Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents

Magnetic nanoparticles are amongst the most promising adsorption materials for oil spill clean-up due to their high surface area, ease of functionalization with high oil affinity and facile separation after the cleaning process with an external magnetic field. In this work, we successfully synthesiz...

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Main Authors: Ajra Hadela, Marijana Lakić, Mateja Potočnik, Aljoša Košak, Andreja Gutmaher, Aleksandra Lobnik
Format: Article
Language:English
Published: SAGE Publishing 2020-07-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617420922014
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author Ajra Hadela
Marijana Lakić
Mateja Potočnik
Aljoša Košak
Andreja Gutmaher
Aleksandra Lobnik
author_facet Ajra Hadela
Marijana Lakić
Mateja Potočnik
Aljoša Košak
Andreja Gutmaher
Aleksandra Lobnik
author_sort Ajra Hadela
collection DOAJ
description Magnetic nanoparticles are amongst the most promising adsorption materials for oil spill clean-up due to their high surface area, ease of functionalization with high oil affinity and facile separation after the cleaning process with an external magnetic field. In this work, we successfully synthesized magnetic cobalt ferrite nanoparticles (CoFe 2 O 4 NPs) that were electrostatically stabilized and functionalized with various alkoxysilanes for effective oil adsorption and oil spill removal. Additionally, the adsorption capacity of CoFe 2 O 4 NPs was determined, and the possibility of their reuse assessed. Prepared samples showed high oil adsorption capacities between 2.6 and 3.5 g of oil per g of nanoparticles and were successfully collected with an external magnet. Furthermore, the samples showed excellent properties after regeneration, as their adsorption capacity decreased by less than 3% after reuse. All the prepared samples were thoroughly characterized to better understand their behaviour and the differences in the use of various silanes were highlighted.
format Article
id doaj-art-555a20603edb4f4399954b4ee4cd74e6
institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2020-07-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-555a20603edb4f4399954b4ee4cd74e62025-01-03T00:10:43ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382020-07-013810.1177/0263617420922014Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbentsAjra HadelaMarijana LakićMateja PotočnikAljoša KošakAndreja GutmaherAleksandra LobnikMagnetic nanoparticles are amongst the most promising adsorption materials for oil spill clean-up due to their high surface area, ease of functionalization with high oil affinity and facile separation after the cleaning process with an external magnetic field. In this work, we successfully synthesized magnetic cobalt ferrite nanoparticles (CoFe 2 O 4 NPs) that were electrostatically stabilized and functionalized with various alkoxysilanes for effective oil adsorption and oil spill removal. Additionally, the adsorption capacity of CoFe 2 O 4 NPs was determined, and the possibility of their reuse assessed. Prepared samples showed high oil adsorption capacities between 2.6 and 3.5 g of oil per g of nanoparticles and were successfully collected with an external magnet. Furthermore, the samples showed excellent properties after regeneration, as their adsorption capacity decreased by less than 3% after reuse. All the prepared samples were thoroughly characterized to better understand their behaviour and the differences in the use of various silanes were highlighted.https://doi.org/10.1177/0263617420922014
spellingShingle Ajra Hadela
Marijana Lakić
Mateja Potočnik
Aljoša Košak
Andreja Gutmaher
Aleksandra Lobnik
Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents
Adsorption Science & Technology
title Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents
title_full Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents
title_fullStr Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents
title_full_unstemmed Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents
title_short Novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents
title_sort novel reusable functionalized magnetic cobalt ferrite nanoparticles as oil adsorbents
url https://doi.org/10.1177/0263617420922014
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AT matejapotocnik novelreusablefunctionalizedmagneticcobaltferritenanoparticlesasoiladsorbents
AT aljosakosak novelreusablefunctionalizedmagneticcobaltferritenanoparticlesasoiladsorbents
AT andrejagutmaher novelreusablefunctionalizedmagneticcobaltferritenanoparticlesasoiladsorbents
AT aleksandralobnik novelreusablefunctionalizedmagneticcobaltferritenanoparticlesasoiladsorbents