ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systems

Abstract This work evaluates the use of zinc oxide nanorods as intensifiers of a latent heat thermal energy storage system working with adipic acid as the phase change material (PCM). By virtue of not participating directly in the solid–liquid and liquid–solid phase transition, ZnO-adipic acid compo...

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Main Authors: N. R. Snekha, V. Hari Suthan, K. S. Suganthi, S. Naren Raggavendra, S. Sudharsan, R. Aishwarya, K. S. Rajan
Format: Article
Language:English
Published: SpringerOpen 2024-11-01
Series:Micro and Nano Systems Letters
Subjects:
Online Access:https://doi.org/10.1186/s40486-024-00212-2
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author N. R. Snekha
V. Hari Suthan
K. S. Suganthi
S. Naren Raggavendra
S. Sudharsan
R. Aishwarya
K. S. Rajan
author_facet N. R. Snekha
V. Hari Suthan
K. S. Suganthi
S. Naren Raggavendra
S. Sudharsan
R. Aishwarya
K. S. Rajan
author_sort N. R. Snekha
collection DOAJ
description Abstract This work evaluates the use of zinc oxide nanorods as intensifiers of a latent heat thermal energy storage system working with adipic acid as the phase change material (PCM). By virtue of not participating directly in the solid–liquid and liquid–solid phase transition, ZnO-adipic acid composites (ZnO-adipic acid) possessed lower specific heat and latent heat. Our results have shown that the overall heat transfer coefficient during the freezing of PCM through heat transfer to a well-mixed liquid bath is amplified by 61%, when adipic acid is replaced with 2 wt.% ZnO-adipic acid. Heterogenous nucleation due to well-dispersed, ZnO nanorods caused this enhancement. The large enhancement in discharge rate of 2 wt.% ZnO-adipic acid during freezing overweighs higher degree of latent heat loss due to its repeated thermal cycling. The enhancement in overall heat transfer coefficient reported here (61%) is the highest reported so far for any latent heat thermal energy system employing adipic acid or its composites.
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institution Kabale University
issn 2213-9621
language English
publishDate 2024-11-01
publisher SpringerOpen
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series Micro and Nano Systems Letters
spelling doaj-art-6144e1c1e9bf4874bcddf261a66d074f2024-11-10T12:37:02ZengSpringerOpenMicro and Nano Systems Letters2213-96212024-11-0112111010.1186/s40486-024-00212-2ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systemsN. R. Snekha0V. Hari Suthan1K. S. Suganthi2S. Naren Raggavendra3S. Sudharsan4R. Aishwarya5K. S. Rajan6ABCDE Innovation Centre, Centre for Energy Storage & Conversion, Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), School of Chemical & Biotechnology, SASTRA Deemed UniversityABCDE Innovation Centre, Centre for Energy Storage & Conversion, Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), School of Chemical & Biotechnology, SASTRA Deemed UniversityABCDE Innovation Centre, Centre for Energy Storage & Conversion, Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), School of Chemical & Biotechnology, SASTRA Deemed UniversityABCDE Innovation Centre, Centre for Energy Storage & Conversion, Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), School of Chemical & Biotechnology, SASTRA Deemed UniversityABCDE Innovation Centre, Centre for Energy Storage & Conversion, Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), School of Chemical & Biotechnology, SASTRA Deemed UniversityABCDE Innovation Centre, Centre for Energy Storage & Conversion, Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), School of Chemical & Biotechnology, SASTRA Deemed UniversityABCDE Innovation Centre, Centre for Energy Storage & Conversion, Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), School of Chemical & Biotechnology, SASTRA Deemed UniversityAbstract This work evaluates the use of zinc oxide nanorods as intensifiers of a latent heat thermal energy storage system working with adipic acid as the phase change material (PCM). By virtue of not participating directly in the solid–liquid and liquid–solid phase transition, ZnO-adipic acid composites (ZnO-adipic acid) possessed lower specific heat and latent heat. Our results have shown that the overall heat transfer coefficient during the freezing of PCM through heat transfer to a well-mixed liquid bath is amplified by 61%, when adipic acid is replaced with 2 wt.% ZnO-adipic acid. Heterogenous nucleation due to well-dispersed, ZnO nanorods caused this enhancement. The large enhancement in discharge rate of 2 wt.% ZnO-adipic acid during freezing overweighs higher degree of latent heat loss due to its repeated thermal cycling. The enhancement in overall heat transfer coefficient reported here (61%) is the highest reported so far for any latent heat thermal energy system employing adipic acid or its composites.https://doi.org/10.1186/s40486-024-00212-2Adipic acidCompositesOverall heat transfer coefficientRenewable energySolidificationZinc oxide nanorods
spellingShingle N. R. Snekha
V. Hari Suthan
K. S. Suganthi
S. Naren Raggavendra
S. Sudharsan
R. Aishwarya
K. S. Rajan
ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systems
Micro and Nano Systems Letters
Adipic acid
Composites
Overall heat transfer coefficient
Renewable energy
Solidification
Zinc oxide nanorods
title ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systems
title_full ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systems
title_fullStr ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systems
title_full_unstemmed ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systems
title_short ZnO-adipic acid composites as phase change material for latent heat thermal energy storage systems
title_sort zno adipic acid composites as phase change material for latent heat thermal energy storage systems
topic Adipic acid
Composites
Overall heat transfer coefficient
Renewable energy
Solidification
Zinc oxide nanorods
url https://doi.org/10.1186/s40486-024-00212-2
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