Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesis

Abstract Reducing greenhouse gas emissions is critical for humanity nowadays, but it can be beneficial by developing engineered systems that valorize CO2 into commodities, thus mimicking nature’s wisdom. Purple phototrophic bacteria (PPB) naturally accept CO2 into their metabolism as a primary redox...

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Main Authors: Sara Díaz-Rullo Edreira, Ioanna A. Vasiliadou, Amanda Prado, Juan José Espada, Ruddy Wattiez, Baptiste Leroy, Fernando Martínez, Daniel Puyol
Format: Article
Language:English
Published: Nature Portfolio 2024-11-01
Series:Communications Biology
Online Access:https://doi.org/10.1038/s42003-024-07188-0
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author Sara Díaz-Rullo Edreira
Ioanna A. Vasiliadou
Amanda Prado
Juan José Espada
Ruddy Wattiez
Baptiste Leroy
Fernando Martínez
Daniel Puyol
author_facet Sara Díaz-Rullo Edreira
Ioanna A. Vasiliadou
Amanda Prado
Juan José Espada
Ruddy Wattiez
Baptiste Leroy
Fernando Martínez
Daniel Puyol
author_sort Sara Díaz-Rullo Edreira
collection DOAJ
description Abstract Reducing greenhouse gas emissions is critical for humanity nowadays, but it can be beneficial by developing engineered systems that valorize CO2 into commodities, thus mimicking nature’s wisdom. Purple phototrophic bacteria (PPB) naturally accept CO2 into their metabolism as a primary redox sink system in photo-heterotrophy. Dedicated use of this feature for developing sustainable processes (e.g., through negative-emissions photo-bioelectrosynthesis) requires a deep knowledge of the inherent metabolic mechanisms. This work provides evidence of tuning the PPB metabolic mechanisms upon redox stressing through negative polarization (−0.4 and −0.8 V vs. Ag/AgCl) in photo-bioelectrochemical devices. A mixed PPB-culture upregulates its ability to capture CO2 from organics oxidation through the Calvin-Besson-Bassam cycle and anaplerotic pathways, and the redox imbalance is promoted to polyhydroxyalkanoates production. The ecological relationship of PPB with mutualist bacteria stabilizes the system and opens the door for future development of photo-bioelectrochemical devices focused on CO up-cycling.
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issn 2399-3642
language English
publishDate 2024-11-01
publisher Nature Portfolio
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series Communications Biology
spelling doaj-art-4fa572dfc35f4fa7b4c8f62f87ad97992024-11-24T12:39:00ZengNature PortfolioCommunications Biology2399-36422024-11-017111410.1038/s42003-024-07188-0Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesisSara Díaz-Rullo Edreira0Ioanna A. Vasiliadou1Amanda Prado2Juan José Espada3Ruddy Wattiez4Baptiste Leroy5Fernando Martínez6Daniel Puyol7Department of Chemical and Environmental Engineering, High School of Experimental Sciences and Technology, University Rey Juan CarlosDepartment of Environmental Engineering, Democritus University of ThraceDepartment of Automation, Electric Engineering and Electronic Technology, Polytechnic University of CartagenaDepartment of Chemical and Environmental Engineering, High School of Experimental Sciences and Technology, University Rey Juan CarlosLaboratory of Proteomics and Microbiology, Research Institute for Biosciences, University of MonsLaboratory of Proteomics and Microbiology, Research Institute for Biosciences, University of MonsDepartment of Chemical and Environmental Engineering, High School of Experimental Sciences and Technology, University Rey Juan CarlosDepartment of Chemical and Environmental Engineering, High School of Experimental Sciences and Technology, University Rey Juan CarlosAbstract Reducing greenhouse gas emissions is critical for humanity nowadays, but it can be beneficial by developing engineered systems that valorize CO2 into commodities, thus mimicking nature’s wisdom. Purple phototrophic bacteria (PPB) naturally accept CO2 into their metabolism as a primary redox sink system in photo-heterotrophy. Dedicated use of this feature for developing sustainable processes (e.g., through negative-emissions photo-bioelectrosynthesis) requires a deep knowledge of the inherent metabolic mechanisms. This work provides evidence of tuning the PPB metabolic mechanisms upon redox stressing through negative polarization (−0.4 and −0.8 V vs. Ag/AgCl) in photo-bioelectrochemical devices. A mixed PPB-culture upregulates its ability to capture CO2 from organics oxidation through the Calvin-Besson-Bassam cycle and anaplerotic pathways, and the redox imbalance is promoted to polyhydroxyalkanoates production. The ecological relationship of PPB with mutualist bacteria stabilizes the system and opens the door for future development of photo-bioelectrochemical devices focused on CO up-cycling.https://doi.org/10.1038/s42003-024-07188-0
spellingShingle Sara Díaz-Rullo Edreira
Ioanna A. Vasiliadou
Amanda Prado
Juan José Espada
Ruddy Wattiez
Baptiste Leroy
Fernando Martínez
Daniel Puyol
Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesis
Communications Biology
title Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesis
title_full Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesis
title_fullStr Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesis
title_full_unstemmed Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesis
title_short Elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo-electrosynthesis
title_sort elucidating metabolic tuning of mixed purple phototrophic bacteria biofilms in photoheterotrophic conditions through microbial photo electrosynthesis
url https://doi.org/10.1038/s42003-024-07188-0
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