Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette development

The use of starch as a binder in biomass briquette production raises concerns regarding food security, prompting the need for alternative, non-food-based binders. This study aimed to develop carboxymethyl holocellulose (CMH) derived from oil palm empty fruit bunches (OPEFBs) as a sustainable and eff...

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Main Authors: Awaly Ilham Dewantoro, Muklis Fauzan, Muhammad Adly Rahandi Lubis, Desy Nurliasari, Efri Mardawati
Format: Article
Language:English
Published: Universitas Brawijaya, Fakultas Teknologi Pertanian 2024-12-01
Series:Advances in Food Science, Sustainable Agriculture, and Agroindustrial Engineering
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Online Access:https://afssaae.ub.ac.id/index.php/afssaae/article/view/18908/269
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author Awaly Ilham Dewantoro
Muklis Fauzan
Muhammad Adly Rahandi Lubis
Desy Nurliasari
Efri Mardawati
author_facet Awaly Ilham Dewantoro
Muklis Fauzan
Muhammad Adly Rahandi Lubis
Desy Nurliasari
Efri Mardawati
author_sort Awaly Ilham Dewantoro
collection DOAJ
description The use of starch as a binder in biomass briquette production raises concerns regarding food security, prompting the need for alternative, non-food-based binders. This study aimed to develop carboxymethyl holocellulose (CMH) derived from oil palm empty fruit bunches (OPEFBs) as a sustainable and effective binder for biomass briquettes made from coconut shells and sawdust. The OPEFBs were converted into CMH through a carboxymethylation process, yielding a product with a carboxyl content of 12.81% and a degree of substitution (DS) of 0.40, indicating effective modification. The synthesized CMH was used as a binder at various concentrations, with citric acid (CA) employed as a crosslinking agent. The total carboxyl content significantly increased with higher CA concentrations, demonstrating improved functional properties. Briquettes produced using CMH exhibited favorable proximate characteristics, such as low moisture content, high fixed carbon, and enhanced calorific value, particularly for coconut shell-based briquettes. The findings suggest that CMH can serve as an alternative to starch, providing sustainable and environmentally friendly solutions for biomass briquette production. Future studies should focus on optimizing the synthesis process and exploring CMHs’ performance in diverse biomass formulations.
format Article
id doaj-art-4d5a239c61f94411b7e8a9f4ca907ee3
institution Kabale University
issn 2622-5921
language English
publishDate 2024-12-01
publisher Universitas Brawijaya, Fakultas Teknologi Pertanian
record_format Article
series Advances in Food Science, Sustainable Agriculture, and Agroindustrial Engineering
spelling doaj-art-4d5a239c61f94411b7e8a9f4ca907ee32025-01-10T08:59:20ZengUniversitas Brawijaya, Fakultas Teknologi PertanianAdvances in Food Science, Sustainable Agriculture, and Agroindustrial Engineering2622-59212024-12-017429230110.21776/ub.afssaae.2024.007.04.2Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette developmentAwaly Ilham Dewantoro0Muklis Fauzan1Muhammad Adly Rahandi Lubis2Desy Nurliasari3Efri Mardawati4Universitas PadjadjaranUniversitas PadjadjaranNational Research and Innovation Agency (BRIN)Universitas PadjadjaranUniversitas PadjadjaranThe use of starch as a binder in biomass briquette production raises concerns regarding food security, prompting the need for alternative, non-food-based binders. This study aimed to develop carboxymethyl holocellulose (CMH) derived from oil palm empty fruit bunches (OPEFBs) as a sustainable and effective binder for biomass briquettes made from coconut shells and sawdust. The OPEFBs were converted into CMH through a carboxymethylation process, yielding a product with a carboxyl content of 12.81% and a degree of substitution (DS) of 0.40, indicating effective modification. The synthesized CMH was used as a binder at various concentrations, with citric acid (CA) employed as a crosslinking agent. The total carboxyl content significantly increased with higher CA concentrations, demonstrating improved functional properties. Briquettes produced using CMH exhibited favorable proximate characteristics, such as low moisture content, high fixed carbon, and enhanced calorific value, particularly for coconut shell-based briquettes. The findings suggest that CMH can serve as an alternative to starch, providing sustainable and environmentally friendly solutions for biomass briquette production. Future studies should focus on optimizing the synthesis process and exploring CMHs’ performance in diverse biomass formulations.https://afssaae.ub.ac.id/index.php/afssaae/article/view/18908/269agricultural residuesalternative binderscitric acidmodified polysaccharidesrenewable energy
spellingShingle Awaly Ilham Dewantoro
Muklis Fauzan
Muhammad Adly Rahandi Lubis
Desy Nurliasari
Efri Mardawati
Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette development
Advances in Food Science, Sustainable Agriculture, and Agroindustrial Engineering
agricultural residues
alternative binders
citric acid
modified polysaccharides
renewable energy
title Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette development
title_full Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette development
title_fullStr Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette development
title_full_unstemmed Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette development
title_short Carboxymethyl holocellulose as alternative carbohydrate-based binder for biomass briquette development
title_sort carboxymethyl holocellulose as alternative carbohydrate based binder for biomass briquette development
topic agricultural residues
alternative binders
citric acid
modified polysaccharides
renewable energy
url https://afssaae.ub.ac.id/index.php/afssaae/article/view/18908/269
work_keys_str_mv AT awalyilhamdewantoro carboxymethylholocelluloseasalternativecarbohydratebasedbinderforbiomassbriquettedevelopment
AT muklisfauzan carboxymethylholocelluloseasalternativecarbohydratebasedbinderforbiomassbriquettedevelopment
AT muhammadadlyrahandilubis carboxymethylholocelluloseasalternativecarbohydratebasedbinderforbiomassbriquettedevelopment
AT desynurliasari carboxymethylholocelluloseasalternativecarbohydratebasedbinderforbiomassbriquettedevelopment
AT efrimardawati carboxymethylholocelluloseasalternativecarbohydratebasedbinderforbiomassbriquettedevelopment