Crystal structure of di-μ-acetato-κ4O:O′-bis{(acetato-κ2O,O′)tetraaqua[1-(pyridin-2-ylmethylidene-κN)-2-(pyridin-2-yl-κN)hydrazine-κN1]lanthanum(III)} dinitrate hemihydrate

Crystal structure of di-μ-acetato-κ4O:O′-bis{(acetato-κ2O,O′)tetraaqua[1-(pyridin-2-ylmethylidene-κN)-2-(pyridin-2-yl-κN)hydrazine-κN1]lanthanum(III)} dinitrate hemihydrate

In the binuclear title complex, [La2(C2H3O2)4(C11H10N4)(H2O)4](NO3)2·0.5H2O, the two lanthanum ions are nine coordinate in a distorted trigonal–prismatic geometry. Each LaIII ion is bonded to three N atoms of the Schiff base, 1-(pyridin-2-yl)-2-(pyridin-2-ylmethylene)hydrazine and is coordinated by...

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Bibliographic Details
Main Authors: Mbossé Ndiaye-Gueye, Bocar Traoré, Ibrahima Elhadji Thiam, Ousmane Diouf, Emmanuel Wenger, Abdou Salam Sall, Claude Lecomte, Mohamed Gaye
Format: Article
Language:English
Published: International Union of Crystallography 2025-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
lanthanum
crystal structure
2-hydrazinopyridine,hydrazone
Online Access:https://journals.iucr.org/paper?S2056989024012349
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