Enantioselective Assembly of Fully Substituted α‐Amino Allenoates Through a Mannich Addition and Stepwise [3,3]‐σ Rearrangement Sequence
Abstract Chiral fully‐substituted allenes are synthetically significant and pivotal building blocks that can engage in diverse transformations toward a variety of bioactive molecules. The enantioselective assembly of these skeletons using readily available reactants offers significant advantages but...
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Main Authors: | Haoxuan Yuan, Yi Zhou, Xiongda Xie, Ming Bao, Kewei Chen, Kemiao Hong, Zhixiang Yu, Xinfang Xu |
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Format: | Article |
Language: | English |
Published: |
Wiley
2025-01-01
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Series: | Advanced Science |
Subjects: | |
Online Access: | https://doi.org/10.1002/advs.202409334 |
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