Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous Carbon

Discarded sports waste faces bottlenecks in application due to inadequate disposal measures, and there is often a neglect of enhancing resource utilization efficiency and minimizing environmental impact. In this study, nanoporous biochar was prepared through co-hydrothermal carbonization (co-HTC) an...

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Main Authors: Tingyu Ma, Jieni Wang, Xiaobo Han, Chuanbing Zhang, Yahui Xu, Leichang Cao, Shuguang Zhao, Jinglai Zhang, Shicheng Zhang
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/30/1/26
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author Tingyu Ma
Jieni Wang
Xiaobo Han
Chuanbing Zhang
Yahui Xu
Leichang Cao
Shuguang Zhao
Jinglai Zhang
Shicheng Zhang
author_facet Tingyu Ma
Jieni Wang
Xiaobo Han
Chuanbing Zhang
Yahui Xu
Leichang Cao
Shuguang Zhao
Jinglai Zhang
Shicheng Zhang
author_sort Tingyu Ma
collection DOAJ
description Discarded sports waste faces bottlenecks in application due to inadequate disposal measures, and there is often a neglect of enhancing resource utilization efficiency and minimizing environmental impact. In this study, nanoporous biochar was prepared through co-hydrothermal carbonization (co-HTC) and pyrolytic activation by using mixed goose feathers and heavy-metals-contaminated pine sawdust. Comprehensive characterization demonstrated that the prepared M-3-25 (Biochar derived from mixed feedstocks (25 mg/g Cu in pine sawdust) at 700 °C with activator ratios of 3) possesses a high specific surface area 2501.08 m<sup>2</sup> g<sup>−1</sup> and abundant heteroatomic (N, O, and Cu), exhibiting an outstanding physicochemical structure and ultrahigh electrochemical performance. Compared to nanocarbon from a single feedstock, M-3-25 showed an ultrahigh capacitance of 587.14 F g<sup>−1</sup> at 1 A g<sup>−1</sup>, high energy density of 42.16 Wh kg<sup>−1</sup>, and only 8.61% capacitance loss after enduring 10,000 cycles at a current density of 10 A g<sup>−1</sup>, positioning M-3-25 at the forefront of previously known biomass-derived nanoporous carbon supercapacitors. This research not only introduces a promising countermeasure for the disposal of sports waste but also provides superior biochar electrode materials with robust supercapacitor characteristics.
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publishDate 2024-12-01
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spelling doaj-art-5fcdae0fa9104a7ebcc0222bcdfacb3e2025-01-10T13:18:39ZengMDPI AGMolecules1420-30492024-12-013012610.3390/molecules30010026Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous CarbonTingyu Ma0Jieni Wang1Xiaobo Han2Chuanbing Zhang3Yahui Xu4Leichang Cao5Shuguang Zhao6Jinglai Zhang7Shicheng Zhang8Henan Key Laboratory of Protection and Safety Energy Storage for Light Metal Materials, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, ChinaHenan Key Laboratory of Protection and Safety Energy Storage for Light Metal Materials, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, ChinaHenan Key Laboratory of Protection and Safety Energy Storage for Light Metal Materials, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, ChinaHuaxia Besince Environmental Technology Co., Ltd., Zhengzhou 450018, ChinaHuaxia Besince Environmental Technology Co., Ltd., Zhengzhou 450018, ChinaHenan Key Laboratory of Protection and Safety Energy Storage for Light Metal Materials, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, ChinaHuaxia Besince Environmental Technology Co., Ltd., Zhengzhou 450018, ChinaHenan Key Laboratory of Protection and Safety Energy Storage for Light Metal Materials, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, ChinaShanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, ChinaDiscarded sports waste faces bottlenecks in application due to inadequate disposal measures, and there is often a neglect of enhancing resource utilization efficiency and minimizing environmental impact. In this study, nanoporous biochar was prepared through co-hydrothermal carbonization (co-HTC) and pyrolytic activation by using mixed goose feathers and heavy-metals-contaminated pine sawdust. Comprehensive characterization demonstrated that the prepared M-3-25 (Biochar derived from mixed feedstocks (25 mg/g Cu in pine sawdust) at 700 °C with activator ratios of 3) possesses a high specific surface area 2501.08 m<sup>2</sup> g<sup>−1</sup> and abundant heteroatomic (N, O, and Cu), exhibiting an outstanding physicochemical structure and ultrahigh electrochemical performance. Compared to nanocarbon from a single feedstock, M-3-25 showed an ultrahigh capacitance of 587.14 F g<sup>−1</sup> at 1 A g<sup>−1</sup>, high energy density of 42.16 Wh kg<sup>−1</sup>, and only 8.61% capacitance loss after enduring 10,000 cycles at a current density of 10 A g<sup>−1</sup>, positioning M-3-25 at the forefront of previously known biomass-derived nanoporous carbon supercapacitors. This research not only introduces a promising countermeasure for the disposal of sports waste but also provides superior biochar electrode materials with robust supercapacitor characteristics.https://www.mdpi.com/1420-3049/30/1/26sports wastesupercapacitorco-hydrothermal carbonizationcapacitive performance
spellingShingle Tingyu Ma
Jieni Wang
Xiaobo Han
Chuanbing Zhang
Yahui Xu
Leichang Cao
Shuguang Zhao
Jinglai Zhang
Shicheng Zhang
Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous Carbon
Molecules
sports waste
supercapacitor
co-hydrothermal carbonization
capacitive performance
title Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous Carbon
title_full Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous Carbon
title_fullStr Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous Carbon
title_full_unstemmed Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous Carbon
title_short Co-Hydrothermal Carbonization of Goose Feather and Pine Sawdust: A Promising Strategy for Disposal of Sports Waste and the Robust Improvement of the Supercapacitor Characteristics of Pyrolytic Nanoporous Carbon
title_sort co hydrothermal carbonization of goose feather and pine sawdust a promising strategy for disposal of sports waste and the robust improvement of the supercapacitor characteristics of pyrolytic nanoporous carbon
topic sports waste
supercapacitor
co-hydrothermal carbonization
capacitive performance
url https://www.mdpi.com/1420-3049/30/1/26
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AT jinglaizhang cohydrothermalcarbonizationofgoosefeatherandpinesawdustapromisingstrategyfordisposalofsportswasteandtherobustimprovementofthesupercapacitorcharacteristicsofpyrolyticnanoporouscarbon
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