Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)

Activated carbon was produced from high-grade bituminous coal, potentially removing Cr metal in textile industrial waste. The purposes of this study were 1) getting activated carbon characteristics, 2) studying the impact of reagent concentration and activation temperature on the activated carbon ch...

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Main Authors: Esthi Kusdarini, Denis Rocky Pradana, Agus Budianto
Format: Article
Language:English
Published: Diponegoro University 2022-06-01
Series:Reaktor
Online Access:https://ejournal.undip.ac.id/index.php/reaktor/article/view/43723
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author Esthi Kusdarini
Denis Rocky Pradana
Agus Budianto
author_facet Esthi Kusdarini
Denis Rocky Pradana
Agus Budianto
author_sort Esthi Kusdarini
collection DOAJ
description Activated carbon was produced from high-grade bituminous coal, potentially removing Cr metal in textile industrial waste. The purposes of this study were 1) getting activated carbon characteristics, 2) studying the impact of reagent concentration and activation temperature on the activated carbon characteristics, and 3) getting the isotherm adsorption equation for activated carbon developed by Freundlich and Langmuir on Cr metal. This research used an experimental method with a laboratory scale, which means the manufacture of activated carbon and a test of adsorbs power of activated carbon to the Cr metal were conducted in the laboratory. Activated carbon manufacture through carbonization process of chemical activation used reagent (NH4)3PO4, neutralization, filtration, physical activation, and cooling. At the same time, it tested the adsorption power of the activated carbon to Cr metal through activated carbon contact with a solution containing some Cr6+ ion. The update in this research was using reagent (NH4)3PO4 and the test of adsorption power of activated carbon to Cr6+ ion contained in the artificial waste. This research showed activated carbon that has been activated using reagent (NH4)3PO4 0.5 – 2 M at physical activation temperature of 825oC and has met the standard of SNI number 06-3730-1995. The best-activated carbon was produced from chemical activation using (NH4)3PO4 1 M solution and physical activation at 825oC. The best-activated carbon characteristics contained 1.27% water; 17.17% content of volatile matter, 9.39% was ash content; 73.17% contained fixed carbon, and the iodine value was 1248.30 mg/g. The best Equation of Langmuir isotherm adsorption of activated carbon to the Cr6+ produced Constant Ar = -90.0901 and Kc = -0.0075.
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issn 0852-0798
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publishDate 2022-06-01
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spelling doaj-art-58c6794d8b0c4208b2986c96304d55d02024-11-13T02:46:30ZengDiponegoro UniversityReaktor0852-07982407-59732022-06-01221142010.14710/reaktor.22.1.14-2020651Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)Esthi Kusdarini0Denis Rocky Pradana1Agus Budianto2Jurusan Teknik Pertambangan ITATS, IndonesiaJurusan Teknik Pertambangan, Institut Teknologi Adhi Tama Surabaya, IndonesiaJurusan Teknik Kimia Institut Teknologi Adhi Tama Surabaya, IndonesiaActivated carbon was produced from high-grade bituminous coal, potentially removing Cr metal in textile industrial waste. The purposes of this study were 1) getting activated carbon characteristics, 2) studying the impact of reagent concentration and activation temperature on the activated carbon characteristics, and 3) getting the isotherm adsorption equation for activated carbon developed by Freundlich and Langmuir on Cr metal. This research used an experimental method with a laboratory scale, which means the manufacture of activated carbon and a test of adsorbs power of activated carbon to the Cr metal were conducted in the laboratory. Activated carbon manufacture through carbonization process of chemical activation used reagent (NH4)3PO4, neutralization, filtration, physical activation, and cooling. At the same time, it tested the adsorption power of the activated carbon to Cr metal through activated carbon contact with a solution containing some Cr6+ ion. The update in this research was using reagent (NH4)3PO4 and the test of adsorption power of activated carbon to Cr6+ ion contained in the artificial waste. This research showed activated carbon that has been activated using reagent (NH4)3PO4 0.5 – 2 M at physical activation temperature of 825oC and has met the standard of SNI number 06-3730-1995. The best-activated carbon was produced from chemical activation using (NH4)3PO4 1 M solution and physical activation at 825oC. The best-activated carbon characteristics contained 1.27% water; 17.17% content of volatile matter, 9.39% was ash content; 73.17% contained fixed carbon, and the iodine value was 1248.30 mg/g. The best Equation of Langmuir isotherm adsorption of activated carbon to the Cr6+ produced Constant Ar = -90.0901 and Kc = -0.0075.https://ejournal.undip.ac.id/index.php/reaktor/article/view/43723
spellingShingle Esthi Kusdarini
Denis Rocky Pradana
Agus Budianto
Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)
Reaktor
title Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)
title_full Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)
title_fullStr Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)
title_full_unstemmed Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)
title_short Production of Activated Carbon from High-Grade Bituminous Coal to Removal Cr (VI)
title_sort production of activated carbon from high grade bituminous coal to removal cr vi
url https://ejournal.undip.ac.id/index.php/reaktor/article/view/43723
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AT denisrockypradana productionofactivatedcarbonfromhighgradebituminouscoaltoremovalcrvi
AT agusbudianto productionofactivatedcarbonfromhighgradebituminouscoaltoremovalcrvi