Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United States

Chloride concentrations in surface and groundwater within the Twin Cities Metropolitan Area of Minnesota are increasing and hand-sample monitoring is not sufficient to understand the scale and temporal nuance of chloride concentrations within the aquifer system. We explore the relationships between...

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Main Authors: John R. McDaris, Joshua M. Feinberg, Jonathan Levine, Anthony C. Runkel
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-12-01
Series:Earth Science, Systems and Society
Subjects:
Online Access:https://www.lyellcollection.org/doi/10.3389/esss.2023.10084
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author John R. McDaris
Joshua M. Feinberg
Jonathan Levine
Anthony C. Runkel
author_facet John R. McDaris
Joshua M. Feinberg
Jonathan Levine
Anthony C. Runkel
author_sort John R. McDaris
collection DOAJ
description Chloride concentrations in surface and groundwater within the Twin Cities Metropolitan Area of Minnesota are increasing and hand-sample monitoring is not sufficient to understand the scale and temporal nuance of chloride concentrations within the aquifer system. We explore the relationships between chloride concentration and specific conductance (SC) in regional aquifers as a mechanism to generate a larger quantity of data related to groundwater chloride concentrations at a higher temporal frequency. Paired measurements (N = 2,118) from 1,050 wells collected between 1972 and 2022 allow statistical relationships to be generated for several aquifer units that enable the use of SC as either a direct proxy or qualitative indicator of chloride concentration going forward. In the uppermost unconsolidated Quaternary aquifer and in the immediately underlying bedrock aquifer (Platteville Formation), correlation between chloride concentration and specific conductance imply that conductances of 1,350 and 3,800 μS/cm correspond to state chronic and acute exposure standards of 230 mg/L and 860 mg/L, respectively. SC values have increased through time in bedrock aquifers that provide the region’s largest volume of residential and industrial groundwater (the Prairie du Chien and Jordan aquifers) and interpreting these changes in detail requires consideration of the local hydrogeologic context.
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spelling doaj-art-6486baf6aa6645729941755e29acf8e72025-01-10T14:04:52ZengFrontiers Media S.A.Earth Science, Systems and Society2634-730X2023-12-013110.3389/esss.2023.10084Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United StatesJohn R. McDaris0Joshua M. Feinberg1Jonathan Levine2Anthony C. Runkel31Department of Earth and Environmental Science, University of Minnesota, Minneapolis, MN, United States1Department of Earth and Environmental Science, University of Minnesota, Minneapolis, MN, United States2Department of Physics and Astronomy, Colgate University, Hamilton, NY, United States3Minnesota Geological Survey, University of Minnesota, St. Paul, MN, United StatesChloride concentrations in surface and groundwater within the Twin Cities Metropolitan Area of Minnesota are increasing and hand-sample monitoring is not sufficient to understand the scale and temporal nuance of chloride concentrations within the aquifer system. We explore the relationships between chloride concentration and specific conductance (SC) in regional aquifers as a mechanism to generate a larger quantity of data related to groundwater chloride concentrations at a higher temporal frequency. Paired measurements (N = 2,118) from 1,050 wells collected between 1972 and 2022 allow statistical relationships to be generated for several aquifer units that enable the use of SC as either a direct proxy or qualitative indicator of chloride concentration going forward. In the uppermost unconsolidated Quaternary aquifer and in the immediately underlying bedrock aquifer (Platteville Formation), correlation between chloride concentration and specific conductance imply that conductances of 1,350 and 3,800 μS/cm correspond to state chronic and acute exposure standards of 230 mg/L and 860 mg/L, respectively. SC values have increased through time in bedrock aquifers that provide the region’s largest volume of residential and industrial groundwater (the Prairie du Chien and Jordan aquifers) and interpreting these changes in detail requires consideration of the local hydrogeologic context.https://www.lyellcollection.org/doi/10.3389/esss.2023.10084groundwaterchlorideconductancecontinuous monitoringhydrogeologic context
spellingShingle John R. McDaris
Joshua M. Feinberg
Jonathan Levine
Anthony C. Runkel
Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United States
Earth Science, Systems and Society
groundwater
chloride
conductance
continuous monitoring
hydrogeologic context
title Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United States
title_full Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United States
title_fullStr Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United States
title_full_unstemmed Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United States
title_short Establishing Specific Conductance-Chloride Relationships for Quaternary and Bedrock Aquifers in the Twin Cities Metropolitan Area, Minnesota, United States
title_sort establishing specific conductance chloride relationships for quaternary and bedrock aquifers in the twin cities metropolitan area minnesota united states
topic groundwater
chloride
conductance
continuous monitoring
hydrogeologic context
url https://www.lyellcollection.org/doi/10.3389/esss.2023.10084
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AT joshuamfeinberg establishingspecificconductancechloriderelationshipsforquaternaryandbedrockaquifersinthetwincitiesmetropolitanareaminnesotaunitedstates
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