Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in Iraq

This research evaluates the physical and chemical properties and concentration of trace elements and heavy metals in Iraqi crude oil. The way in which geographical locations affect oil quality is not widely known, especially in the Middle East. Therefore, crude oils from three locations (East Baghda...

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Main Authors: Ahmed Abdulrazzaq Hadi AlGburi, Vikram Rama Uttam Pandit, Ali Khalil kadom, Talib Mohammed Albayati
Format: Article
Language:English
Published: University of Thi-Qar 2024-12-01
Series:مجلة علوم ذي قار
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Online Access:https://jsci.utq.edu.iq/index.php/main/article/view/1326
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author Ahmed Abdulrazzaq Hadi AlGburi
Vikram Rama Uttam Pandit
Ali Khalil kadom
Talib Mohammed Albayati
author_facet Ahmed Abdulrazzaq Hadi AlGburi
Vikram Rama Uttam Pandit
Ali Khalil kadom
Talib Mohammed Albayati
author_sort Ahmed Abdulrazzaq Hadi AlGburi
collection DOAJ
description This research evaluates the physical and chemical properties and concentration of trace elements and heavy metals in Iraqi crude oil. The way in which geographical locations affect oil quality is not widely known, especially in the Middle East. Therefore, crude oils from three locations (East Baghdad, Khurmala, and Nahr Omar) were selected. The physical and chemical data showed apparent variations in the properties of crude oils from different fields. Nahr Umr oil was the lightest (D = 0.8199 g/cm3, API = 40.57°) and the lowest in sulfur content (1.327 wt%), East Baghdad oil was the heaviest (D = 0.9067 g/cm3, API = 24.39°) and the highest in sulfur content (3.842 wt%), while Khurmala  was (D = 0.8518 g/cm3, API = 34.12°) and (2.44 wt%) of sulfur content, reflecting the differences in the quality of crude oils. Advanced techniques such as the rotating disc electrode optical emission spectrometer (RDE-OES) and inductively coupled plasma (ICP-OES/MS) were used to measure the element content after sample preparation using microwave acid digestion. The content of metals in crude oil indicates that East Baghdad oil contains the highest rate of V, Al, Ag, and Hg. At the same time, Ni, Fe, Na, Ca, Pb, Se, and Li were higher in Khurmala oil, while Mo, Ti, Sr, Bi, Ba, and Hg were higher in Nahr Umr. The statistical analysis of the least significant difference (LSD) test was used to show the significant differences between the measured element concentrations at the 0.05 level
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series مجلة علوم ذي قار
spelling doaj-art-63b4cb46963f498caf8af90651c9f4082025-01-17T17:36:21ZengUniversity of Thi-Qarمجلة علوم ذي قار1991-86902709-02562024-12-0111210.32792/utq/utjsci/v11i2.1326Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in IraqAhmed Abdulrazzaq Hadi AlGburi0Vikram Rama Uttam Pandit1 Ali Khalil kadom2Talib Mohammed Albayati3Science Department, College of Basic Education, AlMuthanna University, AlMuthanna, Iraq.Department of Chemistry, PGK Mandals Haribhai V. Desai College, PuneScience Department, College of Basic Education, AlMuthanna University,Department of Chemical Engineering, University of Technology-IraqThis research evaluates the physical and chemical properties and concentration of trace elements and heavy metals in Iraqi crude oil. The way in which geographical locations affect oil quality is not widely known, especially in the Middle East. Therefore, crude oils from three locations (East Baghdad, Khurmala, and Nahr Omar) were selected. The physical and chemical data showed apparent variations in the properties of crude oils from different fields. Nahr Umr oil was the lightest (D = 0.8199 g/cm3, API = 40.57°) and the lowest in sulfur content (1.327 wt%), East Baghdad oil was the heaviest (D = 0.9067 g/cm3, API = 24.39°) and the highest in sulfur content (3.842 wt%), while Khurmala  was (D = 0.8518 g/cm3, API = 34.12°) and (2.44 wt%) of sulfur content, reflecting the differences in the quality of crude oils. Advanced techniques such as the rotating disc electrode optical emission spectrometer (RDE-OES) and inductively coupled plasma (ICP-OES/MS) were used to measure the element content after sample preparation using microwave acid digestion. The content of metals in crude oil indicates that East Baghdad oil contains the highest rate of V, Al, Ag, and Hg. At the same time, Ni, Fe, Na, Ca, Pb, Se, and Li were higher in Khurmala oil, while Mo, Ti, Sr, Bi, Ba, and Hg were higher in Nahr Umr. The statistical analysis of the least significant difference (LSD) test was used to show the significant differences between the measured element concentrations at the 0.05 level https://jsci.utq.edu.iq/index.php/main/article/view/1326Crude Oil Quality; Physicochemical Parameters; Wear Metals; Heavy metals, ICP-OES and ICP-MS.
spellingShingle Ahmed Abdulrazzaq Hadi AlGburi
Vikram Rama Uttam Pandit
Ali Khalil kadom
Talib Mohammed Albayati
Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in Iraq
مجلة علوم ذي قار
Crude Oil Quality; Physicochemical Parameters; Wear Metals; Heavy metals, ICP-OES and ICP-MS.
title Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in Iraq
title_full Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in Iraq
title_fullStr Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in Iraq
title_full_unstemmed Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in Iraq
title_short Comparative Study of Physicochemical Properties and Metal Contents in Crude Oil from Different Fields in Iraq
title_sort comparative study of physicochemical properties and metal contents in crude oil from different fields in iraq
topic Crude Oil Quality; Physicochemical Parameters; Wear Metals; Heavy metals, ICP-OES and ICP-MS.
url https://jsci.utq.edu.iq/index.php/main/article/view/1326
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