 magnesium alloy.http://www.mat-pro.com/fileup/1001-1560/PDF/20241203.pdfaz31 magnesium alloy; superhydrophobic coating; corrosion behavior; soaking method
spellingShingle LUO Zhonglong, ZHU Li, ZHANG Peng, RAO Sixian
Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium Alloy
Cailiao Baohu
az31 magnesium alloy; superhydrophobic coating; corrosion behavior; soaking method
title Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium Alloy
title_full Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium Alloy
title_fullStr Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium Alloy
title_full_unstemmed Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium Alloy
title_short Preparation and Corrosion Resistance of Superhydrophobic Coating on AZ31 Magnesium Alloy
title_sort preparation and corrosion resistance of superhydrophobic coating on az31 magnesium alloy
topic az31 magnesium alloy; superhydrophobic coating; corrosion behavior; soaking method
url http://www.mat-pro.com/fileup/1001-1560/PDF/20241203.pdf
work_keys_str_mv AT luozhonglongzhulizhangpengraosixian preparationandcorrosionresistanceofsuperhydrophobiccoatingonaz31magnesiumalloy