Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane Droplets

In this study, we examined the impact of droplet size and laser energy on droplet fragmentation and the resulting species composition due to laser irradiation of an acoustically levitated heptane droplet. Using shadowgraphy and spatially resolved laser-induced breakdown spectroscopy (LIBS), we obser...

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Main Authors: Parneeth Lokini, Ciprian Dumitrache, Bret C. Windom, Azer P. Yalin
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Photonics
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Online Access:https://www.mdpi.com/2304-6732/11/11/1044
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author Parneeth Lokini
Ciprian Dumitrache
Bret C. Windom
Azer P. Yalin
author_facet Parneeth Lokini
Ciprian Dumitrache
Bret C. Windom
Azer P. Yalin
author_sort Parneeth Lokini
collection DOAJ
description In this study, we examined the impact of droplet size and laser energy on droplet fragmentation and the resulting species composition due to laser irradiation of an acoustically levitated heptane droplet. Using shadowgraphy and spatially resolved laser-induced breakdown spectroscopy (LIBS), we observed two different fragmentation regimes for the conditions studied. The experiments demonstrated that low laser energy densities (<~70 mJ/mm<sup>3</sup>), designated as regime 1, resulted in a single plasma breakdown event accompanied by broadband emission and C<sub>2</sub> Swan bands, suggesting weak plasma formation. Conversely, high energy densities (>~70 mJ/mm<sup>3</sup>), designated as regime 2, resulted in multiple plasma breakdowns that resulted in the emission of H<sub>α</sub>, O, and N, implying a full laser breakdown in the gaseous reactive mixture. Additionally, in regime 2, we calculated the electron density using Stark broadening of the H<sub>α</sub> line and temperature using Boltzmann analysis of O lines at 715 nm and 777 nm. We found that the electron densities and temperatures within the air spark and heptane droplets are quite similar. The findings from this research could impact the design of spray ignition systems and may also aid in validating the modeling efforts of aerosols, droplet breakdown, and ignition.
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spelling doaj-art-52603c026e894cc9a2787e8be4b411e42024-11-26T18:18:23ZengMDPI AGPhotonics2304-67322024-11-011111104410.3390/photonics11111044Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane DropletsParneeth Lokini0Ciprian Dumitrache1Bret C. Windom2Azer P. Yalin3Department of Mechanical Engineering, Colorado State University, Fort Collins, CO 80524, USADepartment of Mechanical Engineering, Colorado State University, Fort Collins, CO 80524, USADepartment of Mechanical Engineering, Colorado State University, Fort Collins, CO 80524, USADepartment of Mechanical Engineering, Colorado State University, Fort Collins, CO 80524, USAIn this study, we examined the impact of droplet size and laser energy on droplet fragmentation and the resulting species composition due to laser irradiation of an acoustically levitated heptane droplet. Using shadowgraphy and spatially resolved laser-induced breakdown spectroscopy (LIBS), we observed two different fragmentation regimes for the conditions studied. The experiments demonstrated that low laser energy densities (<~70 mJ/mm<sup>3</sup>), designated as regime 1, resulted in a single plasma breakdown event accompanied by broadband emission and C<sub>2</sub> Swan bands, suggesting weak plasma formation. Conversely, high energy densities (>~70 mJ/mm<sup>3</sup>), designated as regime 2, resulted in multiple plasma breakdowns that resulted in the emission of H<sub>α</sub>, O, and N, implying a full laser breakdown in the gaseous reactive mixture. Additionally, in regime 2, we calculated the electron density using Stark broadening of the H<sub>α</sub> line and temperature using Boltzmann analysis of O lines at 715 nm and 777 nm. We found that the electron densities and temperatures within the air spark and heptane droplets are quite similar. The findings from this research could impact the design of spray ignition systems and may also aid in validating the modeling efforts of aerosols, droplet breakdown, and ignition.https://www.mdpi.com/2304-6732/11/11/1044laser-induced breakdown spectroscopy (LIBS)shadowgraphydroplet fragmentationelectron densitytemperaturecombustion
spellingShingle Parneeth Lokini
Ciprian Dumitrache
Bret C. Windom
Azer P. Yalin
Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane Droplets
Photonics
laser-induced breakdown spectroscopy (LIBS)
shadowgraphy
droplet fragmentation
electron density
temperature
combustion
title Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane Droplets
title_full Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane Droplets
title_fullStr Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane Droplets
title_full_unstemmed Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane Droplets
title_short Laser-Induced Breakdown Spectroscopy and Shadowgraphy of Acoustically Levitated Heptane Droplets
title_sort laser induced breakdown spectroscopy and shadowgraphy of acoustically levitated heptane droplets
topic laser-induced breakdown spectroscopy (LIBS)
shadowgraphy
droplet fragmentation
electron density
temperature
combustion
url https://www.mdpi.com/2304-6732/11/11/1044
work_keys_str_mv AT parneethlokini laserinducedbreakdownspectroscopyandshadowgraphyofacousticallylevitatedheptanedroplets
AT cipriandumitrache laserinducedbreakdownspectroscopyandshadowgraphyofacousticallylevitatedheptanedroplets
AT bretcwindom laserinducedbreakdownspectroscopyandshadowgraphyofacousticallylevitatedheptanedroplets
AT azerpyalin laserinducedbreakdownspectroscopyandshadowgraphyofacousticallylevitatedheptanedroplets