Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production
MnO, Mn 2 O 3 , Fe 2 O 3 and Fe 3 O 4 are catalytically active for the steam reforming of ethanol. The main reaction products were acetaldehyde, acetone, CO 2 and H 2 in the temperature range of 300–550°C. At low temperatures, high selectivity for acetone (up to 75%) was observed for MnO. Based on t...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2015-08-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.33.6-8.715 |
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| author | Lidiya Yu. Dolgykh Irina L. Stolyarchuk Larisa A. Staraya Inna V. Vasylenko Yuri I. Pyatnitsky Peter E. Strizhak |
| author_facet | Lidiya Yu. Dolgykh Irina L. Stolyarchuk Larisa A. Staraya Inna V. Vasylenko Yuri I. Pyatnitsky Peter E. Strizhak |
| author_sort | Lidiya Yu. Dolgykh |
| collection | DOAJ |
| description | MnO, Mn 2 O 3 , Fe 2 O 3 and Fe 3 O 4 are catalytically active for the steam reforming of ethanol. The main reaction products were acetaldehyde, acetone, CO 2 and H 2 in the temperature range of 300–550°C. At low temperatures, high selectivity for acetone (up to 75%) was observed for MnO. Based on the study results, the relation between product selectivity of the oxide catalysts and their acid–base/redox properties balance is suggested. The selectivity for hydrogen was about 80% for Fe 2 O 3 at 550°C with 100% ethanol conversion. |
| format | Article |
| id | doaj-art-4e039b3b9e934f4b9aa2fa2376e3edf0 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2015-08-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-4e039b3b9e934f4b9aa2fa2376e3edf02025-01-02T22:38:05ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382015-08-013310.1260/0263-6174.33.6-8.715Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen ProductionLidiya Yu. DolgykhIrina L. StolyarchukLarisa A. StarayaInna V. VasylenkoYuri I. PyatnitskyPeter E. StrizhakMnO, Mn 2 O 3 , Fe 2 O 3 and Fe 3 O 4 are catalytically active for the steam reforming of ethanol. The main reaction products were acetaldehyde, acetone, CO 2 and H 2 in the temperature range of 300–550°C. At low temperatures, high selectivity for acetone (up to 75%) was observed for MnO. Based on the study results, the relation between product selectivity of the oxide catalysts and their acid–base/redox properties balance is suggested. The selectivity for hydrogen was about 80% for Fe 2 O 3 at 550°C with 100% ethanol conversion.https://doi.org/10.1260/0263-6174.33.6-8.715 |
| spellingShingle | Lidiya Yu. Dolgykh Irina L. Stolyarchuk Larisa A. Staraya Inna V. Vasylenko Yuri I. Pyatnitsky Peter E. Strizhak Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production Adsorption Science & Technology |
| title | Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production |
| title_full | Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production |
| title_fullStr | Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production |
| title_full_unstemmed | Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production |
| title_short | Steam Reforming of Ethanol over Manganese and Iron Oxides for Hydrogen Production |
| title_sort | steam reforming of ethanol over manganese and iron oxides for hydrogen production |
| url | https://doi.org/10.1260/0263-6174.33.6-8.715 |
| work_keys_str_mv | AT lidiyayudolgykh steamreformingofethanolovermanganeseandironoxidesforhydrogenproduction AT irinalstolyarchuk steamreformingofethanolovermanganeseandironoxidesforhydrogenproduction AT larisaastaraya steamreformingofethanolovermanganeseandironoxidesforhydrogenproduction AT innavvasylenko steamreformingofethanolovermanganeseandironoxidesforhydrogenproduction AT yuriipyatnitsky steamreformingofethanolovermanganeseandironoxidesforhydrogenproduction AT peterestrizhak steamreformingofethanolovermanganeseandironoxidesforhydrogenproduction |